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91.
A copolymer of 4‐vinylpyridine (4‐VP) and styrene was synthesized by radical mass polymerization using 2,2′‐azobisisobutyronitrile as initiator. An insoluble (linear) pyridinium‐type polymer was prepared by the reaction of P (4VP–St) with 1‐bromooctane. An anion exchange membrane was prepared using a composite of pyridinium‐type polymer and a fibrous woven structure for use in electrochemistry. The composite membrane was characterized by X‐ray diffraction, tensile strength, scanning electron microscopy, and electrochemistry measurements. The experimental results showed that the fibrous woven product had improved the tensile strength more than had the membrane made of a pyridinium‐type polymer alone. The composite membrane was used in alkaline fuel cells, and its properties were measured by electrochemical analysis. The ionic conductivity of the membrane was acceptable, but its performance as a direct methanol fuel cell (DMFC) was not. The primary reason for this was analyzed, and research is ongoing, with analysis to be discussed in later reports. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2248–2251, 2006 相似文献
92.
在制备柱撑蒙脱石的过程中,首次提出了蒙脱石的预处理工艺,并以莱西钙基膨润土为原料,研究了预处理方法、预处理时间、料浆浓度、分散剂种类及用量对蒙脱石分散程度的影响,将钙基蒙脱石颗粒分散达到0.964 μm。经过预处理后,用钙基蒙脱石直接制备柱撑蒙脱石,并用SEM、XRD、DTA-TG和SRF等进行了表征。经300 ℃焙烧2 h后,其层间距为1.262 nm,热稳定性达588 ℃,此法省去了蒙脱石的钠化改性,简化了制备工艺。 相似文献
93.
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95.
生物转化植物纤维产酒精的研究进展 总被引:3,自引:0,他引:3
植物纤维是潜在的可再生资源,利用微生物对其进行降解、转化以实现工业化低成本生产,已成为研究的热点。从生物方法角度对植物纤维为原料产酒精的3个阶段:原料预处理、纤维素酶糖化和发酵进行全面的阐述,包括微生物及其作用机理和处理工艺等方面的内容。 相似文献
96.
铝系阻燃剂阻燃PP的力学性能研究 总被引:2,自引:0,他引:2
将用偶联剂处理的碱式碳酸铝镁加入到聚丙烯中,通过对体系阻燃性、力学性能等研究得出:碱式碳酸铝镁能够对聚丙烯起到良好的阻燃效果,碱式碳酸铝镁的加入提高了聚丙烯的冲击强度,当碱式碳酸铝镁质量分数为23%时,体系的冲击强度最高。研究了偶联荆的用量对体系力学性能的影响,结果表明,随偶联荆用量的增加,体系的拉伸强度降低,冲击强度先升高后降低,当偶联荆质量分数为1.0%时,体系的冲击强度最高。 相似文献
97.
Gold particles supported on carbon and titania were explored as catalysts for oxidation of CO or glycerol by O2 at room temperature in liquid-phase water. Although Au/carbon catalysts were not active for vapor phase CO oxidation at room
temperature, a turnover frequency of 5 s−1 could be achieved with comparable CO concentration in aqueous solution containing 1 M NaOH. The turnover frequency on Au/carbon
was a strong function of pH, decreasing by about a factor of 50 when the pH decreased from 14 to 0.3. Evidently, a catalytic
oxidation route that was not available in the vapor phase is enabled by operation in the liquid water at high pH. Since Au/titania
is active for vapor phase CO oxidation, the role of water, and therefore hydroxyl concentration, is not as significant as
that for Au/carbon. Hydrogen peroxide is also produced during CO oxidation over Au in liquid water and increasing the hydroxyl
concentration enhances its formation rate. For glycerol oxidation to glyceric acid (C3) and glycolic acid (C2) with O2 (1–10 atm) at 308–333 K over supported Au particles, high pH is required for catalysis to occur. Similar to CO oxidation
in liquid water, H2O2 is also produced during glycerol oxidation at high pH. The formation of the C-C cleavage product glycolic acid is attributed
to peroxide in the reaction. 相似文献
98.
利用间歇反应器研究了邻溴苯酚在250℃~350℃高温液态水中的降解行为,探讨了脱溴效率的影响因素和降解反应动力学。结果表明:升高温度和添加碱性物质能显著提高脱溴率;邻溴苯酚在0.1mol/L碳酸钠溶液中的降解符合表观一级反应动力学规律。GC-MS分析结果表明邻溴苯酚在高温碱水中降解的主要产物为苯酚和邻苯二酚,并由此推测出降解途径。 相似文献
99.
该文针对棉针织物前处理过程工艺指标吸水性和白度难以实现在线连续检测,且与前处理过程温度、时间、液碱浓度、双氧水浓度等影响因素具有较强非线性,难以建立精确数学模型。在分析了棉针织物前处理过程质量指标相关影响因素的基础上,采用最小二乘支持向量机建立了前处理过程工艺技术指标软测量模型,并通过实验验证了软测量模型的有效性。 相似文献
100.
Calcium phosphate film was prepared by electrochemical deposition technology. Subsequently, the alkaline treatment process
of calcium phosphate film in 0.1 mol/L NaOH solution was monitored on real time by the piezoelectric quartz crystal impedance
(PQCI) technique. The variations of morphology and composition for the alkaline treatment products were characterized by scanning
electron microscopy (SEM), Fourier transform infrared (FT-IR) and X-ray diffraction (XRD), respectively. The dynamic variations
of calcium phosphate can be characterized by the change of equivalent circuit parameters. The results show that the forming
process of hydroxyapatite (HA) is composed of three stages: (1) acidic calcium phosphate dissolution; (2) phase transformation;
and (3) HA formation. Furthermore, the correlative kinetic equations and parameters are obtained by fitting the static capacitance
(C
s)—time curves.
Foundation item: Project(2005CB623901) supported by the Major State Basic Research and Development Program of China 相似文献