Flow and Flow Decay of Refractory Castables

Installation of refractory castables depend not only on flow,but also on how soon the flow is lost because of setting.The loss of flow(flow decay)has always been one of the main problems of refractory castable manufacturers,a problem that has not been too well described in literature.The flow decay has been studied for a castable system based on alumina,pointing out some general trends.The flow decay was found very temperature sensitive,being strongly accelerated by temperature increases.To compensate for excessive flow loss,a retarder like citric acid may be used.Thus flow decay was measured as a function of citric acid(retarder) addition at 35℃.     

On the inhibiting effect of phenolic compounds in the photopolymerization of acrylates under high‐intensity and polychromatic UV/visible lights

The photopolymerization of wood coatings under UV and visible light in industrial type conditions has been investigated. The inhibiting effect of the phenolic compounds found in wood extractives, especially quercetin, on the final properties of the coating (hardness, gel content) as well as the polymerization kinetics (rates, final conversion) has been discussed. Model clear‐coating formulations — based on an acrylate oligomer, a reactive diluent and a bis‐acylphosphine oxide as photo‐initiator — have been used. This article focuses on the influence of the nature of the acrylate oligomer (polyester, epoxy, polyurethane), the type of phenolic derivative (POHs) and the irradiation conditions (UV conveyor, Xe lamp). It appears that lead to through the strong inner‐filter effect in the presence of quercetin is responsible for the loss of all the observed properties. In order to mimic what happens at the wood–coating interface, the role of the diffusion of the phenolic derivatives have been also investigated and discussed. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3285–3298, 2007     

室温固化双组分水性木器涂料

一种新颖的室温固化双组分水性木器涂料与相应的单组分涂料相比,其显著特点涂膜有极好的附着力、更高的硬度、优异的耐水、耐烫、耐溶剂和抗粘连及耐污渍性等。其配漆后的适用期室温下可达30d以上,涂料的综合性能可与溶剂型漆相媲美。     

木塑复合材料的霉腐真菌危害及防霉抗菌剂的应用进展

木塑复合材料(WPCs)是近年来广泛应用的一种新型复合材料,兼有木材和高分子材料二者的优点,但同时也存在一个很大的弊端:易受霉腐真菌的危害。本文主要介绍了霉腐真菌对WPCs的危害情况及防霉抗菌剂的开发生产情况,同时简要阐述了防霉抗菌剂的发展趋势,最后指出开发防霉抗菌剂的必要性和重要性。     

恢复景德镇柴窑制瓷烧造

著名的景德镇松柴窑，简称镇窑，已属于宝贵的历史文化遗产。其建造、生产过程及烧制的瓷器，正是该文化遗产的具体内容。着重介绍这些概念和内容，说明新建个别小型柴窑，恢复其制瓷烧造，不仅可以产生很大经济效益；对保护景德镇传统陶瓷文化更具有积极的社会价值。     

Phenolic compounds from vacuum pyrolysis of wood wastes

Various softwood and hardwood bark residues, primary sludges and softwood sawdust residues were processed by vacuum pyrolysis in a laboratory scale batch reactor. The pyrolysis oil, water, charcoal, and gas were recovered and analyzed. The pyrolysis oils were analyzed in details for their content in phenolic compounds after derivatization to their acetyl derivatives. The influence of temperature, heating rate, feedstock bed thickness, particle size and feedstock water pretreatment on the yield of phenols was investigated. The highest yield of phenols was obtained when hardwood bark was soaked in water for 48 hours and pyrolyzed at a temperature of 450°C and a heating rate of 10°C/min. Pyrolysis performance was evaluated in terms of total phenolic yield and composition.     

新型栅条反应池在水处理中的应用

论述了一种新型的不锈钢栅条反应池在水处理中的应用效果。通过与传统的木网格反应池的生产性的对比试验，证明原水浊度较高时，该池反应的效果明显较好；但原水浊度较低时，没有明显优势。     

Use of organosolv lignin in phenol-formaldehyde resins for particleboard production: II. Particleboard production and properties

The objective of this work was to demonstrate the utility of lignin-based resins designed for application as an adhesive in the production of particleboard. Bond qualities of lignin-phenol-formaldehyde resins, phenolated-lignin-formaldehyde resins and commercial phenol-formaldehyde (PF-com) resin were assessed by using an automatic bonding evaluation system, prior to production of particleboards. In order to evaluate the quality of lignin-based resins, particleboards were produced and physical and mechanical properties were investigated. These physical properties included internal bond, modules of rupture and modulus of elasticity. Thickness swell and water absorption properties of particleboards bonded with lignin-based resins were also determined. The lignin-based resins have been reported previously in Part I of this study. The results showed that particleboards bonded with phenolated-lignin formaldehyde resins (up to 30% lignin content) exhibited similar physical and mechanical properties when compared to particleboards bonded with PF-com. The work has indicated that phenolated-lignin formaldehyde resins (up to 30% substitution level) can be used successfully as a wood adhesive for constructing particleboard. The performance of these panels is comparable to those of boards made using PF-com resin.     

木炭基活性炭双电层电容器的电化学性能研究

以市售木炭为原材料,采用ZnCl2-CO2联用物理化学活化法制备成活性炭材料,以此活性炭为炭电极材料,6 mol.L-1KOH为电解液,组装成硬币形双电层电容器。用恒流充放电、循环伏安等电化学方法研究实验电容器的电化学性能。结果表明,活化效果显著,能将没有电容特性的普通木炭活化成性能良好的双电层电容器电极材料,适于大电流放电,80 mA放电时质量比电容达161 F.g-1,等效串联内阻为0.4Ω,充放电效率达98%,漏电流为255μA,能量密度达5.6 W.h.Kg-1。     

Effects of compatibilizer type and rubber‐wood sawdust content on the mechanical,morphological, and thermal properties of PVC/LDPE blend

This article aimed to investigate the mechanical, morphological and thermal properties of PVC/LDPE blend with and without the addition of compatibilizers. The effects of LDPE content, compatibilizer type and rubber‐wood sawdust loading on the properties of the blend were evaluated. The experimental results suggested that as the LDPE content was increased the mechanical properties of PVC‐LDPE blend progressively decreased due to poor interfacial adhesion. The continuity and compatibility between PVC and LDPE phases could be improved through three different types of compatibilizers which included chlorinated polyethylene (CPE) poly(methyl‐methacrylate‐co‐butyl acrylate) (PA20) and poly(ethylene‐co‐methacrylate) (Elvaloy). The PA20 was found to be the most suitable compatibilizer for the blend. A radical transfer reaction was proposed in this work to explain the structure and thermal changes of the PVC in PVC‐LDPE blend. The decomposition temperature of PVC in the blend decreased with the loading of the PA20 and the wood sawdust. As the sawdust content was increased the tensile and flexural moduli increased with considerable decreased in the tensile, flexural and impact strength, a slight improvement being achieved if the PA20 was incorporated in the composite. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 598–606, 2006