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81.
82.
83.
Simulation of nitrogen dynamics and biomass production in winter wheat using the Danish simulation model DAISY 总被引:14,自引:0,他引:14
S. Hansen H. E. Jensen N. E. Nielsen H. Svendsen 《Nutrient Cycling in Agroecosystems》1991,27(2-3):245-259
A dynamic simulation model for the soil plant system is described. The model includes a number of main modules, viz., a hydrological model including a submodel for soil water dynamics, a soil temperature model, a soil nitrogen model including a submodel for soil organic matter dynamics, and a crop model including a submodel for nitrogen uptake. The soil part of the model has a one-dimensional vertical structure. The soil profile is divided into layers on the basis of physical and chemical soil characteristics. The simulation model was used to simulate soil nitrogen dynamics and biomass production in winter wheat grown at two locations at various levels of nitrogen fertilization. The simulated results were compared to experimental data including concentration of inorganic nitrogen in soil, crop yield, and nitrogen accumulated in the aboveground part of the crop. Based on this validation it is concluded that the overall performance of the model is satisfactory although some minor adjustments of the model may prove to be necessary. 相似文献
84.
Abstract. For stationary second-order autoregressive normal processes, the conjecture of uniqueness of the solution of the exact likelihood equations is examined. A sufficient condition for uniqueness is given; this condition is satisfied with very high probability if the number of observations is not extremely small. Moreover, it is shown that not more than two maxima may exist. Examples of data which actually produce a likelihood function with two local maxima are given. 相似文献
85.
Cheng-Liang Chang Hsuan Chang Yuan-Cheng Chang 《Journal of the Chinese Institute of Chemical Engineers》2007
A hybrid mathematic model for pervaporation is proposed which incorporates the concepts of solution-diffusion model and pore model. The model allows performance prediction as well as the establishment of the internal concentration and pressure profiles within the membrane. The model parameters specific to the particular membrane and mixture system are determined using liquid sorption and pervaporation experimental data. The model is experimentally examined using ethanol–water mixtures and poly(dimethyl siloxane)–poly(vinyldiene fluoride) (PDMS–PVDF) composite membranes. The characteristics of flux and separation factor predicted using the model are in fair agreement with the experimental data under various feed concentrations and downstream pressures for different membrane arrangements, including single-layer, reverse single-layer and double-layer PDMS–PVDF composite membranes. Internal profiles of pressure, concentration and component mole fraction can be established using the model. Concentration polarization phenomena for ethanol and water are located at membrane interfaces and vapor–liquid interfaces, respectively. Performances of several different membrane designs are compared using the model. 相似文献
86.
Nickel electrodes were prepared by electrodeposition in electrolytes of various anionic compositions. The deposition conditions and bath types were evaluated with special emphasis on the electrocatalytic properties for the oxygen evolution reaction (OER). Electrochemical characterizations in a 5 mol/L KOH solution at 25°C showed that the electrode deposited from the chloride bath, having a low Tafel slope of 50 mV/dec and an overpotential of 396 mV at 100 mA/cm2, is the most catalytically active among electrodes prepared in electrolytes of various anionic compositions. The electrode activity for the OER is related to the real surface areas, which depend on the anion compositions in the deposition bath and the deposition conditions. 相似文献
87.
Wei Li 《Chemical engineering science》2005,60(17):4780-4790
A mathematical model for flowthrough (perfusion) chromatography, namely packed-microtubes (PMT) model, has been proposed for a column packed with biporous (BiP) anion exchanger in which the mesopores and flowthrough pores are created with liquid and solid porogens, respectively. The model is established based on the assumption that the BiP particle is made up of packed microtubes. Bovine serum albumin (BSA) is used as a model protein and three kinds of anion exchangers (i.e., mesoporous, macroporous and BiP resins) are used as adsorbents to determine the model parameters and to evaluate the model. Adsorption equilibrium and finite bath experiments are performed to determine the adsorption isotherms and kinetics parameters. Both the bound amounts of the protein on the surface of the mesopores and macropores are experimentally determined and taken into account in the mathematical model. With all the model parameters determined by independent experiments or calculated from available correlations, model simulations are performed and compared with the experimentally determined breakthrough profiles of the BiP column. It is found that the model predictions agree reasonably well with the experimental data obtained under various conditions and the PMT model fit experimental data better than the modified double linear driving force (LLDF) model proposed by Leitão and Rodriogues (1999. Biochemical Engineering Journal 3, 131) in which the adsorbent particle is considered to be made up of packed microparticles. The results indicate that the PMT model is more reasonable for this kind of BiP adsorbent. 相似文献
88.
Transport phenomena studies on single phase “model” fluids are of limited value in biochemical engineering if they cannot be translated to the heterogeneous systems encountered in real fermentation processes. In this paper we discuss the utility of polymer solutions as models of filamentous fermentation broths for evaluation of: pipeline friction factors and impeller power numbers (turbine and helical ribbon). To a first approximation, polymer solutions can serve as suitable models for the prediction of laminar flow pressure drop in pipelines and turbulent power consumption in stirred tanks. However, results obtained on polymer solutions do not directly apply to filamentous fermentation broths for predictions of laminar flow impeller power consumption and the transition point for turbulent flow in stirred tanks. These discrepancies are believed to result from the existence of a time dependent yield stress in filamentous fermentation broths. 相似文献
89.
《Calphad》2014
Thermodynamic properties and phase diagrams of the MCl–YCl3 (M=Na, K, Rb, Cs) systems were reassessed by using the CALPHAD method with the latest phase diagram data. A two-sublattice ionic solution model (M+)P(Cl−, , YCl3)Q reflecting the ionic behavior of the components was adopted to describe the liquid phase in the systems. A new set of optimized model parameters was found, and the calculated phase diagrams and enthalpies of mixing have good agreement with experimental data. The calculated liquidus near to YCl3 side agrees much better with experimental data compared with previous work. In consideration of high and low temperature modifications as well as stability of intermediate compounds, Gibbs energies of formation of these compounds evaluated in the present work are more reasonable. 相似文献
90.
《Journal of Parallel and Distributed Computing》2014,74(6):2512-2520
Accurate age modeling, and fast, yet robust reliability sign-off emerged as mandatory constraints in Integrated Circuits (ICs) design for advanced process technology nodes. In this paper we introduce a novel method to assess and predict the circuit reliability at design time as well as at run-time. The main goal of our proposal is to allow for: (i) design time reliability optimization; (ii) fine tuning of the run-time reliability assessment infrastructure, and (iii) run-time aging assessment. To this end, we propose to select a minimum-size kernel of critical transistors and based on them to assess and predict an IC End-Of-Life (EOL) via two methods: (i) as the sum of the critical transistors end-of-life values, weighted by fixed topology-dependent coefficients, and (ii) by a Markovian framework applied to the critical transistors, which takes into account the joint effects of process, environmental, and temporal variations. The former model exploits the aging dependence on the circuit topology to enable fast run-time reliability assessment with minimum aging sensors requirements. By allowing the performance boundary to vary in time such that both remnant and nonremnant variations are encompassed, and imposing a Markovian evolution, the probabilistic model can be better fitted to various real conditions, thus enabling at design-time appropriate guardbands selection and effective aging mitigation/compensation techniques. The proposed framework has been validated for different stress conditions, under process variations and aging effects, for the ISCAS-85 c499 circuit, in PTM 45 nm technology. From the total of 1526 transistors, we obtained a kernel of 15 critical transistors, for which the set of topology dependent weights were derived. Our simulation results for 15 critical transistors kernel indicate a small approximation error (i.e., mean smaller than 15% and standard deviation smaller than 6%) for the considered circuit estimated end-of-life (EOL), when comparing to the end-of-life values obtained from Cadence simulation, which quantitatively confirm the accuracy of the IC lifetime evaluation. Moreover, as the number of critical transistors determines the area overhead, we also investigated the implications of reducing their number on the reliability assessment accuracy. When only 5 transistors are included into the critical set instead of 15, which results in a 66% area overhead reduction, the EOL estimation accuracy diminished with 18%. This indicates that area vs. accuracy trade-offs are possible, while maintaining the aging prediction accuracy within reasonable bounds. 相似文献