全文获取类型
收费全文 | 9626篇 |
免费 | 1059篇 |
国内免费 | 432篇 |
专业分类
电工技术 | 419篇 |
综合类 | 759篇 |
化学工业 | 2965篇 |
金属工艺 | 443篇 |
机械仪表 | 189篇 |
建筑科学 | 889篇 |
矿业工程 | 278篇 |
能源动力 | 291篇 |
轻工业 | 1550篇 |
水利工程 | 500篇 |
石油天然气 | 722篇 |
武器工业 | 40篇 |
无线电 | 261篇 |
一般工业技术 | 868篇 |
冶金工业 | 630篇 |
原子能技术 | 127篇 |
自动化技术 | 186篇 |
出版年
2024年 | 29篇 |
2023年 | 131篇 |
2022年 | 281篇 |
2021年 | 356篇 |
2020年 | 394篇 |
2019年 | 312篇 |
2018年 | 276篇 |
2017年 | 341篇 |
2016年 | 362篇 |
2015年 | 381篇 |
2014年 | 511篇 |
2013年 | 622篇 |
2012年 | 740篇 |
2011年 | 713篇 |
2010年 | 511篇 |
2009年 | 560篇 |
2008年 | 498篇 |
2007年 | 591篇 |
2006年 | 541篇 |
2005年 | 424篇 |
2004年 | 364篇 |
2003年 | 308篇 |
2002年 | 252篇 |
2001年 | 206篇 |
2000年 | 170篇 |
1999年 | 165篇 |
1998年 | 129篇 |
1997年 | 112篇 |
1996年 | 108篇 |
1995年 | 101篇 |
1994年 | 84篇 |
1993年 | 58篇 |
1992年 | 58篇 |
1991年 | 63篇 |
1990年 | 52篇 |
1989年 | 48篇 |
1988年 | 41篇 |
1987年 | 36篇 |
1986年 | 38篇 |
1985年 | 38篇 |
1984年 | 43篇 |
1983年 | 22篇 |
1982年 | 19篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1978年 | 4篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
42.
Rodrigo Brquez Mario Espinoza Rodrigo Ormeo 《Journal of the science of food and agriculture》1994,66(2):181-186
Total volatile basic nitrogen (TVB-N) as a measure of protein degradation and total microbial counts or stored raw mackerel (Trachurus murphy), which had been treated with chemical preservatives, were compared with the TVB-N and microbial counts of untreated fish. In unpreserved fish, decomposition of fish protein was rapid. Treatment of mackerel with acetic (1000-5000 μg kg?1), which was the most effective of the parameters studied, approximately halved the rate of increase in TVB-N compared with the untreated samples. Changes in the total microbial counts presented a similar trend. 相似文献
43.
输气管道投产置换过程气体混合规律研究 总被引:2,自引:1,他引:1
目前国内输气管道置换工艺主要依据人工经验进行,存在较大的盲目性,导致天然气管道投产成本较高,安全风险较大,有必要对输气管线安全投产工艺进行科学、系统的研究,实现输气管道的安全、高效、经济投产模式。文章讨论了现有置换工艺中不同的置换方式,认为不加隔离器的置换方法具有置换效率高、费用低以及安全可靠等优点,是一种有前途的新工艺、新方法。同时,为确保置换过程的安全性,针对置换过程中注氮量确定的盲目性问题,采用模拟试验方法,研究了天然气与氮气、氮气与空气混合段在不同流速和背压下长度的变化规律,从而为确定合理的用氮量提供了理论依据。 相似文献
44.
45.
Auguste Commeyras Hlne Collet Laurent Boiteau Jacques Taillades Odile Vandenabeele‐Trambouze Herv Cottet Jean‐Philippe Biron Raphaël Plasson Louis Mion Olivier Lagrille Herv Martin Franck Selsis Michel Dobrijevic 《Polymer International》2002,51(7):661-665
Addressing the still open question of the prebiotic origin of sequential macromolecules (peptides, nucleic acids) on the primitive Earth, we describe a molecular engine (the primary pump), which works at ambient temperature and continuously generates, elongates and complexifies sequential peptides. This new scenario is based on a cyclic reaction sequence, whose keystep is the activation of amino acids into their N‐carboxyanhydrides (NCA) through nitrosation by NOx. This process could have taken place on tidal beaches; it requires a buffered ocean, emerged land and a nitrosating atmosphere. With the help of geochemical studies and computer simulations of atmosphere photochemistry, we show that the primitive Earth during the Hadean may have satisfied all these requirements. © 2001 Society of Chemical Industry. 相似文献
46.
E. Ya. Davydov I. S. Gaponova T. V. Pokholok G. B. Pariiskii G. E. Zaikov 《应用聚合物科学杂志》2008,108(1):128-133
The features of initiation of free radical reactions in polymers by dimers of nitrogen dioxide are considered. The conversion of planar dimers into nitrosyl nitrate in the presence of amide groups of macromolecules has been revealed. Nitrosyl nitrate initiates radical reactions in oxidative primary process of electron transfer with formation of intermediate radical cations and nitric oxide. As a result of subsequent reactions, nitrogen‐containing radicals are produced. The dimer conversion has been exhibited by estimation of the oxyaminoxyl radical yield in characteristic reaction of p‐benzoquinone with nitrogen dioxide on addition of aromatic polyamide and polyvinylpyrrolidone to reacting system. The isomerization of planar dimers is efficient in their complexes with amide groups, as confirmed by ab initio calculations. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
47.
生产电子工业用高纯氮的制氮装置 ,其要点和难点是一氧化碳和氢的清除。采用一氧化碳转换炉和特殊的冷箱内流程组织 ,可以生产纯度为 99 9999%以上的高纯氮。对制取电子工业用高纯氮制氮装置与常规制氮装置加氮终端净化器两种流程进行了比较。 相似文献
48.
Frank J. Owens 《Materials Letters》2007,61(10):1997-1999
Molecular orbital calculations of the ionization potential of single wall carbon nanotubes having donor NH2 and acceptor NO2 groups bonded to the side walls and ends and boron and nitrogen substituted for carbon show substantial increases in ionization potential compared to carbon nanotubes with no functional groups and no carbon substitutions. The presence of a carbon vacancy on the side wall also causes a substantial increase in the ionization potential. The effect of tube length on the ionization energy is also calculated. The calculations also suggest that at appropriate levels of boron and nitrogen doping the armchair carbon nanotubes could be high temperature organic ferromagnetic materials. 相似文献
49.
Zakaria Chajar Michel Primet Hélène Praliaud Michèle Chevrier Catherine Gauthier Frédéric Mathis 《Catalysis Letters》1994,28(1):33-40
The role of nitrogen dioxide in the selective reduction of NO by propane over a Cu-MFI zeolite is investigated. NO2 and NO reductions were carried out under similar conditions of reaction. In the presence of oxygen, the reduction of NO by C3H8 does not differ significantly from that of NO2. In the absence of oxygen, the reduction of NO2 by propane occurs with a partial decomposition of the nitric dioxide molecule. Such a decomposition leads to the formation of oxygen, which is responsible for the increase in catalytic activity by comparison with the same reaction performed with NO. NO2 formed and released in the gas phase during the reduction of NO by propane in the presence of oxygen does not play a predominant role in the catalytic process. 相似文献
50.
R. Niebuhr K. H. Bachem U. Kaufmann M. Maier C. Merz B. Santic P. Schlotter H. Jürgensen 《Journal of Electronic Materials》1997,26(10):1127-1130
Oxygen doped GaN has been grown by metalorganic chemical vapor deposition using N2O as oxygen dopant source. The layers were deposited on 2″ sapphire substrates from trimethylgallium and especially dried
ammonia using nitrogen (N2) as carrier gas. Prior to the growth of the films, an AIN nucleation layer with a thickness of about 300? was grown using
trimethylaluminum. The films were deposited at 1085°C at a growth rate of 1.0 μm/h and showed a specular, mirrorlike surface.
Not intentionally doped layers have high resistivity (>20 kW/square). The gas phase concentration of the N2O was varied between 25 and 400 ppm with respect to the total gas volume. The doped layers were n-type with carrier concentrations
in the range of 4×1016 cm−3 to 4×1018 cm−3 as measured by Hall effect. The observed carrier concentration increased with increasing N2O concentration. Low temperature photoluminescence experiments performed on the doped layers revealed besides free A and B
exciton emission an exciton bound to a shallow donor. With increasing N2O concentration in the gas phase, the intensity of the donor bound exciton increased relative to that of the free excitons.
These observations indicate that oxygen behaves as a shallow donor in GaN. This interpretation is supported by covalent radius
and electronegativity arguments. 相似文献