碳酸化分解工艺的改进与实践

本文针对烧结法生产氧化铝过程中,铝酸钠溶液的碳酸化分解工艺,由间断分解到连续分解的改进进行了论述,指出连续分解是碳酸化分解的发展方向。     

Preparation of Compound Ultrafine CeO2 by Wet-Solid-Phase Mechanochemical Modification

To satisfy practical requirements from industrial applications, an alternate route for synthesis compound ultrafine CeO2 powders by wet-solid-phase mechanochemical modification using industrial grade hydrated cerium carbonate as raw material was proposed.The effect of modifier reaction percentage, reaction time, calcining temperature and modifier amount on particle size, density, suspensibility, and hardness of compound CeO2 powder was investigated.The phase evolutions of preparation process were characterized by XRD.SEM micrograph of the final product shows that compound CeO2 powders obtained are well-dispersed, spherically-shaped, uniformly-sized and submicron-sized particles.The method is readily available in raw material, low in cost, simple in process, and has great potential for industrialization.The compound CeO2 powders of different physical properties can be synthesized by controlling the above-mentioned influence factors in preparation process.     

高压水射流技术粉碎原盐的研究

以原盐为被粉碎研究对象,通过对高压水射流粉碎原盐形貌的观察和成分分析、高压水射流原盐粉碎性能分析,以及高压水射流粉碎原盐各影响因素的正交分析,研究表明高压水射流粉碎技术对原盐具有良好的解理性且粉碎效率高、耗能低。各因素对原盐粉碎效果的影响顺序为:射流压力卤水喷嘴直径、料液混合喷嘴直径、靶面形状。     

汽轮机轴承烧瓦与轴颈的渗巴氏合金现象

简述轴承工作性质，巴氏合金应用与相组成的基本情况。论述汽轮机转子在两个电厂长期运行后，由于轴颈发生的不正常摩擦损伤，在大修改造中由无损检查、机械加工揭示出轴颈存在严重的渗巴氏合金现象，低熔点金属Sn、Sb与Cu向转子材料晶界的深层渗入最终导致了3根大型在投转子的严重开裂与报废。图11表2     

低松装密度水雾化铜粉工艺的研究

本文研究了氧化 还原法生产铜粉的新工艺 ,该工艺是通过氧化还原将水雾化铜粉加以表面改性 ,形成海绵状的粉末 ,显著降低水雾化铜粉的松装密度 ,这种铜粉既具有电解铜粉低的松装密度 ,又具有水雾化铜粉高的流动性。讨论了氧化时间、氧化温度对铜粉松装密度的影响。本工艺是一种新型环保、节能、可替代电解法生产铜粉的先进工艺     

W-Ni-Cu高比重合金注射成形烧结收缩及性能的研究

研究了W-Ni-Cu高比重合金注射成形工艺过程收缩率和性能。比较了模具尺寸、注射坯尺寸、烧结坯尺寸，及烧结阶段各方向收缩率的关系，发现实际收缩与理论预测收缩率较为一致，但在厚度方向存在与其他方向收缩不一致的情形，这与由重力作用产生的塑料流动有关；还探讨了烧结坯密度与烧结条件的关系，测定了烧结坯的力学性能及断口形貌、金相组织，烧结坯在1400℃，90min烧结达到了99％的相对密度，断裂强度600MPa以上。     

光敏树脂及其紫外光固化涂料发展新动向

按紫外光固化涂料形态分类,并着重从光敏树脂方面综述了近年来紫外光固化涂料及其光敏研究及开发的新动向。在开发油性紫外光固化涂料新品种、提高其综合性能、拓宽应用领域的同时,研究开发水性紫外光固化涂料、紫外光固化粉沫涂料是目前紫外光固化涂料的重要发展趋向:在完善线形光敏齐聚物的同时,研究水溶性光敏齐聚物、树枝形和超支化结构聚合物体系又成为紫外光固化涂料用树脂研究的新热点。     

Slip and Twinning in Polycrystalline Alumina (α-Al2O3) Deformed under Hydrostatic Pressure between 600° and 1000°C

The microstructure of polycrystalline alumina deformed under hydrostatic pressure and at low temperature is investigated by transmission electron microscopy. Deformation occurs mainly by prism plane slip and rhombohedral twinning. Introduction of hydrogen leads to a significant decrease in the yield stress. In large grain size alumina deformed with hydrogen, accommodation of twinning involves dislocation reactions in the twin boundary and in the grains rather than by cracking. Prism plane dislocations decompose into basal dislocations by cross slip probably due to a decrease of Peierls stress for basal slip in the presence of hydrogen.     

宽流道板式换热器在氧化铝生产种子分解过程中的应用

介绍了宽流道板式换热器的结构、特点及在氧化铝生产种子分解过程中的应用。     

The interfacial microstructure of joined single crystal and polycrystalline alumina

The interfacial microstructures of 96 and 98% polycrystalline alumina joined with single crystal sapphire have been investigated in relation to the joining parameters. Joining has been evaluated based on either using a thin spin-on silica interlayer or by placing the alumina and sapphire in direct contact. The materials were joined by placing the coated or uncoated surfaces in contact and heating in the range of 1340–1475 °C with minimum external load. With the aid of a silica interlayer, sapphire and 98% polycrystalline alumina were successfully joined in 180 min at 1400 °C and above, while samples without a silica interlayer failed to join under these conditions. However, sapphire and 96% polycrystalline alumina were joined both with and without the use of silica interlayer. A variety of interfacial morphologies have been observed, including amorphous regions, fine crystalline alumina, and intimate contact between the sapphire and polycrystalline alumina.