Combinatorial materials research applied to the development of new surface coatings: II. Process capability analysis of the coating formulation workflow

A combinatorial process has been developed for the high throughput production and evaluation of surface coatings. The workflow designed for the production of arrays of liquid coatings involves the robotic transfer of aliquots of solutions of raw materials to an array of glass vials and mixing of the coatings using an unconventional magnetic stirring process. An investigation of the capability of the workflow to accurately and repeatedly prepare coating arrays was conducted as a function of solution viscosity and aliquot size. In addition, mixing capability was evaluated as a function of solution viscosity, total solution volume, and mechanism of stirring. Overall, the results of the study indicated that adequate accuracy and repeatability of the coating preparation process can be achieved as long as raw material solutions are designed such that viscosity is below about 250 cP and aliquot sizes are above about 75 μl. With regard to mixing capability, total solution volume was found to have a profound affect as did the stirring mechanism.     

缓蚀-阻垢剂的现状与发展

本文阐述了绿色化学技术在水处理缓蚀阻垢剂中的应用，综述了水处理缓蚀剂和阻垢剂及复合型缓蚀阻垢剂的现状，并概述了水处理缓蚀阻垢剂的发展方向。     

《无机及分析化学》在多媒体教学的应用及思考

对多媒体技术在无机及分析化学教学的应用进行了，阐述和分析，指出使用多媒体教学应注意的问题。     

现代量子化学在染料工业中的应用--量子化学对染料应用的研究以及相关软件的介绍

本文通过对现代量子化学发展的简介,探讨了将其应用于染料工业的可能性与优越性,并具体分析了它对染料的染色和褪色机理研究的指导作用。指出量子化学必将成为染料工作者强有力的应用工具。文章对目前常用的量子化学计算软件进行了初步介绍。     

3,5-二氨基-1,2,4-三唑的合成与表征

以80%水合肼与37%浓盐酸为起始原料得到二盐酸肼,然后在水中与二氰二胺缩合环化合成了标题化合物,收率89%,精制后纯度达到99%以上,m.p.208~210℃。合成的最佳反应条件为:温度48~50℃,反应时间2 h,二氰二胺与二盐酸肼最佳料比为1∶1.1,pH控制在10.4~10.8。并利用元素分析、红外光谱、核磁共振光谱、质谱等分析手段对其结构进行了表征。     

生物化工

从生物化工的形成、研究内容、研究现状与展望等方面介绍了生物化工。     

Microstructure and morphology of amine-cured epoxy coatings before and after outdoor exposures—An AFM study

Atomic force microscopy (AFM) has been used to study the morphology and microstructure of an amine-cured epoxy before and after outdoor exposure. Measurements were made from samples prepared in an essentially CO₂-free, H₂O-free glove box and from samples prepared in ambient conditions. For those prepared in a CO₂-free glove box, AFM imaging was conducted on (1) an unexposed air/coating surface, (2) an unexposed coating bulk, (3) an unexposed coating/substrate interface, and (4) a field exposed air/coating surface. For samples prepared in ambient conditions, only the unexposed air/coating surface was investigated. The same regions of the exposed samples were scanned periodically by the AFM to monitor changes in the surface morphology of the coating as UV exposure progressed. Small angle neutron scattering and Fourier transform infrared spectroscopy (FTIR) studies were performed to verify the microstructure and to follow chemical changes during outdoor exposure, respectively. The results have shown that amine blushing, which occurs only under ambient conditions, had a significant effect on the surface morphology and microstructure of the epoxy. The surface morphology of the samples prepared under CO₂-free, dry conditions was generally smooth and homogeneous. However, the interface and the bulk samples clearly revealed a two-phase structure consisting of bright nodular domains and dark interstitial regions, indicating an inhomogeneous microstructure. Such heterogeneous structure of the bulk was in good agreement with results obtained by small angle neutron scattering of unexposed samples and by AFM phase imaging of the degraded sample surface. The relationship between submicrometer physical changes and molecular chemical degradation is discussed. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004, in Chicago, IL.     

应用化学专业实践教学模式初探

介绍了以江西农业大学理学院基础化学实验室为基础,以2002级应化专业学生为对象,以培养具有“基础扎实、知识面广、能力强、素质高”的优秀化学人才为目标,改革应用化学专业实践教学内容和方法,改善实验条件.     

国外过氧化氢在化学合成中应用研究进展

介绍了近期国外过氧化氢在部分化学品合成中应用研究新进展 ,产品包括过碳酸钠、过碳酰胺、4Na2 SO4·2H2 O2 ·NaCl加合物、叔胺氧化物、水合肼、二羟基苯、季铵盐过氧化氢和甲乙酮肟。内容涉及产品质量 (纯度、安定性、溶解速率、外观等 )、产品收率、催化剂、工艺过程等方面改进。主要介绍专利技术。     

Novel approaches to developing carbon nanotube based polymer composites: fundamental studies and nanotech applications

The adsorption of several types of conducting polymers on carbon nanotubes is investigated by electrical transport measurements. We report the optoelectronic properties occurring in single-walled carbon nanotubes (SWNTs) conjugated polymer, poly(3-octylthiophene), composites. Al/polymer-nanotube composite/indium-tin oxide diodes show photovoltaic behavior proposing that the main reason for this increase is the photoinduced electron transfer at the polymer/nanotube interface. Interesting results were obtained in the case of poly(o-anisidine) (POAS)-multi-walled nanotubes (MWNTs) composites where the increment of monolayers results in a significant improvement of the specific conductivity. POAS-coated MWNTs thin films demonstrated their potentiality as a new class of materials for inorganic vapors detection for environmental applications.