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91.
新一代高活性,高水热稳定性3961(PS-Ⅳ)型连续重整催化剂于1996年在上海石化芳烃厂400kt/a连续重整装置上首次进行工业应用试验。开工5a,催化剂跟踪分析结果表明,该剂保持了良好的物化性质和反应性能,表现为良好的比表面积稳定性和持氯能力,经过200个以上再生周期的催化剂未发现有明显的相变和金属分散度的变化。 相似文献
92.
93.
We modeled nisin's anticlostridial activity and assessed the antagonistic or potentiating influences of food ingredients. The model systems contained yeast extract, proteose peptone, and glucose; were supplemented with protein (0.075, 0.75, 7.5% w/v), phospholipid (0.075, 0.75, 7.5% w/v), or soluble starch (5, 17.5, 30% w/v); and were adjusted to pH 5.5, 6.0, or 6.5. Samples inoculated with 104/mL spores were incubated at 15, 25, or 35°C. Statistical analysis developed an equation (r2= 0.76) that modeled the response and identified temperature as the most significant (α 0.001) variable. Nisin lost effectiveness with increasing temperature. Nisin concentration had significant positive and phospholipid negative, linear effects. Many interactive effects were significant (α 0.20). Nisin inhibited C. botulinum until its residual level dropped below a threshold, which decreased from 154 IU/mL at 35°C to 12 IU/mL at 15°C. 相似文献
94.
大型焦炉计算机优化控制系统 总被引:7,自引:2,他引:5
本文介绍一个大型焦炉计算机优化控制系统,它不仅实现了燃烧系统的DDC控制,而且完成了结焦终点的在线预报和以焦炉能耗最小为目标的优化控制。 相似文献
95.
Adsorption and inhibitive properties of benzimidazole derivatives in acid mild steel corrosion 总被引:1,自引:0,他引:1
Eight diazoles were investigated as corrosion inhibitors of mild steel in 1 M hydrochloric acid using gravimetric and polarization techniques. It was found that the inhibition efficiency increased with the increase of organic substrate concentration, while the adsorption followed the Frumkin isotherm. A correlation between the electronic parameters (induction and mesomeric effects of the substituents, ionization potential values) as well as those of the chemical structure (molecular area) of diazoles molecules and their inhibiting properties was looked for. The results obtained show that a definite interdependence exists but it is not as simple and straightforward as might be expected. 相似文献
96.
The primary problem in concentrating phosphoric acid is due to fouling on the tube‐side of the heat exchangers of the evaporator units. Scaling on the heat transfer surfaces occurs because of high supersaturation of phosphoric acid liquor with respect to calcium sulphate. A review of the existing literature reveals that no information is available on heat transfer and on crystallization fouling of industrial phosphoric acid solutions. In this investigation, the solubility of different calcium sulphate types in phosphoric acid solution was studied and its dependency on acid concentration and temperature was investigated. A large number of fouling experiments were carried out in a side‐stream of a phosphoric acid plant at different flow velocities, surface temperatures and concentrations to determine the mechanisms, which control the deposition process. After identifying the effects of operational parameters on the deposition process, a model was developed for prediction of fouling resistances. The reaction of calcium sulphate crystallization followed a second order rate with respect to the supersaturation. The activation energy evaluated for the surface reaction of the deposit formation was found to be 57 kJ/mol. The predicted fouling resistances were compared with the experimental data. Quantitative and qualitative agreement between measured and predicted fouling rates is good. 相似文献
97.
98.
FCC待生催化剂多级组合式汽提器的开发 总被引:1,自引:0,他引:1
从冷模试验入手,以提高汽提器汽提效率为目标,开发了催化裂化沉降器待生催化剂多级组合式结构汽提器.该技术在着眼于加大汽固接触面积、提高汽固接触效率的同时,在汽提器内用间隔距离较大的挡板实现多级串联式汽提,以减小各区内汽固的返混程度,提高传质效率,从而提高汽提效率.冷模试验研究对比结果表明,新开发的汽提器汽提效率较普通环形挡板式汽提器汽提效率提高10百分点以上.在济南分公司重油催化裂化装置的工业应用结果表明,投用新汽提器后,焦炭中氢质量分数为6%~7%,降低了18.3%,焦炭产率下降0.5百分点. 相似文献
99.
盐家油田油水井结垢原因探讨 总被引:2,自引:0,他引:2
对地层温度65~75℃的盐家油田油水井近井地带、井底、井筒发生严重结垢的原因进行了分析探讨。7口油井采出的地层水均为NaCO3型水.矿化度6.4~10g/L,HCO3浓度高(1.6~3.7g/L),Ca^2++Mg^2+浓度较低;1口水源井水及1口水井注入水为CaCl2型水,矿化度32~33g/L,Ca^2++Mg^2+浓度高(3.1~3.8g/L)而HCO3浓度低;采用CaCO3饱和指数法和CaSO4热力学溶解度法预测,在70℃下所有水样均有CaCO3结垢趋势,除3口油井采出的地层水外,均有CaSO4结垢趋势。3口油井采出的地层水与水源水在25℃按不同比例混合后,悬浮物含量大幅度上升。在70℃放置7天后再次大幅度上升,烘干的悬浮物易溶于稀盐酸.其主要成分为碳酸盐.说明注入水、地层水不配伍。1口电泵采油井和1口注水井油管垢样含盐酸可溶物(碳酸盐)超过90%。讨论了碳酸盐、硫酸盐垢的生成条件:温度、压力及pH值。图1表4参3。 相似文献
100.
Although comparative judgment methods have a number of distinct advantages over ratings, they share one common problem: On the basis of comparative judgments, it is not possible to recover the origin of item evaluations. One item may be judged more positively than another, but this result does not allow any conclusions about whether either of the items are attractive or unattractive. This article discusses the implications of this limitation for the interpretation of individual differences in comparative judgments. It also presents 3 different methods that may allow determination of the scale origin using a nested model comparison approach. An application illustrates the proposed approach as well as the benefits of determining the scale origin in understanding value judgments. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献