新型光解水制氢用半导体光催化材料的研究进展

综述了钛酸盐、钽酸盐和铌酸盐为主的层状钙钛矿型光催化材料,简述了层状钙钛矿型光催化剂光解水的机理,比较了各种层状钙钛矿型结构材料的催化活性,分析了影响活性的原因,并对层状钙钛矿型结构光催化材料的研究和应用提出了一些自己的观点.     

功率合成与分配网络的混合模式 S参数分析方法

文中应用混合模式S参数分析了功率合成／分配网络，给出了网络的单端S参数与混合模式S参数之间相互转化的关系式。最后在测量单端S参数的基础上给出了混合模式S参数的曲线，其与理论分析的结果具有较好的一致性。     

大理岩抗拉强度的离散性及与厚度的关系

大理岩劈裂抗拉强度具有较大的离散性,并受非均质性、劈裂形式及尺寸效应等多种因素影响.采用钢丝垫条形式的大理岩劈裂抗拉强度离散度小于采用钢平板形式的离散度;大理岩劈裂抗拉强度值越高,其离散度越小;采用钢丝垫条形式的劈裂抗拉强度在总趋势上随厚度的增加先增加后减小;而采用平板形式的劈裂抗拉强度随厚度的增加而减小.     

电力系统状态估计可观测性分析中关于量测岛合并的理论分析

分析了电网量测岛的特点和可观测性的概念。在此基础上，根据电路理论中的两个基本性质，得出了量测岛内最多只含一个复电压未知状态量的基本结论，并由此给出了量测岛间合并的理论依据。出了简化网络分析的目的，提出了内网等值和节点分裂这两个合并分析时的基本处理手段，为新的可观测性拓扑算法的提出做了理论上的准备，文中所提量测岛合并的理论依据得到了实际系统的验证。     

R2Fe17Mx化合物的磁性研究

用自旋极化的ＭＳ－Ｘα方法计算了Ｎｄ２Ｆｅ１７Ｎｘ（ｘ＝０，３）化合物中含哑铃Ｆｅ原子对的Ｆｅ８及含Ｎｄ原子的ＮｄＦｅ６原子簇的电子结构和磁矩。计算结果显示，Ｎｄ２Ｆｅ１７化合物在Ｆｅ（ｃ）和Ｆｅ（ｆ）间的分子轨道中，有三个奇宇称轨道呈现负交换耦合。通过比较α－Ｆｅ的ＭＳ－Ｘａ计算结果能够箐好地说明Ｒ２Ｆｅ１７化合物居里温度较低的原因。在化合物Ｎｄ２Ｆｅ１７Ｎ３中Ｆｅ（ｃ）－Ｆｅ（ｆ）间分子轨道只     

应用聚类有效性函数指导数据分类算法的研究

研究了应用聚类有效性函数指导数据分类的算法,指出文[6]中算法的不足并对其进行了修改。实验结果表明,修改后的算法是可行的。     

一个改进的欺骗识别协议

在(m,n)门限方案中,如果有欺骗者提供错误的分享秘密,那么重构共享秘密的过程将失败。欺骗识别协议使得诚实的用户在重构共享秘密时能够发现欺骗行为,并找出欺骗者。在目前已经提出的多个欺骗识别协议中,Wu-Wu协议是一个比较常用,步骤比较简单的协议,其安全性依赖于一个单向hash函数。通过在Wu-Wu协议的基础上引入离散对数,增加随机参数,设计了一个新的欺骗识别协议,该协议在安全强度、抵抗重放攻击、可重用性三方面对Wu-Wu协议有了实质的改进。     

Investigation on a spectral splitting photovoltaic/thermal hybrid system based on polypyrrole nanofluid: Preliminary test

The present work developed a spectral splitting hybrid photovoltaic/thermal (PV/T) system based on polypyrrole nanofluid. This hybrid PV/T system can overcome the limitation of temperature in traditional PV/T, and achieve a high-temperature thermal output. In this system, the polypyrrole nanofluid employed in the spectral splitting filter can absorb the solar radiation that can't be efficiently utilized by PV cell unit, and convert it into medium-temperature thermal energy. The principle and methodology of the experimental system design was discussed, and the effect of particle concentration on the performance of system was investigated as well. The present work not only verifies the application potential of polypyrrole nanofluid in spectral splitting PV/T system, but also obtains some important rules on the performance. The results indicate that the temperature of nanofluid and the PV efficiency of cell unit itself increases with the particle concentration, but the thermal efficiency decreases simultaneously. The maximum overall efficiency of this hybrid PV/T system with polypyrrole nanofluid filter was 25.2%, which was 13.3% higher than that without filter. More importantly, the medium-temperature thermal energy can be harvested in such a hybrid system. Furthermore, an optimal particle concentration can probably realize a higher overall efficiency.     

Photoelectrochemical water oxidation of LaTaON2 under visible-light irradiation

Lanthanum tantalum oxynitride (LaTaON₂) powders were prepared by one-step flux method. LaTaON₂ photoanodes, which are fabricated by using LaTaON₂ powders, are found to exhibit photoelectrochemical activity for overall water splitting. The photocurrent for LaTaON₂ photoelectrodes was ca. 120 μA cm⁻² at 1.5 V vs. reversible hydrogen electrode (RHE) in 1 M NaOH aqueous solutions (pH = 13.6) under AM 1.5 G simulated sunlight irradiation (100 mW cm⁻²). The photocurrent of LaTaON₂ photoelectrode from back-side illumination is much larger than that from front-side illumination, suggesting that the photoelectrochemical property is mainly limited by poor continuous electron transport in the bulk. Further efforts to ameliorate the electron transport in the bulk of LaTaON₂ photoelectrodes are expected to significantly improve their photoelectrochemical performance.     

Impact of hydrogen generated by splitting water with nano-silicon and nano-aluminum on diesel engine performance

Efficient utilization of hydrogen generated during the reactions of nano-silicon/water and nano-aluminum/water in internal combustion engine has been investigated in the current work. Engine performance and emission studies of formulated and stabilized nanoemulsion fuels (water in diesel W/D), nano-aluminum in water/diesel (W/DA) and water in nano-silicon/diesel (W/DS) have been compared with those of diesel. Experimental investigations showed reduction in brake specific fuel consumption (BSFC) by 21% and 37%; rise in brake thermal efficiency (BTE) by 16% and 14% when engine was fueled with W/DA and W/DS respectively. For nanoemulsion fuels an increase in induced power was also recorded. Brake mean effective pressure, BTE and NOx emission dropped for W/D due to reduced exhaust gas temperatures. Nevertheless due to elevated peak cylinder pressures and exhaust gas temperatures a marginal rise in NOx, CO, HC and radiative heat emissions was observed with W/DA and W/DS.