Prediction of liquid–liquid phase diagrams of aqueous salt+PEG systems using a thermodynamic model

In this study a thermodynamic model for the phase behavior of aqueous salt+polymer solutions is developed. The model is based on the solution theory of Hill, which included scaling laws for the polymer molecular mass dependence and Pitzer–Debye–Hückel theory. This model was tested for systems composed of two different molecular mass of polyethylene glycols (PEG) and five different inorganic salts. All the model parameters were determined from independent measurements. The agreement between the experimental and predicted phase diagrams by this model is good.     

落脚河水电站引水发电系统的调节保证计算分析

水轮发电机组在运行中遇到启动、正常停机、增减负荷、事故甩负荷等工况变化时，经常会引起引水发电系统的水力过渡过程，所以在设计中必须通过调节保证计算以选择合适的导叶调节规律及其调节时间，从而优化压力引水系统的运行工况，使水电站的水工建筑物布置既经济合理又安全可靠。     

石油钻机提升系统穿绳方法研究

目前国内外钻机大绳一般采用顺穿法或花穿法。分析了2种穿绳方法的受力特点,大绳顺穿时游车的受力不平衡,会发生倾斜和摆动;采用大绳花穿方法,避免了游车的倾斜和摆动,但造成大绳入轮槽的倾角大,大绳易脱槽。顺穿法一般在电动钻机上采用,主要考虑到电控操作提升系统比较平稳;花穿法一般在机械钻机上使用,以受力平衡来缓解气控操作带来的冲击载荷的影响。为了克服这2种穿绳方法的不足,提出了两行双联滑轮组顺穿法和双联滑轮组顺穿法,可以提高安全性,减少磨损。     

闸门自动启闭控制系统在冯家山水库的建设与运用

经过两年多的努力,冯家山水库闸门自动启闭控制系统于2006年3月建成.初步投入运用后,该系统在精确度、安全性、可靠性等方面均取得了较好的效果,值得类似水库自动化建设时参考.     

高压加氢工艺生产冷冻机油研究

克拉玛依具有丰富的环烷基原油资源，为研制适合国际市场需要的冷冻机油产品，在实验室中，参照德国DIN51503VG46冷冻机油标准，以克拉玛依环烷基原油减二线馏分油为原料，利用国产加氢精制催化剂RN-1、临氢降凝催化剂RDW-1，在100mL小型加氢实验装置上，采用高压加氢精制-高压加氢降凝-分馏切割工艺路线开展工艺研究，目标产品收率高，经检测分析产品质量好，各项指标均可满足德国DIN51503 VG46冷冻机油标准要求。     

Corrosion protection of iron by polypyrrole coatings electrosynthesised from a surfactant solution

This work is a study of the electropolymerisation of pyrrole onto iron electrodes in the presence of sodium bis(2-ethylhexyl) sulfosuccinate in a wide pH interval. The characterisation of the films was done using electrochemical techniques, SEM/EDX and IR spectroscopy. We show that it is possible to synthesise homogeneous, adherent and very compact films in the pH range between 7 and 12 under potentiodynamic, galvanostatic and potentiostatic conditions without substrate dissolution. The effects of various parameters on electrodeposition were investigated. The new procedure for the electrochemical synthesis of polypyrrole results in improved anticorrosion properties. The inhibition is proposed to be due to the sum of a repulsion of chloride ions because AOT remains entrapped in the polymer matrix and the presence of the iron oxide. Advantages of the use of surfactants in the electropolymerisation solution are discussed.     

Effect of cationic surfactant and inorganic anions on the electrochemical behavior of carbon steel in formation water

Corrosion behavior of carbon steel in formation water associated crude oil from Egyptian western desert was studied at various concentrations of dodecyl dimethyl ammonium chloride (CS) as a cationic surfactant. Polarization curves indicate that CS has a good inhibition efficiency for carbon steel in formation water and behaves as cathodic inhibitor. The inhibition efficiency was found to increase with increase in CS concentration until reaches a maximum constant value corresponding to the critical micelle concentration of CS and decrease with increase in solution temperature. The adsorption of CS follows the kinetic thermodynamic model and Flory-Huggins isotherm. Thermodynamic parameters obtained indicate that that the presence of the CS increases the activation energy. Polarization and Impedance measurements indicate that the addition of KI has a significant synergistic effect with CS and results in increase the inhibition efficiency of CS in formation water.     

PIII treatment of Ti alloys and NiTi for medical applications

PIII is a powerful method to obtain hard and wear resistant surface on Ti alloys and NiTi by oxygen or nitrogen implantation. By adjusting the temperature, treatment time and heating regime, different phase compositions and layer thickness can be obtained. Depending on the specific system, a strong influence of the resulting microstructure on the wear and fatigue properties was observed. By considering these restrictions, successful animal tests can be designed and executed, as shown in this review article.     

有机发光显示的几项新技术

有机发光显示(OLED)作为下一代显示器倍受关注。本文简要介绍OLED显示器的几项新技术和制作方法，以及其研究现状和今后的发展趋势。     

Synthesis of red-luminescent Eu-doped lanthanides compounds hollow spheres

Eu³⁺-doped Y₂O₃, YOF, La₂O₃, LaOF hollow spheres have been synthesized by a facile template route. Eu³⁺ were doped into the various host materials to make the hollow sphere red-luminescent. Difference in fluorescence spectra recorded on the hollow spheres were compared in detail and attributed to the different crystal symmetry of host materials. These phosphors might find applications in the fields such as light phosphor powders, advanced flat panel display, or biological labeling.