甲烷无氧芳构化研究进展及其工业应用前景

综述了最近20多年来甲烷无氧芳构化催化剂的制备、积炭失活和再生方面的研究进展，特别分析了催化剂再生过程的工程化问题及反应器型式；还根据甲烷芳构化技术产业化的需要，分析了甲烷芳构化技术的发展趋势。     

正确选择气顶油藏高效开发模式

通过对不同类型气顶油藏的油气水分布特征及气顶和边水能量的研究分析，计算水侵量与边水体积及合理的弹性产率。提出适合气顶油藏特点的开发模式是先开采油区后开采气顶，并以唐家河油田港深18—2断块为例，证明采用该模式可以高效开发气顶油藏。图3表1参6     

天然气井井筒及井口安全技术研究

天然气勘探开发具有高温、高压、高风险,安全技术及管理难度大等特点,通过实例分析天然气井存在的主要问题,提出应采取的关键安全技术及需要解决的问题。     

山区长输气管线的曲线测设

该文介绍了在山区长输气管线测量中 ,管线的折点桩之间大部分不通视且部分点上空有障碍物 ,采用GPS不能施测坐标时 ,结合山区的自然地理条件 ,采用全站仪间接施测折点水平角 ,极坐标法测设曲线以及跨越障碍物测设曲线的内容和方法 ,可在一定精度要求下应用     

天然气中甲烷和乙烷直接转化制乙烯

天然气中的甲烷和乙烷可以同时在Ｎａ２ＷＯ４－Ｍｎ／ＳｉＯ２催化剂上得到活化生成乙烯。在甲烷转化率为２０％时，原料甲烷氧化偶联反应生成Ｃ２＋的选择性为～８０％，原料乙烷反应的转化率为～８５％，选择性为～７０％。     

带隔板底水油藏油井临界产量计算公式

本给出了带隔板底水油藏油井的监界产量计算公式，它适用于所有带隔板底水油藏的油井。     

微生物烟气脱硫技术及其研究方向

微生物烟气脱硫 ,是用含有脱硫菌的溶液作循环吸收液、以粉煤灰中Fe2 O3被离子化后产生的铁离子作催化剂和反应介质、以脱除烟气中SO2 的一项新技术 .从能源、酸度、温度、需氧类型等方面综合考虑 ,氧化亚铁硫杆菌、氧化硫硫杆菌、氧化亚铁硫螺菌可作为三层滤料生物滤池脱硫的菌种 .而选育适宜性和稳定性更强、使用寿命更长的高效菌和合适的生化反应器 ,是脱硫菌种研究的趋势 .     

气体引射器流体动力特性实验研究

在实验装置上对气体引射器计算基本公式进行了实测验证，分析了理论特性曲线的可信度。通过实验，获得一些参数对引射器工况的影响规律。     

Nitric oxide reduction and carbon monoxide oxidation over carbon-supported copper-chromium catalysts

Carbon supported copper-chromium catalysts are shown to be very active for both the reduction of nitric oxide with carbon monoxide and the oxidation of carbon monoxide with oxygen. Mixed copper-chromium oxide active phases have good activity in the simultaneous removal of nitric oxide and carbon monoxide from exhaust gases. The influence of several catalyst variables has been investigated. The activity per volume of catalyst increases with increasing loading, while the intrinsic activity shows a maximum around C/M=100−50. An optimum catalyst for nitric oxide reduction and carbon monoxide oxidation has a copper/chromium ratio of 2/1. The apparent activation energy for the carbon monoxide oxidation over carbon supported copper-chromium catalysts is 77 kJ/mol, suggesting that the Cu---O bond rupture is the rate-limiting process. The reduction of nitric oxide takes place at higher temperatures. Since all catalysts have a low selectivity for molecular nitrogen formation at lower temperatures, the dissociation of nitric oxide is probably rate determining, resulting in a slightly reduced catalyst system. In an excess of carbon monoxide the reaction is first-order in nitric oxide and zero-order in carbon monoxide. Moisture inhibits the reaction by reversible competitive adsorption, whereas carbon dioxide does not. Oxygen completely inhibits the reduction of nitric oxide due to the more rapid reoxidation of the catalytic sites compared to nitric oxide. Therefore, the reduction of nitric oxide takes place only when all oxygen has been converted and, hence, is shifted to higher temperatures. As a possible consequence, the production of nitrous oxide is reduced. Nitric oxide and molecular oxygen react preferentially with carbon monoxide, so, in an excess of oxidizing component, gasification of the carbon support occurs at higher temperatures after carbon monoxide has been completely consumed.     

二氧化碳增油技术在孤岛油田的应用

介绍了二氧化碳增油机理和二氧化碳增油技术在孤岛油田的应用情况。现场应用表明 ,二氧化碳非混相驱油是封闭小断块油田的有效增产措施 ,二氧化碳酸化 (压裂 )助排能起到缩短排液时间 ,保护油气层的作用