无线无源声表面波传感器研究进展

声表面波（SAW）传感器是一种无线无源传感器,在无源传感、适应恶劣环境等许多方面具有普通传感器不能实现的优点.阐述了声表面波器件的原理和结构特点,并对射频信号收发、信息处理等关键技术进行详细论述,综述了近些年国内外的相关研究现状,并进行了总结与展望.     

聚氯乙烯(PVC)共混合金──(Ⅰ)聚氯乙烯(PVC)基础知识

本讲主要介绍聚氯乙烯（PVC）的基础知识，如PVC发展史、生产情况、型号、性能、用途及改性的必要性等，使读者对PVC的基本情况有一个大概的了解。     

Electrochemical anticorrosion performance evaluation of Al2O3 coatings deposited by MOCVD on an industrial brass substrate

Alumina (Al₂O₃) coatings of different thickness were deposited on OT59 brass substrate (BS) using the metal organic chemical vapour deposition (MOCVD) technique to evaluate the corrosion performance by EIS measurements. The used precursor was dimethyl-aluminium-isopropoxide. Electrochemical characterizations of the deposited films were performed in a standard very aggressive acidic solution (aerated 1N H₂SO₄ at 25 °C up to 168 h of immersion time) by means of direct current method (Tafel curves) and electrochemical impedance spectroscopy (EIS). The Rutherford backscattering spectroscopy (RBS) indicated that the films are very pure with the correct Al₂O₃ stoichiometry, while the IR absorption spectra showed that the films did not contain any OH groups. The surface film morphology was investigated by atomic force microscopy (AFM) and displayed a globular texture. The films were very smooth, with a maximum root mean square roughness, for example, of 14 nm for a 0.96 μm thick coating. The EIS data confirmed, as expected, that a 2.40 μm Al₂O₃ layer ensures the best corrosion protection after 168 h of immersion in the very acidic environment used.     

Preparation of new poly(amide–imide)s with chiral architectures via direct polyamidation reaction

N‐trimellitylimido‐L ‐methionine ( 3 ) was prepared by reaction of trimellitic anhydride ( 1 ) with ‐L ‐methionine ( 2 ) in acetic acid solution at refluxing temperature. This diacid was reacted with thionyl chloride, and N‐trimellitylimido‐L ‐methionine diacid chloride ( 4 ) was obtained in quantitative yield. The resulting diacid chloride was reacted with p‐aminobenzoic acid in dry acetone and bis(p‐aminobenzoic acid)‐N‐trimellitylimido‐L ‐methionine ( 5 ) was obtained as a novel optically active amide–imide diacid monomer in high yield. The direct polycondensation of amide–imide diacid monomer 5 with several aromatic diamines was carried out with tosyl chloride (TsCl)/pyridine (Py)/dimetheylformamide (DMF) system. The resulting thermally stable poly(amide–imide)s (PAIs) were obtained in good yields and inherent viscosities ranging between 0.24 and 0.46 dL g^?1 and were characterized with FTIR, ¹H NMR, CHN, and TGA techniques. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1248–1254, 2007     

Synthesis, morphology and photophysics of novel hybrid organic-inorganic polyhedral oligomeric silsesquioxane-tethered poly(fluorenyleneethynylene)s

A series of novel hybrid organic-inorganic light-emitting materials, polyhedral oligomeric silsesquioxane-tethered poly(fluorenyleneethynylene)s, were successfully synthesized via Sonagashira coupling reaction. The chemical structures of these copolymers were determined by ¹H NMR and FT-IR spectra. The morphologies of these copolymers were studied in details using TEM and WAXD. The WAXD data showed that POSS formed aggregation instead of crystallization in the polymer matrix, indicating the significant effect of the backbone constraint on POSS crystallization. Furthermore, it also revealed that the interchain interaction weakened and the interchain distance increased after introducing POSS groups. The TEM data indicated that POSS aggregates were well dispersed in polymer matrix. In accordance with the morphological investigation, the results of UV-vis absorption and photoluminescence emission spectra of these copolymers showed that the tendency toward planar conformation of conjugated backbones reduced to a certain extent due to weakened interchain interaction. Accordingly, these copolymers exhibited the enhanced quantum yields in the solid state. In addition, owing to the thermal and oxygen stability of hybrid POSS, the thermal spectral stability of these polymers was also improved greatly.     

改进的GrabCut方法在舌诊系统中的应用

数字舌象图片的正确分割是实现计算机中医舌诊自动化系统的重要前提,为了高效而准确地分割出舌象,提出了一种基于四叉树与GrabCut的舌象分割方法.该方法首先利用四叉树分解对采集的舌象初分割,然后用相似区域的颜色均值优化GrabCut算法中高斯混合模型参数,最终完成舌象分割.实验结果表明：该算法使得舌象分割效率大大提高,具有很好的实用性.     

一种集中式水下无线传感器网跨层调度协议

分析了水下无线传感器网络（WSNs）中单链路发射功率和距离与频率的关系,提出一种跨层的集中式调度方法,AP（access point）在网络中通过广播信标的形式收集估计各节点的时延和距离信息,在MAC层考虑水下链路延迟特点,对各链路进行调度减少冲突;节点在物理层通过自适应地改变节点发射功率和发射频率,减少能耗.仿真结果表明：所提方案在节省系统能量消耗的同时,能够减少碰撞,提高系统吞吐量.     

莫达非尼的绿色化学合成

采用[bm im]BF4离子液体作为反应溶剂,以二苯甲硫醇为原料,经醚化、氨解、氧化得到新型提神醒脑药物莫达非尼。讨论了不同的氯乙酸酯和反应温度对醚化反应收率的影响,讨论了不同的二苯甲硫乙酸酯对氨解反应收率的影响,及离子液体的回收使用。研究表明,采用氯乙酸甲酯作为醚化试剂,反应时间4 h,反应温度100℃,二苯甲硫醇∶氯乙酸甲酯=1∶1.5(摩尔比),室温下氨解反应20 h,二苯甲硫乙酰胺收率76%;采用过氧化氢作为氧化试剂,反应时间3 h,反应温度60℃,过氧化氢∶二苯甲硫乙酰胺=1∶1(摩尔比),莫达非尼收率79%,反应总收率可达48%。     

过氧化物DCP母料的研制

研究了采用过氧化物DCP、将DCP制成母料、在DCP母料中加入分散剂、在加入分散剂的母料中再加入助交联剂MAH(顺丁烯二酸酐)这4种条件下LDPE的交联情况，讨论了DCP的加入量对LDPE交联度的影响，同时讨论了交联度随交联时间的变化。     

小磷酸生产新进展

分析我国小磷酸装置存在的问题,介绍解决这些问题行之有效的方法:磷矿均化,配矿使用;采用ZL型真空冷却装置移走反应热提高装置能力;以及在设备、机泵、流量自调方面的技术进展。对小磷酸技改规模及生产工艺控制要点与适宜条件提出建议。