Surface designing of polypropylene by critical monitoring of the grafting conditions

The grafting of acrylic acid onto electron beam‐irradiated polypropylene was carried out using preirradiation method. The stability of peroxy radicals was investigated by electron spin resonance. It was found that the decay of peroxy radicals is much faster at 70°C than at 40°C and ambient temperature. The grafting has been observed to be strongly dependent on the monomer dilution in the reaction medium. The grafting was ascertained by attenuated total reflectance (ATR). The distribution of grafts across the samples was monitored by infrared microscopy. It was found that the graft management is considerably influenced by composition of the grafting medium. The grafting involving pure monomer leads to the surface enrichment with the polyacrylic acid chains. The samples grafted in pure monomer led to much lower contact angles as compared to the diluted monomer solution. The swelling of the grafted samples also showed a trend that was governed by the graft management. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 546–553, 2006     

基于"替换法"的汉字加、解密实现技术

文章讨论的基于“替换法”的汉字信息加、解密实现技术,改变了传统的汉字加密结果,使加密后的密文仍是可以识别和再利用的汉字,发送者可以在任何可编辑汉字的通讯设备上发送和接收密文,确保中文信息传输过程中的安全性。加、解密算法实现的代码语言为VFP6.0。     

红外目标模拟器校准系统的研制与应用

采用标准辐射和红外目标模拟器的辐射交替折转进入红外光谱辐射计的方法，研制的红外目标模拟器校准系统可以对红外目标模拟器进行直接校准．该系统由标准准直辐射源，光束偏转装置和红外光谱辐射计组成．标准准直辐射源由工作温度为50℃～1050℃的标准黑体和口径300mm的离轴抛物面作主镜的准直光管组成．光束偏转装置由口径465mm的反射镜和定位精度5″的转台组成．红外光谱辐射计采用圆形渐变滤光片CVF对入射的辐射分光，3个光谱工作区间为1μm～3μm，3μm～5μm和8μm～14μm。3个区间的测试数据显示了最小可校准的光谱辐照度低于10^-11／cm^2，系统的相对标准不确定度为2％．     

红外干扰弹及其发展

叙述了红外干扰弹在现代高科技战争中的地位，介绍了红外干扰弹的类型及其关键技术，提出了红外干扰弹的发展方向．     

一种基于自然数线性八叉树的优化构造算法

本文提出了一种基于自然数线性八叉树的优化构造算法。该算法以活动结点表为中间辅助结构，在图像输入过程中直接生成基于Ｎ码的八叉树叶结点．与常规构造算法相比，新提出的优化构造算法省去了Ｎ码的计算及合并过程，从而具有较高的时空效率．     

UO_2(HCOO)_2·H_2O在290K-10K的红外光谱及~(235)U-~(238)U同位素位移的研究

本文通过测定甲酸铀酰[UO_2(HCOO)_2·H_2O]在290K-10K的红外光谱,确定了该化合物铀酰基团(O-U-O)v_(as)振动峰位,研究了温度对峰宽、峰位的影响,并采用差减及峰内标法估算了甲酸铀酰在290K-10K的同位素位移值。测得290K,77K及10K时~(238)U的v_(as)值分别为931.90cm~(-1),930.82cm~(-1)和930.74cm~(-1),~(235)U-~(238)U同位素位移△v分别为0.63cm~(-1),0.67±0.18cm~(-1)和0.71±0.21cm~(-1),位移值与理论计算值接近。     

Control of polymerization processes of 10,12-pentacosadiynoic acid LB films

Studies have been carried out on KrF excimer laser light (EX), X-ray or electron beam (EB) induced polymerization of 10,12-pentacosadiynoic acid (PDA) Langmuir-Blodgett (LB) films in relation to molecular density or molecular arrangement of the films using X-ray diffraction analysis, infrared (IR) spectroscopy and Raman spectroscopy. The molecular arrangement or density of the PDA LB films was controlled by subphase conditions when the films were built up, such as pH, temperature of a subphase or salt concentration in the subphase. Polymerization sensitivity of the PDA LB film was affected by the arrangement or molecular density. On low density (A type) films the polymerization occurred by irradiation with EX, X-ray or EB, but on high density (B type) films the polymerization occurred only when the irradiation was carried out by high energy beams such as X-ray or EB. Decomposition of polymerized films was observed further by excessive irradiation of EX or X-ray, but not on the B type films. It was revealed by X-ray diffraction analysis that in the A type film, the PDA molecules bent to a larger extent than those in the B type film and the polymerization proceeded topochemically, that is, the thickness decreased little after EB irradiation in a helium atmosphere. On the other hand, in the B type film, the thickness decreased by about 10% as a result of EB irradiation. By IR reflection-absorption (RA) and Raman measurements, it was confirmed that conjugated diacetylenic bonds disappeared and conjugated double and new conjugated triple bonds appeared after high energy beam irradiations. These results support the supposition that 1,4-polymerization, i.e. polydiacetylene type polymerization, occurs easily in the A type film and 1,2- or 3,4-polymerization, i.e. polyacetylene type polymerization, occurs in the B type film, and that the polymerized A type film was decomposed at the polydiacetylenic bond when the irradiation continued further. It was also shown that the polyacetylene type polymer was obtained only when the B type film was irradiated with the high energy beam.     

基于条码扫描的特种冰箱集存库系统设计与应用

本文将条码扫描器应用于特种冰箱的制造中,建立了一种新型全自动集存库系统,重点分析了本系统的工作原理和硬件配置,及PLC的程序设计和触摸屏组态软件设计。     

MIMO系统中的分组全分集全码率空时编码

针对未编码的多输入多输出（MIMO，Multi—Input Multi—Output）系统，提出一种复杂度适中的分组全分集全码率（GFDFR，Group—wise Full Diversity Full Rate）空时编码方案。该方案通过在发送端进行天线分组，各组独立编码，减小全分集全码率（FDFR，Full Diversity Full Rate）编码块的大小从而降低系统编解码复杂度；在频率选择性信道中，进一步对子载波分组进行独立编码，获得频率分集（或多径分集），以适中的复杂度在不降低系统分集度的情况下保证了信息的全码率传输，是一种在MIMO信道中极具实用价值的空时编码方案。     

Irradiation Defects in Silicon Crystal

The application of irradiation in silicon crystal is introduced.The defects caused by irradiation are reviewed and some major ways of studying defects in irradiated silicon are summarized.Furthermore the problems in the investigation of irradiated silicon are discussed as well as its properties.