全文获取类型
收费全文 | 74002篇 |
免费 | 7339篇 |
国内免费 | 5480篇 |
专业分类
电工技术 | 2369篇 |
技术理论 | 1篇 |
综合类 | 4811篇 |
化学工业 | 19008篇 |
金属工艺 | 6432篇 |
机械仪表 | 3907篇 |
建筑科学 | 2684篇 |
矿业工程 | 2089篇 |
能源动力 | 1857篇 |
轻工业 | 5003篇 |
水利工程 | 1115篇 |
石油天然气 | 2707篇 |
武器工业 | 604篇 |
无线电 | 9026篇 |
一般工业技术 | 10695篇 |
冶金工业 | 3023篇 |
原子能技术 | 977篇 |
自动化技术 | 10513篇 |
出版年
2024年 | 246篇 |
2023年 | 1459篇 |
2022年 | 1951篇 |
2021年 | 2975篇 |
2020年 | 2403篇 |
2019年 | 2172篇 |
2018年 | 1946篇 |
2017年 | 2403篇 |
2016年 | 2667篇 |
2015年 | 2692篇 |
2014年 | 3922篇 |
2013年 | 4232篇 |
2012年 | 4895篇 |
2011年 | 6260篇 |
2010年 | 4622篇 |
2009年 | 5191篇 |
2008年 | 4561篇 |
2007年 | 5264篇 |
2006年 | 4705篇 |
2005年 | 3960篇 |
2004年 | 3057篇 |
2003年 | 2693篇 |
2002年 | 2148篇 |
2001年 | 1629篇 |
2000年 | 1591篇 |
1999年 | 1288篇 |
1998年 | 1028篇 |
1997年 | 804篇 |
1996年 | 766篇 |
1995年 | 594篇 |
1994年 | 568篇 |
1993年 | 439篇 |
1992年 | 347篇 |
1991年 | 286篇 |
1990年 | 214篇 |
1989年 | 175篇 |
1988年 | 115篇 |
1987年 | 99篇 |
1986年 | 108篇 |
1985年 | 57篇 |
1984年 | 39篇 |
1983年 | 38篇 |
1982年 | 45篇 |
1981年 | 23篇 |
1980年 | 38篇 |
1979年 | 28篇 |
1977年 | 17篇 |
1976年 | 16篇 |
1975年 | 9篇 |
1974年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
中国人丙型肝炎病毒全长NS3基因的克隆、序列分析及表达 总被引:1,自引:0,他引:1
目的 为改进HCV试剂的质量克隆 1b型丙型肝炎病毒 (HCV)全长NS3基因并在原核细胞中表达。方法 用RT PCR方法从中国人血清中扩增全长NS3片段 ,进行序列分析 ,并克隆到pET3 0a(+)原核表达载体中 ,构建的原核表达载体pET NS3 180 0在大肠杆菌BL2 1(DE3 )中表达 ,用Westernblot方法进行验证。结果 扩增到 1b型HCV全长NS3片段 ,经Westernblot实验表明该片段具有抗原活性。结论 构建的质粒可在大肠杆菌中表达完整的NS3蛋白 相似文献
992.
993.
阐述了Ni/Al2 O3 复合颗粒在生产中的应用 ,讨论了在Al2 O3 陶瓷颗粒上形成Ni膜的三种方法 ,分析了这些方法的优缺点。 相似文献
994.
采用沉淀-焙烧法制备了室温下对NH3具有高灵敏度和高选择性的rGO-SnO2纳米复合材料。利用X射线衍射(XRD),傅里叶红外光谱(FTIR),X射线光电子能谱(XPS),扫描电子显微镜(SEM),透射电子显微镜(TEM)和比表面积(BET)表征分析了纯SnO2与rGO(1.0%)-SnO2纳米复合物的属性。与纯SnO2相比,rGO(1.0%)-SnO2纳米复合物中SnO2晶体尺寸较小,约为6~20nm,比表面积更大,为33m2/g;rGO(1.0%)-SnO2纳米复合材料对0.01% NH3的灵敏度达到了49.6%,是相同NH3浓度下纯SnO2灵敏度的2.1倍,并且响应和恢复时间分别为21s和204s,比纯SnO2缩短了24s和10s,具有良好的重复性,选择性与稳定性;rGO(1.0%)-SnO2纳米复合材料优良的气敏性能是由rGO与SnO2产生的p-n异质结以及溶解的NH3电离出导电离子共同作用的结果。 相似文献
995.
996.
The three-dimensional model of isothermal flow of power-law fluid in a coat-hanger die has been developed using finite element
method. The shape of coat-hanger die used in the present model was determined according to the previous analytical design
equation which is based on one-dimensional flow model in the manifold and the slot. Because uniform flow rate across the die
outlet is most important to achieve uniform thickness of extruded polymer sheet or film, flow rate distribution is mainly
examined to determine the valid process condition for the design equation as the design parameters are changed. The effects
of fluid property in terms of power-law index and process parameters not considered in one-dimensional design equation such
as die inlet size and the presence of land were analyzed. Results show that the manifold angle is the most influencing design
parameter on flow rate distribution. When the material of different power-law index from design value is processed, the change
of power-law index affects the uniformity of flow rate appreciably. 相似文献
997.
998.
A. Barrera J.A. Montoya M. Viniegra J. Navarrete G. Espinosa A. Vargas P. del Angel G. Prez 《Applied Catalysis A: General》2005,290(1-2):97-109
The catalytic performance of mono- and bimetallic Pd (0.6, 1.0 wt.%)–Pt (0.3 wt.%) catalysts supported on ZrO2 (70, 85 wt.%)–Al2O3 (15, 0 wt.%)–WOx (15 wt.%) prepared by sol–gel was studied in the hydroisomerization of n-hexane. The catalysts were characterized by N2 physisorption, XRD, TPR, XPS, Raman, NMR, and FT-IR of adsorbed pyridine. The preparation of ZrW and ZrAlW mixed oxides by sol–gel favored the high dispersion of WOx and the stabilization of zirconia in the tetragonal phase. The Al incorporation avoided the formation of monoclinic-WO3 bulk phase. The catalysts increased their SBET for about 15% promoted by Al2O3 addition. Various oxidation states of WOx species coexist on the surface of the catalysts after calcination. The structure of the highly dispersed surface WOx species is constituted mainly of isolated monotungstate and two-dimensional mono-oxotungstate species in tetrahedral coordination. The activity of Pd/ZrW catalysts in the hydroisomerization of n-hexane is promoted both with the addition of Al to the ZrW mixed oxide and the addition of Pt to Pd/ZrAlW catalysts. The improvement in the activity of Pd/ZrAlW catalysts is ascribed to a moderated acid strength and acidity, which can be correlated to the coexistence of W6+ and reduced-state WOx species (either W4+ or W0). The addition of Pt to the Pd/ZrAlW catalyst does not modify significantly its acidic character. Selectivity results showed that the catalyst produced 2MP, 3MP and the high octane 2,3-dimethylbutane (2,3-DMB) and 2,2-dimethylbutane (2,2-DMB) isomers. 相似文献
999.
甲磺酸伊马替尼的合成 总被引:3,自引:0,他引:3
以4-甲基-3-硝基苯胺为起始原料,经过缩合、还原、环合等反应制得抗肿瘤药物甲磺酸伊马替尼。并分别讨论了采用无水碳酸钾代替二异丙基乙胺、水合肼和普通催化剂代替铂炭催化剂以及采用异戊醇作为溶剂的优点。最终反应总收率超过50%,用高效液相色谱分析产品纯度在99.5%以上。 相似文献
1000.
Linear low‐density polyethylene (LLDPE), based on butene‐1 or hexene‐1, was irradiated with γ‐rays under vacuum or in the presence of air. The study focused on the influence of the dose rate and the γ‐dose on the thermal properties of LLDPE. Differential scanning calorimetry, thermogravimetric analysis (TGA), and TGA/FTIR techniques were used to address the thermal behavior as a result of γ‐irradiation. During this irradiation, competition between crosslinking and scission reactions, subsequent to oxidation reactions, occurred in the polymeric material, which strongly depends on the experimental conditions. A decrease of the crystallinity for γ‐irradiated samples was observed in particular for samples irradiated under vacuum. This observation may be explained by increased hindrance of segment mobility due to crosslinking reactions that prevent crystal growth. TGA investigations revealed an enhancement of the thermal stability for samples irradiated under vacuum but not for those irradiated in air. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2790–2795, 2006 相似文献