Sulfuric acid recovery from rare earth sulphate solutions by diffusion dialysis

1 Introduction As an important industrial chemical, sulfuric acids are widely used in metallurgical and chemical processes, in which some waste solutions containing free sulfuric acids and metallic ions are therefore produced[1, 2]. If these waste acids …     

自动壳封焊机焊缝位置控制的实验研究

为解决自动壳封焊机机械凸轮式仿形的缺点，提出了基于电子凸轮的控制方案，为实现电子凸轮控制方案，在焊接轨迹形成分析的基础上，建立了焊枪位置控制的数学模型，改进后的自动焊机焊接试验表明，焊接位置误差较小，可以满足生产的需要。     

Structure and electronic properties of SiC thin-films deposited by RF magnetron sputtering

SiC thin-films were prepared by RF-magnetron sputtering technique(RMS) with the target of single crystalline SiC and then annealed. The surface morphology of thin-films was characterized by AFM. The result shows that the surface of the thin-films is smooth and compact; XRD analysis reveals that the thin-films are amorphous. The thickness, square-resistance and curves of resistance—temperature were measured. The results show that the curves of lnR versus 1/kT both before and after annealing satisfy the expression of lnR∝△W/kT, where ?W is electron excitation energy in the range of 0.014 2-0.018 5 eV, and it has a trend of increasing when the temperature is increased. After synthetical analysis we get the conclusion that the electronic mechanism of the thin-films is short distance transition between the localized states in the temperature range of 25-250 ℃. The resistivity is in the range of 2.4×10-3-4.4×10-3 Ω·cm and it has the same trend as electron excitation energy when annealing temperature is increased, which further confirms the electronic mechanism of thin-films and the trend of electron excitation energy versus annealing temperature.     

超声参振对Al-Fe合金凝固过程的影响

在Al-Fe合金的凝固过程中引入不同功率的超声振动,利用受控凝固和受控振动相结合的实验装置和方法,研究了超声参振对Al-Fe合金熔体温度场以及组织形态和抗拉强度的影响.实验表明:熔体的温度场随振动功率的增加和振动时间的延长而升高,并趋于一个平衡的温度场;超声参振可以显著细化先共晶FeAl3相,Al-Fe合金生长的组织形态的差异主要取决于凝固速度;超声参振凝固的Al-Fe合金的热稳定性好,有良好的应用前景.     

热压变形对灰口铸铁石墨形态的影响

研究了灰口铸铁(HTl50)在900℃大压下量塑性变形后石墨的分布形态，结果表明：随着压下量的增加，石墨片逐渐趋于平行分布；变形过程中发生了碳的回溶，同时伴随着石墨片的断裂；石墨片体积分数及片间距随压下量的增加而逐渐减少。     

单道自动对接焊应变应力场分析

通过给出模拟单道自动对接焊过程的数学模型，用有元法计算瞬时应变场和应力场并与实测值进行比较，结果证实计算值与实测值基本吻合，表明用数学模拟自动对接焊过程是可行的。     

金品纯度的比重法测定

介绍了金品纯度的测定方法,推导出了比较实用的纯度计算、杂质估算和温度影响等几个表达式。     

Application of a time-dependent constitutive model to rheocast systems

A mathematical model has been developed to describe the velocity field in an agitated Al- 5Cu alloy in which B4C particles were suspended at different loading rates of up to 40 %. The material system was agitated by means of an electromagnetic rotary stirrer. The non- Newtonian behavior of the melt/solid slurry was allowed for using two models: the steady- state model of Joly and Flemings and the model of Brown, which takes account of time- dependent behavior. Calculations have shown that the two models behave similarly at high shear rates. In addition, if agitation was discontinued, very little time was required for the velocity (and hence the fluidity) of the slurry to decay.     

新型硬齿面环面蜗杆传动研究

采用精确磨削TI蜗杆的砂轮，用类似直廓环面蜗杆或平面包络环面蜗杆的磨削方法加工环面蜗杆，使该蜗杆和齿面形状与砂轮曲面相同的蜗轮相配合，形成一种新型蜗杆传动，给出了这种传动蜗杆副齿面的数学模型，并通过计算机仿真得出了这种传动蜗轮齿面上接触线的形状及分布特征，初步分析了其啮合特点。     

形态对钯-氢体系热力学性质的影响

基于实验测定海绵Pd颗粒在278K-323K范围内吸放H2，D2的P-C-T曲线．结合文献给出的其它形态的Pd吸放氢结果进行系统比较分析．探讨了形态对钯-氢体系热力学性质的宏观影响和微观本质。在室温附近，氢的饱和固溶度与坪压随Pd的粒度减小而增加；Pd的形态或粒度对氢的饱和固溶度和吸氧坪压的影响程度刚随温度升高而减小，而且坪压之间的差别在温度较高时不再明显甚至消失。吸氘坪压差别大，解吸坪压差别小。Pd—H体系中α→β的相变热焓、热熵（绝计值)随粒度减小而减小，单晶Pd相应热力学函数最小。海绵Pd颗粒中的压力迟滞效应最明显．材料本底缺陷密度决定不同形态Pd-H体系的压力迟滞效应的大小。