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51.
52.
Somnath Karmakar 《Polycyclic Aromatic Compounds》2019,39(2):159-171
Eigensolutions of {X( = C,B,N),Y( = C,B,N)}-cyclacene graphs with next nearest neighbor (nnn) interactions have been obtained in analytical forms by adapting n-fold rotational symmetry followed by two-fold rotational symmetry (or a plane of symmetry). Expressions of eigensolution indicate the subspectral relationship among such cyclacenes with an even number of hexagonal rings e.g., eigenvalues of {X,Y}-di-cyclacene are found in the eigenspectra of all such even cyclacenes. Total π-electron energies and highest occupied molecular orbital and lowest unoccupied molecular orbital (HOMO–LUMO) gaps are calculated using the analytical expressions obtained and are found to vary negligibly with the variation of nnn interactions in such cyclacenes. Total π-electron energy is found to increase due to increase in restriction intensity of nnn interactions, whereas the HOMO–LUMO gap of polyacenecs having the even number of hexagonal rings and with one electron at each site (atom) decreases with increase in the restriction intensity since such systems contain degenerate half-filled HOMO (bonding or nonbonding) that are much more vulnerable for perturbations imposed through nnn interactions. 相似文献
53.
针对某乘用车发动机转速在1 573 r/min,压缩机开启时车内噪声异常的问题,对样车进行试验分析与诊断,对压缩机-支架系统进行仿真分析,提出改进方案并验证改进效果。利用LMS声振信号采集系统采集振动噪声数据,采用频谱分析、阶次追踪等方法,并结合压缩机-支架系统模态仿真结果,确定车内异常噪声是压缩机轴频21阶与压缩机-支架系统3阶模态频率接近发生共振造成的。通过优化支架结构来提高压缩机-支架系统3阶模态频率以此来避免共振,并换装橡胶驱动盘缓和压缩机输入扭矩波动。将改进结构进行整车试验,结果表明:匀速工况空调开启时问题转速下,车内噪声降低了2.5 dB(A);匀加速工况空调开启时发动机转速1 500~1 650 r/min区间,车内噪声无峰值,其余转速空调开启时改进前/后车内噪声基本不变,噪声波动趋势平缓。 相似文献
54.
《Oil and Energy Trends》2020,45(1):56-58
Currency exchanges rates – updated monthly. Economic indicators of industrial production. Countries included: France, Germany, Italy, the United Kingdom, the United States, Canada, Japan (Total G-7), Eurozone and Total EU-28 (Total OECD). Updated monthly. Economic indicators of car registration in the United States, Canada, France, Germany, Italy, Poland, Spain, Turkey, the United Kingdom, Japan, Republic of Korea and Other OECD (Total OECD-30). Updated monthly. Monthly averages of crude steel production in thousand metric tons for the United States, Canada, Brazil, Mexico, Austria, Belgium, Czech Republic, France, Germany, Italy, Netherlands, Poland, Spain, Sweden, Turkey, the United Kingdom, Russia, Ukraine, South Africa, Iran, China, India, Japan, Republic of Korea, Taiwan and Australia. 相似文献
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《International Journal of Hydrogen Energy》2019,44(5):2905-2917
In this study, a multi-tubular thermally coupled packed bed reactor in which simultaneous production of ammonia and methyl ethyl ketone (MEK) takes place is simulated. The simulation results are presented in two co-current and counter-current flow modes. Based on this new configuration, the released heat from the ammonia synthesis reaction as an extremely exothermic reaction in the inner tube is employed to supply the required heat for the endothermic 2-butanol dehydrogenation reaction in the outer tube. On the other hand, MEK and hydrogen are produced by the dehydrogenation reaction of 2-butanol in the endothermic side, and the produced hydrogen is used to supply a part of the ammonia synthesis feed in the exothermic side. Thus, 30.72% and 31.88% of the required hydrogen for the ammonia synthesis are provided by the dehydrogenation reaction in the co-current and counter-current configurations, respectively. Also, according to the thermal coupling, the required cooler and furnace for the ammonia synthesis and 2-butanol dehydrogenation conventional plants are eliminated, respectively. As a result, operational costs, energy consumption and furnace emissions are considerably decreased. Finally, a sensitivity analysis and optimization are applied to study the effect of the main process parameters variation on the system performance and obtain the minimum hydrogen make-up flow rate, respectively. 相似文献
59.
《International Journal of Hydrogen Energy》2021,46(69):34449-34462
Three-dimensional Bödewadt flow (fluid rotates at a large enough distance from the stationary plate) of carbon nanomaterial is examined. Single walled and multi walled CNTs are dissolved in water and gasoline oil baseliquids. Darcy-Forchheimer porous medium is considered. Stationary disk is further stretched linearly in radial direction. Heat transfer effect is examined in presence of radiation and convection. Effect of viscous dissipation is accounted. Entropy generation rate is studied. By using adequate transformation (von Kármán relations), the flow field equations (PDEs) are transmitted into ODEs. Solutions to these ODEs are constructed via implementation of shooting method (bvp4c). In addition to Entropy generation rate, Bejan number, heat transfer rate (Nusselt number), skin friction and temperature of fluid are examined through involved physical parameters. Axial component of velocity intensifies with increment in nanoparticles volume fraction and ratio of stretching rate to angular velocity parameter while it decays with higher porosity parameter. Higher nanoparticles volume fraction and porosity parameter lead to decay in radial as well as tangential component of velocity. However it enhances with higher ratio of stretching rate to angular velocity parameter. Temperature of fluid directly varies with higher ratio of stretching rate to angular velocity parameter, radiation parameter, Eckert number, Biot number and nanoparticles volume fraction. Rate of Entropy generation is reduced with higher estimations of porosity parameter, nanoparticles volume fraction and radiation parameter. Skin friction coefficient decays with higher porosity parameter and ratio of stretching rate to angular velocity parameter. Intensification in porosity parameter, nanoparticles volume fraction and Biot number leads to higher Nusselt number. Prominent impact is shown by multiple-walled CNTs with gasoline oil basefluid than single-walled CNTs with water basefluid. 相似文献
60.
本文以喷淋液滴在空气环境下运动特性为工程背景,建立单个液滴在常温、常压空气环境中的动量方程,分析液滴沉降特性、追赶特性及运动轨迹行为。计算结果表明,不同喷淋液滴初始条件下,短时间内存在重力大于曳力和重力小于曳力两种情况,但最终减速液滴均会达到受力平衡状态;液滴离开喷淋头后,垂向位移均迅速增大,液滴粒径越大、初始速度越大,垂向位移增长的速率也越大,达到相同位移的用时越短;液滴尺寸、初始速度相差越大,液滴追赶所用的时间越短,追赶位移越小,液滴尺寸、初始速度越接近,液滴追赶所用的时间越长,追赶位移越大;液滴初始速度越大、初始直径越大、喷射角度越大,横向速度消失越慢,达到的横向位移越大,喷射液滴覆盖的面积也越大。计算结果有助于优化工程实际中喷淋系统的设计与布置。 相似文献