Use of pyrogenic silicas for petroleum oil polar fraction characterisation. Fourier transform infrared spectroscopy and microelectrophoresis studies

In the power transformer, the presence of polar or charged species in the insulating oil can cause failure and electric discharges. Solid substrates such as silica can be used to extract the polar species and to refine the oil in order to prevent future failure in the power transformer. However, the use of silica for petroleum oil separation and refining will depend on the silica characteristics such as surface charge, surface composition, specific surface area and particle size.Various pyrogenic silicas having various specific surface areas (49-200 m² g⁻¹) and particle sizes (207-500 nm) were used to extract the polar fractions from the neat transformer insulating oils (a new, NO, and used, UO2, oils). The oil covered silica samples were investigated by diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy in the range 4000-600 cm⁻¹. The bare silica surfaces present two main hydroxyl components, a sharper peak at 3745 cm⁻¹, I₃₇₄₅, due to isolated silanols and a second broad, which spreads over 3745-3000 cm⁻¹, I_3745-3000, due to H-bonded silanols. The relative intensities of the two components, I₃₇₄₅/I_3745-3000, varied for the bare and the oil covered silicas depending on the solid surface characteristics. The adsorption of the NO polar fraction onto silica leads to strong reduction in intensity of the sharper peak in favour of the broad one. However, the adsorption of the UO2 polar fraction onto silica leads in all cases to the decrease in the intensity of the both silica OH components. Further, the UO2 adsorption on the silica leads to the apparition of a broad peak at low frequency in the region 3250-3300 cm⁻¹ which, is due to the associated phenolic groups of UO2 oil polar fraction. The analysis of the DRIFT spectra for various samples indicates that the oil polar fraction resembles to asphaltenes compounds.The microelectrophoresis method used to investigate the surface charge at the water/oil polar fraction covered silica interface, indicates negatively charged particles. Further, the negative charge increased with the pH, as resulting from the increase of the ionisation and/or the amount of the oil polar carboxylic and phenolic groups. The oil polar fraction, i.e. the asphaltene components, in contact with both the silica surface and water at high pH values rearrange, due to their amphiphilic character.Finally, the use of the silica substrates seems to be suited to extract and analyse polar species present in petroleum oil. A correlation is found between the nature of the oil, its functionalities, and the magnitude of its zeta potential value at the water/oil covered silica interface.     

Autolisp在开发V画面体视图自生成系统中的应用

介绍了近年来体视投影技术的应用及发展，并提出了用AutoCAD的内嵌开发工具Autolisp语言结合Visualisp中的对话框控制语言DCL来开发体视图自动生成系统的新思路．根据V画面体视投影原理，推导出了V画面体视变换矩阵．给出了该系统的程序流程框图及相应的功能模块．并将该系统的界面和基本功能进行了展示，从而为体视自生成技术的研究开辟了新的道路．     

基于小波的彩色序列图象压缩编码

此文提出了一种基于小波变换的运动估计算法，时间复杂度比常规算法降低了一个数量级，同时在估值精度上可与常规算法媲美。利用更佳频率分辨率小波分解处理运动补偿余量误差善了复现图象质量。实验结果表明，该算法在高压缩比情况下图象复现质量显著优于ＭＰＥＧ－２，具有广阔的应用前景。     

Instability of zeolite Y supported cobalt sulfide hydrotreating catalysts in the absence of H2S

Ion exchanged CoNaY was sulfided at 473 and 673 K and subsequently heated in He at 673 and 773 K. The resulting samples were characterized by means of overall sulfur analysis, temperature programmed Ar treatment and Fourier transform infrared spectroscopy. It was shown that during He flushing at sufficiently high temperature a protolysis reaction occurs resulting in the decomposition of Co sulfide into Co²⁺ ions and H₂S.     

叠后记录Radon变换压制干扰方法

在叠加剖面中,下伏反射界面的反射信号同相轴呈连续的或带有限个间断点的连续层状图像,各种干扰则呈无规则的图像。对此剖面的振幅数据进行 Radon 变换,即分别向各方向进行投影,层状图像将产生一定形状的光滑曲线,而干扰数据将相互抵消,其剩余数据呈高斯分布。在Radon 域中通过平滑等方法消除这些呈高斯分布的噪声数据,再经 Radon 逆变换,便可获得信噪比较高的叠加剖面。其结果不改变原叠加剖面的分辨率和信号波形特征。理论与实际剖面的处理结果表明,这是一种良好的压制干扰方法。     

Modified Imidazoles: Degradation Inhibitors and Adhesion Promoters for Polyimide Films on Copper Substrates

Polyimide films on copper substrates that are exposed to elevated temperatures and an oxidizing environment will be subject to degradation. In order to halt this degradation without changing the properties of the system, a polymeric agent could be placed between the polyimide and the copper. This paper will investigate three such materials that will not only slow down the degradation of the polyimide and the oxidation of the copper, but will also improve adhesion within the system. Fourier transform infrared reflection-absorption spectroscopy (FTIR-RAS) will be used to investigate the polyimide/polymeric agent/copper system.     

一种新颖的求解离散Gabor展开对偶窗的方法

本文给出了一种新颖的简捷的求解离散Gabor展开最佳对偶窗的方法．首先推导了离散Gabor展开的公式，给出了连续Gabor展开和离散Gabor展开间的关系．最后利用连续展开和离散展开间的关系给出了一求解离散Gabor展开最佳对偶窗的表达式及实例．     

Synthesis, characteristics and oxygen-sensitive properties of SrMgxTi 1 − xO3 nanocrystals

SrMg_xTi_{1 - x}O₃ nanocrystals (x = 0.1–0.6) were synthesized by the stearic acid gel method. Powder samples were characterized by X-ray diffraction and X-ray photoelectron (XP) spectroscopy. The results showed that the lattice parameter a and the O 1s XP spectrum changed not only with the Mg content x but also with the grain size d of the samples. The conductivity of a thick film specimen fabricated on an aluminium oxide wafer was investigated in a nitrogen—oxygen atmosphere.     

WAVELET ALGORITHM FOR INTEGRAL OPERATOR EQUATION AND ITS APPLICATIONS TO ELECTROMAGNETIC PROBLEMS

A brief summary of the basic theory of wavelet is proposed. The properties of wavelet function are discussed. The possible applications of wavelet to electromagnetics are given. Examples show that the wavelet method is feasible and effective for solving electromagnetic problems.