Theoretical investigation of intrinsic point defects and the oxygen migration behavior in rare earth hafnates

In this work, the composition-dependent point defect types and formation energies of RE₂Hf₂O₇ (RE = La, Ce, Pr, Nd, Pm, Sm, Eu and Gd) as well as the oxygen diffusion behavior are systematically investigated by first-principles calculations. The possible defect reactions and dominant defect complexes under stoichiometric and non-stoichiometric conditions are revealed. It is found that O Frenkel pairs are the predominant defect in stoichiometric pyrochlore hafnates. Hf-RE cation anti-site defects, accompanied by RE vacancies and/or oxygen interstitials, are stable in the non-stoichiometric case of HfO₂ excess. On the other hand, RE-Hf anti-site defects together with oxygen vacancies and/or RE interstitials are preferable in the case of RE₂O₃ excess. The energy barriers for the migration along the V_O48f - V_O48f pathway of pyrochlore hafnates were calculated to be between 0.81 eV and 0.89 eV. Based on these results, a defect engineering strategy is proposed and the pyrochlore hafnates investigated here are predicted to exhibit potential oxygen ionic conductivity.     

Single-Crystalline TiO2(B) Nanobelts with Unusual Large Exposed {100} Facets and Enhanced Li-Storage Capacity

The {100} facet of single-crystalline TiO₂(B) is an ideal platform for inserting Li ions, but it is hard to be obtained due to its high surface energy. Here, the single-crystalline TiO₂(B) nanobelts from H₂Ti₃O₇ with nearly 70% {100} facets exposed are synthesized, which significantly enhances Li-storage capacity. The first-principle calculations demonstrate an ab in-plane 2D diffusion through the exposed {100} facets. As a consequence, the nanobelts can significantly accommodate Li ions in LiTiO₂ formula with specific capacity up to 335 mAh g⁻¹, which is in good agreement with the electrochemical characterizations. Coating with conductive and protective poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), the cut-off discharge voltage is as low as 0.5 V, leading to a capacity of 160.7 mAh g⁻¹ after 1500 cycles with a retention rate of 66% at 1C. This work provides a practical strategy to increase the Li-ion capacity and cycle stability by tailoring the crystal orientation and nanostructures.     

有线电视工程建设流程再造设计

从理论与实际工作相结合的角度出发,以淄博广电青鸟公司为研究对象,对有线电视网络工程建设流程的现状、存在的问题和原因进行细致深入分析,然后按照提出的再造方案的设计原则,设计了工程建设流程的再造方案,并对新旧流程进行比较。     

从图像的二维谱分析现行电视的缺陷

从图像的二维谱可以得出现行广播电视图像为什么不能满足人眼的视觉匹配以及现行电视制度的不足 ,从而对未来的高清晰度电视发展提出要求。     

"通信原理"课程教学改革探索

针对我院省重点专业“电子信息工程”的必修主干专业基础课程。“通信原理”教学中存在的不利于培养和提高学生分析问题、解决问题的能力的因素，从课程的教学内容、教学手段等方面论述了课程改革的基本构想，并对课程的实践环节——设计性实验的改革进行了探讨。     

有线电视宽带网边界路由系统安全技术研究

提出在当今有线电视宽带网络环境下,从构建安全的边界路由系统出发,研究在边界路由器上采取针对有线电视宽带网内部网络的报文过滤和针对路由系统本身的安全策略,并在某有线电视宽带网络中进行了典型应用,实践证明可以达到事半功倍的网络安全目的.     

基于多抽样率信号处理的无源雷达MTD方法

以数字电视信号为机会照射源的雷达系统研究为背景 ,提出用以多抽样率信号处理为基础的多级抽取信号处理算法解决运动目标检测中海量数据处理问题。文中叙述了数字电视广播信号回波的数学模型、多级抽取基本原理、目标检测算法 ,以数字电视信号为反射回波做了仿真 ,对运动目标进行检测 ,并对仿真结果做了分析。     

光纤通信在市内接入网的应用

先说明市内接入网的单位用户和住家用户两大类使用通信和电视、交互型和分配型业务的要求不相同，相应地对光纤传输的应用须作不同的考虑，文中认为；光纤从市内交换局直连办公大楼是合乎现实需要的，而对于居民住家，宜选用光纤连至路边或光纤与同轴结合和适当利用无源光网络等方案，俟将来时机成熟才实行光纤连至每一家，文末有概括总结，说明接入网不同于长途网，接入网的光纤系统可以使用常规单模光纤，工作于波长1．3μm，而光放大器和波分多路系统不是普遍需要，但光电子集成在光端机中是必要的。     

基于LCoS芯片的微型电视系统设计与实现

介绍了LCoS芯片在电视接收系统中的应用，重点讨论了LCoS芯片的结构与特点。自主开发的LCoS模块采用模拟视频接口、兼容隔行和逐行扫描方式，可以简化系统电路设计，降低系统功耗。同时论述了LCoS微型电视机在信号接收、模拟视频处理、时序控制和音频电路等方面的特点，并给出了相关电路的设计方案。     

Minimum spanning trees made easier via multi-objective optimization

Many real-world problems are multi-objective optimization problems and evolutionary algorithms are quite successful on such problems. Since the task is to compute or approximate the Pareto front, multi-objective optimization problems are considered as more difficult than single-objective problems. One should not forget that the fitness vector with respect to more than one objective contains more information that in principle can direct the search of evolutionary algorithms. Therefore, it is possible that a single-objective problem can be solved more efficiently via a generalized multi-objective model of the problem. That this is indeed the case is proved by investigating the computation of minimum spanning trees.This work was supported by the Deutsche Forschungsgemeinschaft (DFG) as part of the Collaborative Research Center Computational Intelligence (SFB 531) and by the German-Israeli Foundation (GIF) in the project Robustness Aspects of Algorithms.