山东电网部分500 kV线路不平衡电流偏大原因的分析及改善措施的研究

针对山东电网部分500 kV线路的局部电流不平衡现象,通过仿真模拟了系统运行中的大(上午10:00)、小(凌晨3:00)潮流方式下的电流不平衡现象,并与电网运行中实测积累的大量不平衡电流数据进行比较,找出500 kV系统局部产生不平衡电流的原因是线路参数不平衡,即淄川-益都-潍坊同塔双回线路全线不换位及多条不平衡线路构成的2个环网,使个别线路在一定条件下产生了严重的不平衡电流。为改善该不平衡现象,对22种同塔双回线路的导线排列方式进行模拟计算分析,得出优化的导线排列组合方式。模拟计算结果表明,通过在变电站出线处合理调整同塔双回线路的导线排列方式,可有效改善山东500kV系统的局部电流不平衡现象。     

大截面架空导线输电技术的研究与分析

随着我国电力需求的增长,输电容量日益增大,大截面架空导线输电技术的应用将日益广泛。本文分析了大截面架空导线输电技术的优势及其不利因素;探讨了采用大截面架空导线输电技术后对系统的影响;并指出大截面架空导线输电技术的适宜范围及注意问题。     

中小企业硅烷交联聚乙烯绝缘单线制造的探索

硅烷交联聚乙烯绝缘单线制造可以借鉴聚氯乙烯绝缘单线的制造,然而,其对导体制品的要求和绝缘挤出工艺存在着很多不同之处。本文通过比较和分析,探索传统生产聚氯乙烯绝缘电线电缆的中小型企业,通常产品的产量较小、品种较多、一机多用或品种变化频繁的条件下,增加硅烷交联电线电缆生产时,在绝缘单线制造中应采取相应的对策和注意事项,指出了导体制造、绝缘挤出和交联工艺中质量控制要点。     

混合氧离子导体膜材料的应用及研究进展

介绍了混合氧离子导体材料同时具备电子和氧离子导电能力,在一些应用领域极具研究价值;这类材料构建的致密陶瓷膜可以在中高温的氧梯度条件下,实现氧气的选择性分离,应用于陶瓷膜分离器从空气中直接获得氧气,和膜反应器中使甲烷部分氧化获得合成气,以及用作氧化物燃料电池的阴极和阳极材料;这类材料的氧分离性能、机械和化学稳定性的研究进展将为今后走上实际运用奠定基础.     

采用换位导线绕组提高变压器抗短路能力

提高变压器的抗短路能力是制造部门和电力运行部门的一致目标，采用换位导线绕组的变压器可有效的提高变压器的抗短路能力。文章详细介绍了换位导线的特性、用途和在我国的应用情况。     

Relaxation peaks associated with the oxygen-ion diffusion in La2−xBixMo2O9 oxide-ion conductors

The effects of bismuth doping on the oxygen-ion diffusion in oxide-ion conductors La_2−xBi_xMo₂O₉ (x=0.05, 0.1, and 0.15) have been studied by both internal friction and dielectric relaxation techniques. Two internal friction peaks of relaxation type (P₁ and P₂ peak) were observed at a measurement frequency of 4 Hz around 380 and 430 K, respectively. As for the dielectric measurement, a prominent dielectric relaxation peak (P_d) was found in all the Bi-doped samples around 700 K at a measurement frequency of 50 kHz, which actually consists of two sub-peaks (denoted as P_d1 and P_d2 peak). With increasing Bi-doping content, two peaks shift to higher temperature and decrease in height, while the activation energy of both peaks increases. The main reason was interpreted as the introduction of the lone-pair electrons of bismuth, which tends to block the diffusion of oxygen ion.     

Fabrication of NiO Buffer Layer for YBCO Coated Conductors by Combining Sputtering and SOE Method

In research of YBCO coated conductors, the development of a oxide template for epitaxial growth of YBCO is very important. Matsumoto et al have demonstrated the potential of the surface oxidation epitaxial (SOE) route for formation a cube textured NiO layer on nickel tapes. The epitaxial NiO functions as a buffer layer of chemical reaction between YBCO and nickel, and as a template for the epitaxial growth of YBCO. However, the surface quality of NiO is difficult to control and defects such as crack, spall and deep grooves exist in SOE NiO layer. A new approach combining sputtering and SOE method to obtain crack-free and cube textured NiO layer were reported. Ni tapes prepared by the combination of rolling and recrystallization were used for this work. A coating of Ni was first deposited on the tapes via magnetron sputtering. Then on the coating tapes, continuous and textured NiO layer were achieved by SOE technology.     

Development of the bus joint for the ITER Central Solenoid

The terminations of the Central Solenoid (CS) modules are connected to the bus extensions by joints located outside the CS in the gap between the CS and torodial field (TF) assemblies. These joints have very strict space limitations. Low resistance is a common requirement for all ITER joints. In addition, the CS bus joints will experience and must be designed to withstand significant variation in the magnetic field of several tenths of a Tesla per second during initiation of plasma. The joint resistance is specified to be less than 4 nΩ.The joints also have to be soldered in the field and designed with the possibility to be installed and dismantled in order to allow cold testing in the cold test facility. We have developed coaxial joints that meet these requirements and have demonstrated the feasibility to fabricate and assemble them in the vertical configuration. We introduced a coupling cylinder with superconducting strands soldered to the surface of the cable that can be installed in the ITER assembly hall and at the cold test facility. This cylinder serves as a transition area between the CS module and the bus extension.We made two racetrack samples and tested four bus joints in our Joint Test Apparatus. Resistance of the bus joints was measured by a decay method and by a microvoltmeter; the value of the current was measured by the Hall probes. This measurement method was verified in the previous tests. The resistance of the joints varied insignificantly from 1.5 to 2 nΩ.One of the challenges associated with a soldered joint is the inability to use corrosive chemicals that are difficult to clean. This paper describes our development work on cable preparation, chrome removal, compaction, soldering, and final assembly and presents the test results.     

Spatial mapping of electronic states in κ-(BEDT-TTF)2X using infrared reflectivity

Abstract

We review our recent work on spatial inhomogeneity of the electronic states in the strongly correlated molecular conductors κ-(BEDT-TTF)₂X. Spatial mapping of infrared spectra (SMIS) is used for imaging the distribution of the local electronic states. In molecular materials, the infrared response of the specific molecular vibration mode with a strong electron–molecular vibration coupling can reflect the electronic states via the change in the vibration frequency. By spatially mapping the frequency shift of the molecular vibration mode, an electronic phase separation has been visualized near the first-order Mott transition in the bandwidth-controlled organic conductor κ-(BEDT-TTF)₂Cu[N(CN)₂]Br. In addition to reviewing SMIS of the phase separation, we briefly mention the electronic and optical properties of κ-(BEDT-TTF)₂X.     

Nanostructured MIEC Ba0.5Sr0.5Co0.6Fe0.4O3−δ (BSCF5564) cathode for IT-SOFC by nitric acid aided EDTA–citric acid complexing process (NECC)

Ba_0.5Sr_0.5Co_0.6Fe_0.4O_3−δ(BSCF5564) was synthesized by nitric acid aided EDTA–citric acid complexing sol-gel method (NECC). Both, the phase formation temperature and time of BSCF5564 synthesized NECC were found to be low i.e. single perovskite phase formation temperature is 200 °C less as compared to the conventional method of synthesis. The orthorhombic perovskite structure has been formed after calcination at 800 °C for 5 h. Scanning electron microscopy reveals the formation of porous material constituting nano-sized and irregularly shaped rod-like structure with particle size approximately ranges from 90 to 160 nm. The total weight loss of the BSCF5564 sample comes out to be 6.6%, indicating that quadrivalence state Co⁴⁺ and Fe⁴⁺ in the sample have been completely reduced to the trivalent state Co³⁺ and Fe³⁺ due to thermal analysis. The value of E_a for BSCF5564 prepared by NECC was 0.2288 eV. The electrical conductivity of BSCF5564 synthesized by NECC is observed to be steady at high temperature (above 700 °C).