An investigation on electrochemical performances of as-cast and annealed La0.8Mg0.2Ni3.3Co0.2Six（x = 0-0.2） alloy electrodes for Ni/MH battery application

The La-Mg-Ni-based A2B7-type La0.5Mg0.2Ni3.3Co0.2Six （x=0-0.2） electrode alloys were prepared by casting and annealing. The influences of the additional silicon and the annealing treatment on the structure and electrochemical performances of the alloys were investigated systemically. Both of the analyses of XRD and SEM reveal that the as-cast and annealed alloys are of a multiphase structure, involving two main phases （La, Mg）2Ni7 and LaNi5 as well as one minor phase LaNi3. The addition of Si and annealing treatment bring on an evident change in the phase abundances and cell parameters of （La, Mg）2Ni7 and LaNi5 phase for the alloy without altering its phase structure. The phase abundances decrease from 74.3% （x=0） to 57.8% （x=0.2） for the （La, Mg）2Ni7 phase, and those of LaNi5 phase increase from 20.2% （x~0） to 37.3% （x=0.2）. As for the electrochemical measurements, adding Si and performing annealing treatment have engendered obvious impacts. The cycle stability of the alloys is improved dramatically, being enhanced from 80.3% to 93.7% for the as-annealed （950 ℃） alloys with Si content increasing from 0 to 0.2. However, the discharge capacity is reduced by adding Si, from 399.4 to 345.3 mA.h/g as the Si content increases from 0 to 0.2. Furthermore, such addition makes the electrochemical kinetic properties of the alloy electrodes first increase and then decrease. Also, it is found that the overall electrochemical properties of the alloys first augment and then fall with the annealing temperature rising.     

用Al作中间层的Si3N4陶瓷的扩散焊接

在温度为600℃，压强为30MPa和保温2h的条件下，成功地实现了Si3N4／Al／Si3N4试样的直空扩散连接，用SEM和EPMA方法进行的连接机理分析表明，Si3N4和Al的连接是通过有限的原子相互扩散实现的。用SEM和EDXA方法研究了Si3N4／Al界面的断口。结果表明，Si3N4／Al界面的断裂模式属于界面脆性剥离。     

Sr对Al-Si-Mg铸造合金中Mg2Si相结晶行为影响的研究

采用光学显微镜和扫描电镜观察了不同Sr量Al 11 6 %Si 0 4%Mg合金的组织变化 ,并分析了Sr的存在对Mg2 Si相结晶行为的影响。在未完全变质合金中 ,Mg2 Si相以网络状或笋状等形式存在 ,与共晶Si片之间存在附着生长关系。而在完全变质合金中 ,Mg2 Si相以细小的颗粒相形式孤立地存在于共晶团边界上 ,数量极少。Sr的存在对Mg2 Si相凝固结晶行为产生了重要的影响 ,这与枝晶α的数量和共晶Si的变质程度等因素有关     

电磁场对水平连铸Al-1Si合金线材组织和性能的影响

研究了工频电磁场对水平连铸10 mm的Al-1Si合金键合线铸坯表面质量、凝固组织、溶质偏析和力学性能的影响.试验结果表明,在工频电磁场作用下,铸坯的表面质量得到了改善,当励磁电流达到100 A时,表面粗糙度由未施加电磁场时的40 μm降为20 μm;凝固组织得到了细化,晶粒尺寸均匀;溶质偏析得到了抑制,Si元素在α（Al）基体中的固溶度及其分布的均匀性得到提高;并且力学性能得到了改善,抗拉强度和伸长率分别提高了16.5%和36%.     

EFFECT OF COMPOSITION ON PHYSICAL PROPERTIES OF AMORPHOUS Fe-Si-B ALLOYS

ＥＦＦＥＣＴＯＦＣＯＭＰＯＳＩＴＩＯＮＯＮＰＨＹＳＩＣＡＬＰＲＯＰＥＲＴＩＥＳＯＦＡＭＯＲＰＨＯＵＳＦｅＳｉＢＡＬＬＯＹＳ①ＷａｎｇＬｉｎｇｌｉｎｇ，ＺｈａｏＬｉｈｕａ，ＨｕＷａｎｇｙｕ，ＷｕＬｉｊｕｎ，ＺｈａｎｇＢａｎｇｗｅｉＤｅｐａｒｔｍｅ...     

Development of Si3Na/Al composite by pressureless melt infiltration

Pressureless infiltration process to synthesize Si3N4/Al composite was investigated. Al-2%Mg alloy was infiltrated into Si3N4 and Si3N4 containing 10% Al2O3 preforms in the atmosphere of nitrogen. It is possible to infiltrate Al-2%Mg alloy in Si3N4 and Si3N4 containing 10% Al2O3 preforms. The growth of the dense composite of useful thickness was facilitated by the presence of magnesium powder at the interface and by flowing nitrogen. During infiltration Si3N4 reacted with aluminium to form Si and AIN, the growth of composite was found to proceed in two ways, depending on the Al2O3 content in the initial preform. Firstly, preform without Al2O3 content gives rise to AIN, Al3.27Si0.47 and Al type phases after infiltration. Secondly, perform with 10% Al2O3 content gives rise to AIN-Al2O3 solid solution phase （AION）, MgAl2O4, Al and Si type phases. AlON phase was only present in composite, containing 10% Al2O3 in the Si3N4 preforms before infiltration.     

Formation and crystallization of bulk Pd_(82)Si_(18) amorphous alloys

1　INTRODUCTIONMetallicglassisregardedasastatethatisofdis orderunlikecrystalalloyswith periodicatomstruc ture.Soitshowsexcellentcapabilitiesofsoftmag netism ,mechanics ,corrosionresistance ,etc .How ever ,mostofamorphousalloyswereproducedbyus ingrapidsolidificationmethodssuchassplatquench ing ,meltspinning ,andsoon ,withcharacteristiccoolingratesof 10 4 10 6 K/s .Becauseamorphousal loysarepreparedwithsilk ,powderandribbon ,itisgreatlylimitedinengineeringapplication .Recently ,severalbulk…     

金属间化合物Mg2Si研究进展

对金属闯化合物Mg2Si的研究进展进行了综述，重点对Mg2Si的性质及其基础研究和Mg2Si的应用研究现状进行了论述。研究表明：虽然在Mg2Si热电性能方面的研究取得了很多突破，但它的热电转换效率仍然偏低；在结构材料的应用研究方面，Mg2Si除了和更具优势的材料复合提高其韧性和高温性能以外，另一个值得研究的方向就是将Mg2Si熔覆或喷涂在其他合金的表面，如Al、Mg合金等。另外熔体浸渗也是一种非常有希望改善Mg2Si脆性的方法。     

合金元素对Mg-Al-Si系镁合金中Mg2Si相形貌影响的研究进展

合金化和微合金化作为变质Mg-A1-Si系镁合金中汉字状Mg2Si相的一种工艺手段,目前已引起国内外的广泛关注和高度重视,并对此开展了大量的研究。本文综述了合金元素变质Mg-Al-Si系耐热镁合金中汉字状Mg2Si相的研究进展,尤其是Al、Si、Sb、Ca、P、RE和Sr等合金元素对汉字状Mg2Si相形貌的影响及其变质机理,指出了目前还存在的问题,并对今后的发展进行了展望。