超高分子量聚乙烯纤维的表面改性研究

针对超高分子量聚乙烯纤维表面黏结性差的缺点,采用超声下铬酸溶液处理纤维表面。根据正交试验,分析了处理过程中影响纤维性能的因素,并对各单独因素进行了探讨。通过SEM和FTIR分析了处理前后纤维的结构变化,并用自制的单丝抽拔装置对纤维黏结性进行了表征。结果表明:温度是影响处理纤维效果的最主要因素,低于60℃时,对纤维表面仅进行了刻蚀;温度达到60℃时,在纤维表面产生了极性基团,且表面刻蚀和产生极性基团都提高了纤维的黏结性。     

Morphology and mechanical properties of injection‐molded ultrahigh molecular weight polyethylene/polypropylene blends and comparison with compression molding

The mechanical properties and morphology of UHMWPE/PP(80/20) blend molded by injection and compression‐molding were investigated comparatively. The results showed that the injection‐molded part had obviously higher Young's modulus and yield strength, and much lower elongation at break and impact strength, than compression‐molded one. A skin‐core structure was formed during injection molding in which UHMWPE particles elongated highly in the skin and the orientation was much weakened in the core. In the compression‐molded part, the phase morphology was isotropic from the skin to the core section. The difference in consolidation degree between two molded parts that the compression molded part consolidated better than the injection one was also clearly shown. In addition, compositional analysis revealed that there was more PP in the skin than core for the injection‐molded part, whereas opposite case occurred to the compression‐molded one. All these factors together accounted for the different behavior in mechanical properties for two molded parts. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

以DCP和DTBP引发制备交联UHMWPE

分别以DcP和DTBP对UHMWPE进行交联改性,通过改变DcP或DTBP的用量、交联温度、交联时间等成型条件制备了模压烧结试样。结果表明：在DcP交联工艺中,DcP与U删1vPE质量比为0．15％、交联温度为155℃、时间为30min时,制品耐磨粒磨损性能最好;在DTBP交联工艺中,DTBP与UHMWPE质量比为O．50％、交联温度为140℃、时间为20min时,制品耐磨粒磨损性能最好。从改进耐磨粒磨损性能角度来说,采用DTBP交联工艺更好。     

黏度法测试UHMWPE黏均分子量实验过程探讨

研究和分析了黏度法测量UHMWPE黏均分子量过程中各个环节对测试结果的影响,整个操作过程的各种主客观因素都可能引入实验误差,只有严格控制好测试过程中的每一个环节,才能保证测试结果的准确性和可靠性。     

无机填料改性超高分子量聚乙烯性能研究

采用流动改性剂、偶联剂、无机填料等对超高分子量聚乙烯(UHMWPE)进行改性.旨在保持UHMWPE良好的耐磨、耐冲击等性能的基础上,提高材料的熔体流动性,以能通过注塑机注射成型.通过扫描电子显微镜及力学性能测试等确定其改性效果.结果表明,经改性的UHMWPE的熔体流动性有明显提高,但耐磨损性降低(摩擦系数增大).该改性UHMWPE被注塑成机械密封垫,经使用证明材料具有良好的加工性能,但耐磨损性有待进一步提高.     

纤维表面处理对聚乙烯纤维增强PMMA复合材料性能的影响

用液态氧化法对超高分子量聚乙烯纤维进行了表面处理 ,并对其表面形貌进行了SEM观察 ,采用真空浸渍法 ,成功制备出超高分子量聚乙烯纤维增强PMMA复合材料。详细阐述了纤维表面处理对复合材料弯曲 ,冲击性能的影响     

石墨微胶囊改性超高分子量聚乙烯舰船水润滑尾轴承复合材料的摩擦学性能

舰船水润滑尾轴承用超高分子量聚乙烯(UHMWPE)材料在低速重载工况下常出现严重磨损,填充石墨能够提高材料的自润滑性,但会因团聚效应难以共混均匀,将石墨微胶囊化可提高分散性。通过复乳液法制备芯材为石墨、壁材为脲醛树脂的微胶囊,与UHMWPE共混制成复合材料,并制备石墨共混材料作为对照组。在载荷为0.6 MPa、转速分别为150 r/min和250 r/min的工况下测试复合材料的摩擦磨损性能;利用激光干涉表面轮廓仪和扫描电子显微镜观察其磨损面形貌,分析磨损机理。结果表明：石墨微胶囊在基体材料中具有良好的分散性,能够降低材料的摩擦系数并且使摩擦系数变化更为稳定;适量的石墨微胶囊能改善磨损面形貌,降低磨损量;试验中微胶囊含量为5%的材料摩擦学性能最好,150 r/min时摩擦系数为0.110,与纯UHMWPE相比降低了23.61%.     

HDPE-g-GMA对PA6/UHMWPE共混物性能的影响

采用自制甲基丙烯酸缩水甘油酯接枝高密度聚乙烯(HDPE-g-GMA)作为增容剂来增容尼龙6/超高分子量聚乙烯(PA6/UHMWPE)共混物。通过Molau试验、红外光谱分析、扫描电子显微镜观察和物理力学性能测试,研究了HDPE-g-GMA在熔融共混过程中对PA6/UHMWPE共混物的增容作用。结果表明,HDPE-g-GMA与PA6发生化学反应所生成的接枝聚合物对PA6/UHMWPE共混物有较好的增容作用;PA6/UHMWPE共混物的界面形态和力学性能均有较大改善．吸水率也有所降低。     

用于个体防刺服的UHMWPE纤维针刺毡的性能研究

对UHMWPE(超高分子量聚乙烯)纤维针刺毡单层样品的撕破强力、顶破强力和多层样品的抗刺穿能力进行了测试,结果表明:随着单层UHMWPE纤维针刺毡面密度的增加,试样的顶破强力增大;在20~55℃范围内,随着试样预处理温度升高,顶破强力和抗刺穿能力皆增强,但是试样的撕破强力则无这种变化趋势。     

Experimental and theoretical analysis of failure mechanism of UHMWPE Yarn under transverse cut loading

This paper is concerned with transverse cut resistant properties of UHMWPE yarns by the methods of experimental and theoretical analysis. Rheological theory of fabric was applied to evaluate relation of stress and strain of UHMWPE yarn, when the UHMWPE yarn is subjected to external cut force. The dynamic response of yarn and the contact volume of yarn and blade in the cutting have been identified to interpret cut failure mechanism of yarn. The experimental results show that yarn structure, blade edge, and test parameters have great influence on cut resistant property of UHMWPE yarn, and which are consistent with the theoretical analysis. It provides a theoretical basis for quantifying the cutting resistance of fabrics.