金刚石薄膜的人工合成及其结合力的评估

在硬质合金ＷＣ—Ｃｏ基体上，用热丝ＣＶＤ法，人工合成出金刚石薄膜。利用Ｘ衍射、激光拉曼光谱和扫描电镜对金刚石薄膜的结构进行了测定，结果是令人满意的。精确测量金刚石薄膜与基体间的结合力是很困难的。本文报导了金刚石薄膜涂层刀具的实际切削结果，并以此来评估该涂层与基体间的结合力。     

Ni在WC合成过程中加速效应机理的研究

以W—C体系为研究出发点,高能球磨W、活性C和Ni的混合粉末,应用XRD、SEM、化学分析等手段,对球磨产物进行分析。结果发现,在机械合金化合成WC的过程中,Ni能有效的缩短反应时间,捉高反应速率;原因是,在Ni的周围形成了以Ni为中心的微聚团,增大了W和C的接触机率和接触面积,缩短了扩散距离,从而缩短了反应时间。     

Ultrafine porous boron nitride nanofiber-toughened WC composites

Porous fibers are widely used in catalysis chemistry and hydrogen storage but are rarely used in structural ceramics. In this study, spark plasma sintering was used to prepare an ultrafine porous boron nitride nanofiber-toughened WC composite for the first time. The obtained WC-0.05 wt% ultrafine porous boron nitride nanofiber composites exhibited better properties (ie, a 2.3% increase in hardness and a 19.6% increase in fracture toughness) compared to those of the pure WC specimen. The fiber porosity improved the second phase-WC matrix microstructural combination. The described approach is a novel preparation method for the WC composites. Furthermore, a new toughening mechanism, which is based on “pinning and stretching”, was determined. These findings suggest that porous boron nitride fibers can be considered to be second phases for toughening the WC composites.     

Fabrication of novel ZnTe-based photocatalyst: Synergistic effect of dye sensitization and bridge engineering for boosting hydrogen evolution over ZnTe

Herein, a novel ZnTe-based photocatalyst is successfully synthesized via a facile combination of water-bath and hydrothermal processes. Morphology characterization and X-ray diffraction analysis reveal that ZnTe presents irregular granular shape and cubic crystal structure. Moreover, Mott-Schottky measurement shows that the conduction band potential of ZnTe is ?0.84 V (vs NHE). With Eosin Y (EY) sensitization, ZnTe exhibits superior photocatalytic hydrogen evolution activity (223.5 μmol g^?1 h^?1). Meanwhile, WC-ZnTe heterojunction is constructed by depositing ZnTe nanoparticles on bulk WC and obtains the optimal H₂ generation rate (559.1 μmol g^?1 h^?1) under EY sensitization. Electrochemical and photoluminescence results further prove that WC as electron bridge could reduce the interfacial resistance and suppress e^?-h⁺ pairs recombination. This study explores the potential application of ZnTe as a newly active photocatalyst in photocatalytic water splitting, and emphasizes the synergistic effect of dye sensitization and bridge engineering.     

HVOF制备MCrAlY涂层过程中WC杂质颗粒的演变遗传行为研究

在热喷涂工业生产过程中,喷涂制备不同材料体系的涂层之前需要对送粉路径(送粉罐、送粉盘、搅拌器、送粉管路、送粉针)进行清理,但由于送粉路径内部结构复杂且存在静电吸附效应,使得残留于喷涂系统的粉末无法被完全去除,通常以微量杂质颗粒的形式被带入新涂层,进而影响新涂层的性能。为此,本文研究了在单晶基材表面采用高速火焰(HVOF)喷涂制备MCrAlY涂层过程中,送粉路径残留的WC杂质颗粒(WC-10Co4Cr)在涂层及涂层与基材界面处的遗传演变行为,分别采用SEM、EDS分析了WC杂质在喷涂态、热处理态涂层中的微观组织和相组成。研究结果表明,WC杂质颗粒确实存在于MCrAlY涂层中,并在后期热处理及氧化试验中进一步分解而固溶于涂层中,甚至扩散至单晶基材内部引起含W碳化物的生成,影响涂层及单晶基材的显微组织,改变局部的成分均匀性。同时,本文还采用ThermoCalc软件进行了热力学计算模拟,辅助分析了WC分解及W与C元素在显微组织中的遗传特性。对于WC类粉末和MCrAlY粉末共用的HVOF喷涂设备,建议给MCrAlY粉末配备单独的送粉路径,以确保涂层的纯净度与质量。     

Dry Machining Tool Design via Chlorine Ion Implantation

DRY MACHINING is a keyword for manufacturingand production science in the twenty-first century,which requires significant reduction of environmentalburden and COi emission11.In the modern high-speedwet and semi-dry machining processes,huge amountsof lubricants and cleansing agents are wasted in dailyproduction2).Among various proposals aiming at thedry machining3"5>,in-situ formation of tribo-filrns mustbe an important concept to make dry machining tools.Authors have pointed out the impor…     

WC/NiCrSiB复合覆层抗冲蚀气蚀性研究

用氧乙炔焰喷焊法制备了NiCrSiB及其加入WC陶瓷颗粒的复合覆层材料，用光学显微镜分析了覆层的显微组织，并对覆层材料的浆体冲蚀和气蚀抗力进行了研究，用扫描电子显微镜对覆层表面气蚀破坏形貌进行了观察。结果表明：WC／NiCrSiB复合覆层材料不仅抗浆体冲蚀能力比基体材料有了很大的提高，而且耐气蚀性也有一定的提高。最后对覆层材料的浆体冲蚀和气蚀机理进行了分析。     

激光熔覆与激光-感应复合熔覆WC-Ni60A涂层的结构与性能特征

对单纯激光熔覆与激光-感应复合熔覆Ni60A+35%WC涂层的几何外形、稀释率、WC颗粒分布、显微组织与抗干滑动磨损性能进行对比分析。结果表明,单纯激光熔覆的最大激光扫描速度与最大送粉量仅为600 mm.min–1与25 g.min–1,当激光-感应复合熔覆采用相同的工艺参数时,复合熔覆层的宽度、热影响区、稀释率均大于单纯激光熔覆层,厚度却小于单纯激光熔覆层,WC颗粒与析出的碳化物不均匀地分布于复合熔覆层内,复合熔覆层的抗干滑动磨损性能比单纯激光熔覆层的差。但是,激光-感应复合熔覆的最大激光扫描速度可以提高到2 200 mm.min–1,最大送粉量可以提高到75.6 g.min–1,加工效率是单纯激光熔覆的3倍多,复合熔覆层内WC颗粒分布均匀,经检测无裂纹且稀释率仅为5.2%,抗干滑动磨损性能约是单纯激光熔覆层的1.42倍。     

一种利用WC电极的电火花表面改性技术

研究了1种在普通电火花加工机床上实现金属工件表面改性的新方法。它是在传统电火花加工方法的基础上，采用WC烧结体电极和普通煤油工作液，在工件表面形成1层硬质陶瓷层，从而达到改善工件表面性能的目的。系统地对放电沉积原理进行了探讨，在大量试验的基础上，总结了放电沉积的工艺方法。通过扫描电镜、电子探针、X射线衍射分析、摩擦磨损等一系列试验手段，对形成的沉积层特性进行了定量和定性的分析。试验与分析表明，用电火花加工的方法进行表面处理是1种极具潜力的改性方法。     

WC喷焊层对Ni60自熔合金冲蚀磨损机制的影响

在转盘式磨蚀实验台上,对N i60和N i60 35%WC涂层进行冲蚀磨损实验,研究了试验材料的表面失效规律及微观破坏机制。结果表明:2种试样的冲蚀磨损规律相同,分为跑合期和稳定期;由于硬质点WC的加入,使得2种试样的冲蚀磨损机制不一样,但N i60 35%WC涂层的耐冲蚀性能明显高于N i60材料;N i60 35%WC涂层的冲蚀磨损机制主要是剥落坑和疲劳点蚀,而N i60材料主要是微切削和犁沟剥落。