新型重整催化剂的研究——Pt／L中沸石酸碱性的作用

Ｐｔ／ＫＬ、Ｐｔ／ＢａＫＬ及Ｐｔ／ＨＬ上的铂与沸石的酸碱位发生相互作用，导致催化剂上存在不同电子状态和粒度分布的铂位，从而产生有着完全不同催化作用、不同抗硫性能的两类催化剂，即以碱性沸石为载体的“单功能”催化剂和以酸性沸石为载体的“双功能”催化剂。在Ｐｔ／ＫＬ、Ｐｔ／ＢａＫＬ催化剂上，存在着对硫敏感的具有环化脱氢功能和对硫不敏感的仅具有脱氢功能的两类铂活性位。     

国产活性炭在合成气净化中的应用

选择国产Ｋ０１活性炭脱除羰基铁、镍，以达到保护铑催化剂并减少副产物的目的。１年的实际应用结果表明：国产Ｋ０１活性炭能够替代进口活性炭在合成气净化中应用。     

柔性冗余度机器人残余振动主动控制

研究柔性冗余度机器人的残余振动主动控制问题，设计了具有压电作动器与应变传感器的机敏杆件，建立了受控系统的状态空间表达式，采用独立模态空间控制理论设计LQR状态反馈控制器，并基于对偶原理设计了具有指定收敛特性的Luenberger全维状态观测器，最后，以平面3R柔性冗余度机器人为例进行了计算机仿真，结果表明，采用这种主动控制方法可以显著改善柔性冗余度机器人的动力学品质。     

热流法计算高温炉内辐射传热

高温炉内的辐射传热是工业生产中常遇到的问题。过去，人们在应用热流法计算辐射传热时遇到了一定的困难，使计算结果与实际有一定的偏差。本文运用文献［１］中给出的新热流数学模型，开发出由新热流方程与能量方程相耦合的计算机程序，其中的比热流参数由线加热热源情况下计算得到。用该程序计算了实验室用马弗炉内的温度场，并且用热电偶实测了炉内的一些温度值，理论计算与实测值符合很好。     

Advancing controlled release packaging through smart blending

Researchers from Rutgers University and Clemson University have collaborated to develop a concept of using smart blending to generate functional packaging films for the controlled release of active compounds such as antimicrobials, antioxidants and flavour compounds to extend the shelf‐life of food. In this paper, literature results are reviewed to justify the significance of controlled release packaging (CRP) and the research gaps for further development are identified. A major research gap is the lack of packaging materials that can provide the release of active compounds at rates suitable for a wide range of food packaging applications. Smart blending is a promising technology for bridging this research gap. To fully realize the potentials of smart blending, a systematic approach for developing CRP using smart blending is also presented. Copyright © 2005 John Wiley & Sons, Ltd.     

基于二阶矩阵微分方程的机械振动系统线性二次型调节器设计

本文讨论机械振动系统线性二次型状态调节器（LQR）问题，直接针对系统二阶运动微分方程，性能指标为一个依赖于二阶导数的泛函。由欧拉-拉格朗日方程得出一个系统矩阵增广的二阶线性微分方程，指出该方程稳定的特征对就是最优控制振动系统闭环特征对，并给出求解最优控制状态反馈矩阵的方法，另外，由本文方法还可得出基于速度和加速度反馈的最优控制反馈矩阵。这里不涉及求解代数矩阵Riccati方程。     

聚丙烯催化剂的研发进展

综述了用于丙烯聚合的Ziegler-Natta催化剂在给电子体技术及催化剂制备工艺等方面,茂金属催化剂在制备丙烯均聚物、丙烯共聚物及特殊聚丙烯等方面,非茂单活性中心催化剂在丙烯活性聚合、丙烯与极性单体共聚及水介质聚合等方面的研发进展;讨论了聚丙烯催化剂的前景。     

结构滑模控制的一种指数趋近律方法

提出了一种指数趋近律 ,当正常运动段远离切换面时 ,能快速地趋向切换面 ;当运动接近切换面时 ,趋近速度又大大降低。这样与常用指数趋近律相比 ,过渡时间、系统的抖动以及所需控制力都能进一步减小。最后将这一理论应用到三层剪切型框架进行数值模拟 ,振动控制效果明显。     

三种新型流量计在醋酸装置中的应用

阐述了阿牛巴、超声波、电磁等3种流量计的性能特点、选用原则和安装要点。重点分析了低压甲醇羰基化生产醋酸装置中的各种介质的特点如强腐蚀性、两相流、低电导率等,根据不同介质的特点和工艺要求选用不同类型的流量计,并且总结了这些流量计替代原有孔板、涡街、涡轮流量计的实际使用情况以及经验教训。     

Sediment chemistry and nutrient influx in a hydrologically restored bottomland hardwood forest in Midwestern USA

Exchanges of total N and C between a river and its floodplain forest have been enhanced by sedimentation processes during flood pulses at a 5‐ha bottomland hardwood forest located at the Olentangy River Wetland Research Park in central Ohio. In the spring of 2000, the forest was hydrologically restored by notching an artificial levee that had separated the Olentangy River and its floodplain forest for 100 years. One‐hundred flat sediment traps (30 cm × 30 cm) were used to collect sediment samples during spring/summer flooding events from 2003 to 2005. Results showed that sediment deposition is determined by the landscape variability during flooding events, Net sediment deposit in the wettest area averaged 134 ± 12 g‐dry wt m^?2 in 2003, 127 ± 17 g‐dry wt m^?2 in 2004 and 149 ± 23 g‐dry wt m^?2 in 2005. Total N and C sedimentation ranged from 0.49 to 0.92 g‐N m^?2 and 5.2 to 19.9 g‐C m^?2. Fe dominates the sediment chemistry and results show the elemental abundance in the order of Al > Fe > Ca > K > Mg > S > P > Na > Mn > Zn > B > Cu > Mo. A hydrologic pulsing index (HPI) could be used as an indicator for mass changes of energies with hydrologic pulsing events. Restoration of seasonally flooded bottomland forests could stimulate potentially large nutrient and Fe releases, which would eventually lead to an enhanced forest productivity and biodiversity. Copyright © 2007 John Wiley & Sons, Ltd.