化学键性质机械合金化过程中非晶形成能力的影响

研究了Ｂ２型金属间化合物ＦｅＡｌ和ＦｅＴｉ的机械合金化过程，发现的相同的试验条件下，ＦｅＡｌ形成化学无序的固溶体，ＦｅＴｉ形成结构无序的非晶态，此现象可用ＦｅＡｌ的化学键为金属－离子混俣键，而ＦｅＴｉ的化学键为金属－共价－离子混合键来解释。     

A storage heat pump using an ‘ozone-friendly’ refrigerant

The paper describes the integration of a chemical and a vapour-compression heat pump for energy storage applications. The vapour-compression system is designed to operate using the UK cheap rate ‘Economy 7’ electricity tariff. The system is characterized thermodynamically using various refrigerant/absorbent pairs in the chemical storage circuit and an ozone-friendly refrigerant, R134a, in the vapour-compression circuit. Results indicate that the H₂O/Na₂S pair provides a high energy storage density and is the most suitable for use in this system. The paper also describes the design features of a domestic-sized version of this heat pump system. Air in the sunspace (conservatory) of a house was used as a heat source for the heat pump.     

Microstructural Effects of Ion Implantation on Molybdenum

The effects of ion implantation and subsequent annealing on the microstructure of molybdenum have been investigated by transmission electron microscopy. The ions investigated were carbon, nitrogen, and tellurium. The ion-induced damage was found to give rise to grain boundary migration phenomena both during implantation and during subsequent annealing. Precipitation or ordering was found to occur for each ion on annealing.     

Chemical States of Lanthanum in Carbonized La2O3-Mo Thermionic Cathode Materials

The chemical reaction between lanthanum oxide and molybdenum carbide was studied by thermodynamic calcu-lation, thermal analysis and in-situ X-ray Photoelectron Spectroscopy. The theoretical results show that at the environment allowing for the evaporation of lanthanum, such as in high vacuum, La2O3 in the La2O3-Mo materials can be reduced to metallic lanthanum by molybdenum carbide (Mo2C). To confirm the conclusion, many analysis methods such as XRD, SPS, and TG-DTA were taken. The experimental results show that the chemical state of lanthanum changes during heat-ing. It was proved, for the first time, that reacted metallic lanthanum appears at the surface of this kind of material at high temperature.     

化工企业环境因素的评价

化工企业环境因素评价是建立环境管理体系的核心任务，化工企业生产过程的特点决定了其环境因素数量多、环境影响大、识别评价难、控制难度大。本文介绍了化工企业环境因素评价的技术方法和过程，可以为提高环境因素评价的科学性、客观性和充分性提供参考。     

SISAK快速化学分离装置的建立

SISAK(Short-lived Isotopes Studies by the AKUFVE technique)技术是目前使用最广泛的快速化学分离方法之一,主要应用在短寿命核素的分离和鉴别、超重元素的人工合成以及化学性质研究等方面的工作中.本文简单地叙述了SISAK技术的流程、原理和发展现状,介绍了自行建立的国内第一套基于SISAK技术的快速化学分离装置,并通过从裂变产物中分离短寿命核素这一实例验证了SISAK技术在快速化学分离中的优越性.     

山药

山药是一种常用的中药，营养丰富，具有较高的药疗价值，现对山药的化学成分、药理作用、临床应用的研究进展作一介绍。     

弱凝胶调驱降维数值模拟方法研究

目前用于弱凝胶调驱的化学驱软件大多存在计算速度慢、数值弥散现象严重的问题,为了提高弱凝胶调驱数值模拟的速度和精度,提出了降低维数的模拟方法。利用追踪流线的方法,将弱凝胶调驱的三维渗流问题,转化为沿流线计算饱和度的一维问题,大大降低了求解饱和度方程组中方程的数目,从而提高了计算速度。利用该方法,模拟了玉门老君庙油田一个试验井区的水驱开发历史,优化了弱凝胶调驱的注入浓度、注入速度及注入体积等参数,并预测了弱凝胶调驱的动态,预测该方案可提高采收率7.6%。     

焦化生产中含硫容器自燃氧化倾向性分析

分析了炼焦化工生产过程中硫的分布和存在形态、硫铁化合物自燃的影响因素,提出了防止储罐、管道等设备自燃事故的安全控制方法.