烷基化换热器的腐蚀失效分析和防护措施

通过对烷基化车间换热器腐蚀形貌、特征、产物、腐蚀介质、积垢、材料以及换热器流体特性的研究和分析,认为烷基化换热器的腐蚀失效主要由空泡腐蚀和湍流腐蚀引起,并提出了4项防腐蚀措施.经现场应用证明:改变设计或安排辅助管可以有效地减缓冷却管与管板结合部位的严重腐蚀.     

Nucleate Pool Boiling of Pure Liquids and Binary Mixtures：PartI－Analytical Model for Boiling Heat Transfer of Pure Liquids on Smooth Tubes

ＮｕｃｌｅａｔｅＰｏｏｌＢｏｉｌｉｎｇｏｆＰｕｒｅＬｉｑｕｉｄｓａｎｄＢｉｎａｒｙＭｉｘｔｕｒｅｓ：ＰａｒｔＩ－ＡｎａｌｙｔｉｃａｌＭｏｄｅｌｆｏｒＢｏｉｌｉｎｇＨｅａｔＴｒａｎｓｆｅｒｏｆＰｕｒｅＬｉｑｕｉｄｓｏｎＳｍｏｏｔｈＴｕｂｅｓＧｕｏｑｉｎ...     

重Fermi子体系反常比热的理论研究

利用文献中Ｋｏｎｄｏ格子理论模型，研究了重Ｆｅｒｍｉ子体系比热与温度的反常关系。     

用红外热象技术研究有凸台热源倾斜板的散热

本文介绍红外热象技术在工程热物理研究中某些应用的探索。作为实例，通过热象技术，实验研究了具有水平凸台离散热源的倾斜板的散热，在研究它的自然对流换热部份结合利用激光全息干涉技术。此间着重于分析倾斜角对散热的影响。     

热流法计算高温炉内辐射传热

高温炉内的辐射传热是工业生产中常遇到的问题。过去，人们在应用热流法计算辐射传热时遇到了一定的困难，使计算结果与实际有一定的偏差。本文运用文献［１］中给出的新热流数学模型，开发出由新热流方程与能量方程相耦合的计算机程序，其中的比热流参数由线加热热源情况下计算得到。用该程序计算了实验室用马弗炉内的温度场，并且用热电偶实测了炉内的一些温度值，理论计算与实测值符合很好。     

Spray forming: Science and technology

Spray forming involves sequential gas atomization of a melt into a spray of fine droplets and their deposition on a substrate to build up a high-density preform. The rapid solidification inherent in spray deposition generates refined, equiaxed and low segregation microstructures. A number of promising features of this near-net shape manufacturing process are highlighted and compared, wherever possible, with the conventional casting and PM techniques. Some commercial nozzles used to create spray and mechanisms associated with spray generation are described. The consolidation of the droplets and the development of the microstructure in the deposit are primarily governed by the nature of the spray and the thermal state of droplets on the deposition surface. Several microstructural characteristics of the deposit are presented and their origin in spray deposition is discussed.     

Influence of the counter-ion on the effective charge of polyacrylic acid in dilute condition

Osmotic pressure measurements were satisfactorily used to compute the effective charge of poly(acrylic) acid (PAA) at different pHs and with different monovalent and divalent counterions. This experimental method is sensitive to the osmotically active species (polymer and counterions). After correction for the polymer contribution to the total osmotic pressure (solvency and excluded volume), the remaining pressure can be attributed to the polyelectrolyte counterions and processed with Donnan and equation of state in order to compute the effective charge number per polymeric chain (Z^eff). The behavior of Z^eff against the chain concentration and pH was investigated after neutralization of PAA with LiOH, NaOH, and TMAOH. The results clearly indicate that the nature of the monovalent counterion has no effect on Z^eff leading to the conclusion that the interaction between monovalent counterions and the acrylate functionality is purely electrostatic in agreement with conductimetric and potentiometric results reported in the literature. The behavior of Z^eff against the degree of ionization of the polymer and its concentration is also in good agreement with the theoretical expectations of the theory of ionic condensation. Osmotic measurements were also used in order to understand the influence of divalent cations (Mg²⁺, Ca²⁺, Ba²⁺) on Z^eff of the sodium salt of PAA at pH 9 and at different divalent/acrylate molar ratio. All the divalent cations depress Z^eff each of one at different degrees, confirming a specific divalent/polymer interaction. The energy of hydration of cations can explain most of the observed results with divalents.     

用电子自旋共振研究导热油的热稳定性

用电子自旋共振对国内几种典型合成油，基础油及加有添加剂的基础油，分别在不同温度下测定生成自由基的相对浓度，以及一定温度下放置一段时间自由基衰减情况，来考察导热油的热稳定性。     

基底元素表面富集与扩散阻档层

根据An－Ag系统以及An－Cu系统的扩散系数计算，提出了扩散阻挡层模型。利用这个模型对Au－Ag系统进行有关实验，得利了较好的验证。     

Minimizing sample evaporation in the environmental scanning electron microscope

The ElectroScan environmental scanning electron microscope (ESEM) enables wet samples to be observed by eliminating air but allowing water vapour into the sample chamber. However, evaporation from, and condensation on, the sample may occur during the pumpdown sequence used to reach this state, which means that the sample may not be in its natural state when viewed if due care is not taken. In this paper, the pumping system of the ESEM is described mathematically and expressions are derived for the evaporation and condensation. This treatment is then used to calculate the optimum pumpdown sequence. The importance of using the optimized procedure is illustrated by micrographs of fat emulsions.