Recycling of multilayer packaging using a reversible cross-linking adhesive

Plastic-based multilayer packaging has an important function on the packaging market, but is currently not recyclable as the polymer layers used are usually thermodynamically immiscible. This work therefore follows the approach to prepare separable multilayer packaging using a packaging adhesive modified with thermally unstable adducts, and proposes a corresponding recycling process. For this purpose, typical multilayer structures (polyethylene (PE)// polyethylene terephtalate (PET), PET//aluminum, and PE//aluminum) were prepared by curing furan-/maleimide-functionalized polyurethane (PU)-prepolymers with a three-functional cross-linking agent. Adhesions of up to over 3N per 15 mm test specimen were measured or substrate failures of PET films were observed. However, heating in dimethylsulfoxide, the retro-Diels–Alder reaction takes place and the cross-linked adhesive turns thermoplastic and dissolves in the solvent. Thus, the laminate separates and the pure PE, PET, and aluminum foils can be recovered without any PU residue.     

强化研磨加工中喷射角度对GCr15轴承钢板塑性变形的影响

利用ABAQUS有限元仿真软件研究不同喷射角度强化研磨加工GCr15轴承钢板过程的塑性变形,得到不同喷射角度与等效塑性应变沿真实路径距离的关系,并通过拉伸试验进行验证。喷射角度为90°的强化研磨加工伸长率为1.4%,相比未经过强化研磨加工的伸长率数值缩减了2.0%。断口收缩率由空白组的4.9%降低到喷射角为90°的2.2%。结合仿真和试验可知,强化研磨加工中喷射角度越大,塑性变形能力越低,材料加工越难。     

汽车雨挡导流片浮顶式侧抽芯机构注射模设计

介绍了一款汽车雨挡导流片异型塑件两板注射模的结构设计,该模具基于采用常规的滑块抽芯机构及斜顶机构难以实现塑件完全脱模的机构设计困难问题,突破常规设计思路,设计了一种型芯浮顶式侧抽芯机构来实现塑件的自动化注射生产。机构中,在模具开模打开后,通过顶出板及顶杆将塑件和部分成型一同顶出,而后再通过侧边二次顶出机构将塑件从局部型芯上顶出而实现塑件的完全脱模,有效地简化了模具结构设计,降低了模具的加工制造难度,降低了模具的制造成本,模具结构复杂新颖,工作稳定可靠,为异型类塑件的模具结构及机构设计创新设计提供了一个较好的案例借鉴。     

Microstructure,mechanical properties and bio-corrosion properties of Mg-HA bionanocomposites fabricated by a novel severe plastic deformation process

This research investigates the alterations in microstructure, mechanical properties, and corrosion behavior of binary magnesium-hydroxyapatite bionanocomposites with 2, 5, and 10 wt%HA. By mixing Mg and HA powders with different percentages of HA contents, a combined method of cyclic extrusion compression (CEC), equal channel angular pressing (ECAP) and conventional extrusion were employed to consolidate the mixture of powders. All composites were examined. The results indicate that the addition of hydroxyapatite to magnesium improves the mechanical properties, but these properties are deteriorated with the hydroxyapatite content of over 5 wt%. The corrosion behavior of the composites was examined by immersion test, mass loss and polarization tests in Hank’s solution. The results indicate that Mg-5HA exhibits the best corrosion resistance and the corrosion rate increases when the HA content rises to more than 5 wt%. In addition, the specimen produced through the proposed method in this work indicates better corrosion resistance in comparison with cast and extruded pure Mg.     

Measurement of Electrophysiological Signals In Vitro Using High-Performance Organic Electrochemical Transistors

Biological environments use ions in charge transport for information transmission. The properties of mixed electronic and ionic conductivity in organic materials make them ideal candidates to transduce physiological information into electronically processable signals. A device proven to be highly successful in measuring such information is the organic electrochemical transistor (OECT). Previous electrophysiological measurements performed using OECTs show superior signal-to-noise ratios than electrodes at low frequencies. Subsequent development has significantly improved critical performance parameters such as transconductance and response time. Here, interdigitated-electrode OECTs are fabricated on flexible substrates, with one such state-of-the-art device achieving a peak transconductance of 139 mS with a 138 µs response time. The devices are implemented into an array with interconnects suitable for micro-electrocorticographic application and eight architecture variations are compared. The two best-performing arrays are subject to the full electrophysiological spectrum using prerecorded signals. With frequency filtering, kHz-scale frequencies with 10 µV-scale voltages are resolved. This is supported by a novel quantification of the noise, which compares the gate voltage input and drain current output. These results demonstrate that high-performance OECTs can resolve the full electrophysiological spectrum and suggest that superior signal-to-noise ratios could be achieved in high frequency measurements of multiunit activity.     

纳米纤维素的疏水改性及应用研究进展

纳米纤维素作为一种性能优越的可再生纳米材料，应用前景极为广阔。然而，由于纳米纤维素结构上富含羟基，使其具有极强的亲水性，严重影响了纳米纤维素的疏水性能，并且在一定程度上限制了其在复合材料领域的应用。综述了纳米纤维素疏水改性的研究进展，从物理吸附、表面化学修饰（甲硅烷化、烷酰化、酯化等）、聚合物接枝共聚3个方面简述了目前应用较为广泛的疏水化改性方法，并对疏水纳米纤维素在包装材料、造纸、水净化等方面的应用现状进行了总结。最后对疏水改性纳米纤维素的未来发展进行了展望，旨在为疏水纳米纤维素的研究和应用提供参考。     

最大塑性功原理在烧结体上限分析中的应用

最大塑性功原理又称第二塑性变分原理，在致密体塑性变形分析叶l是运用能量法进行变形力能计算的基础。本文从分析Drucker公设的亢要条件出发，证明了烧结体塑性变形最大塑性功原理的存在，片在该原理的荩础卜，推导出塑性变形的上限功率表达式，并以平面挤压条件下的上限法应用作为实例加以说明。     

浅析医药包装

随着市场经济的深入，医药包装正成为我国经济发展的朝阳产业，文中意在介绍先进的医药包装材料。分析其应用情况及发展趋势和动态。     

Inhibition of microbial growth in ready‐to‐eat food stored at ambient temperature by modified atmosphere packaging

This study was undertaken to develop a modified atmosphere package to control microbial growth in ready‐to‐eat (RTE) products stored at ambient temperature. Ethanol and/or limonene associated with modified atmosphere (CO₂ : O₂ : N₂ = 30% : 5% : 65%) was used to inhibit the growth of total air‐borne microorganisms and Escherichia coli in RTE products stored at 25°C. The results indicated that 0.05% ethanol vapour in the headspace was effective to inhibit the growth of air‐borne microorganisms and E. coli at 25°C for 72 h in a model study, and the effectiveness was related to ethanol content. Both 73 ppm limonene and 0.05% ethanol vapour enhanced the bacteriostatic effect of modified atmosphere in RTE sushi roll products, and no off‐flavour was detected using this formulated gas; however, no significant inhibitory effect was observed for RTE cold noodle products. This study concludes that combinations of carbon dioxide, ethanol or limonene vapours are effective to inhibit microbial growth in RTE food at ambient temperature, and the outcome may be due to the hurdle effect. Copyright © 2003 John Wiley & Sons, Ltd.     

低水分抗热震高铝可塑料在加热炉上的应用

用矾土作为主原料,选择适当结合剂和添加剂,引入微粉技术,采用真空炼泥等工艺手段,研制成低水分抗热震高铝可塑料。该制品用作热媒加热炉衬里,显示出良好的耐高温和耐热冲击性能。