Synthesis of TiO<Subscript>2</Subscript> Hybrid Molecular Imprinted Polymer for Ethofumesate Linked by Silane Coupling Agent

TiO₂ hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as testified by UV spectrometric method. KH570 modified TiO₂ nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive adsorption capacity were achieved, which made it promising in chemical sensor applications.     

Clay compaction modelling by homogenization theory

The modelling of hydromechanical behavior of clayey sediments by homogenization theory is described. The rheological model of clays buried in depth requires a three-dimensional approach and laboratory experiments to quantify the model parameters. An iterative process which can be coupled to any homogenization method is used to model the porous media behavior. Hydromechanical compaction results from oedometric experiments are simulated with the proposed model.     

应用金属迭片挠性联轴器改造D1000-32型风机

使用液力偶合器因故障频繁，对高炉稳产、高产造成严重威胁，而且维修费用较高，对偶合器改造后，应用金属迭片挠性联轴器其故障率、维修费用都很低。     

提高塑封双列直插式光耦合器绝缘耐压的设计和工艺要点

介绍了研制出其性能达国际先进公司同类产品水平的塑封双列直插式光耦合器的工作原理和提高绝缘耐压的技术难点，从引线框架设计、加工精度控制、内包封材料选型、理想内包封形状控制、塑封气密性的实现、环境条件的完善等方面讨论了提高绝缘耐压的设计和工艺要点。     

Position synchronization of multiple motion axes with adaptive coupling control

A new control approach to position synchronization of multiple motion axes is developed, by incorporating cross-coupling technology into adaptive control architecture. The control strategy is to stabilize position tracking of each axis while synchronizing its motion with other axes’ motions so that differential position errors amongst axes converge to zero. The proposed adaptive controller and parameter estimator employ coupling control by feeding back position errors and differential position errors, and have been realized to guarantee asymptotic convergence to zero of both position and synchronization errors. Simulations conducted on a multi-axis motion control system demonstrate the effectiveness of the method.     

Applications of the discrete element method in mechanical engineering

Compared to other fields of engineering, in mechanical engineering, the Discrete Element Method (DEM) is not yet a well known method. Nevertheless, there is a variety of simulation problems where the method has obvious advantages due to its meshless nature. For problems where several free bodies can collide and break after having been largely deformed, the DEM is the method of choice. Neighborhood search and collision detection between bodies as well as the separation of large solids into smaller particles are naturally incorporated in the method. The main DEM algorithm consists of a relatively simple loop that basically contains the three substeps contact detection, force computation and integration. However, there exists a large variety of different algorithms to choose the substeps to compose the optimal method for a given problem. In this contribution, we describe the dynamics of particle systems together with appropriate numerical integration schemes and give an overview over different types of particle interactions that can be composed to adapt the method to fit to a given simulation problem. Surface triangulations are used to model complicated, non-convex bodies in contact with particle systems. The capabilities of the method are finally demonstrated by means of application examples. Commemorative Contribution.     

基于压水试验数据的渗透系数应力敏感性研究

岩体渗透率与应力关系是进行岩体渗流应力耦合分析的基础。基于龙滩水电站边坡岩体渗流压水试验结果和边坡岩体岩性及物理力学性质，对岩体渗透系数和地应力进行了分析计算，给出了边坡岩体渗透率随应力变化的关系式，为进行边坡岩体渗流一应力耦合分析提供了可靠数据。     

弹性杆与水下壳体接触冲击的冲击力计算研究

对弹性杆与水下壳体接触冲击问题进行了研究，用有限元法模拟壳体，边界无法模拟无限域流体，通过温面上的耦合条件进行联立求解，文中给出了典型算例，并进行了有关讨论。     

Effects of a Nd—Fe—B magnetic filler on the crystallization of poly(phenylene sulfide)

The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002     

河道溃堤与溃堤波的一、二维耦合计算数值模拟

建立了一维河道溃堤与二维溃堤波耦合计算的水力模型、其中，河道的计算采用一维明渠非恒定流Saint—Venant方程组，求解的过程与溃口的数值模拟耦合；溃堤按渐溃计算，将溃口模拟为梯形，随时间线性增大；溃堤波的计算采用在有限体积无结构网格上建立的TVD—MUSCL格式．模拟算例表明，建立的河道溃堤与溃堤波的一、二维耦合计算水力模型模拟结果比较接近真实溃堤过程．