悬浮液进样FAAS法测定土壤样品中微量锰

采用悬浮液进样火焰原子吸收光谱法(FAAS法)测定土壤样品中微量锰;并对样品的粒度、悬浮液的浓度、介质酸度、校正方法及抗干扰等进行了探讨.结果表明,本法简便、快速、准确可靠.     

Preparation and characterization of novel poly(glycidyl methacrylate) beads carrying amidoxime groups

Poly(glycidyl methacrylate) (PGMA) beads with an average size of 350 μm were synthesized by suspension polymerization technique. The PGMA beads were first modified with iminodiacetonitrile (IDAN). Then, the IDAN‐modified beads were subsequently modified by hydroxylamine. The IDAN modification and the conversion of the nitrile groups to amidoxime were followed by FT‐IR spectroscopy. The surface morphology and thermal behavior of the PGMA and its modified forms were also characterized by scanning electron microscopy and thermogravimetric analysis techniques, further confirming modification and amidoximation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Preparation and application of polybenzoxazine adsorption resin

The synthesis and application of polybenzoxazine adsorption resin was studied. First, the precursor was synthesized by the solventless method. And then a kind of spherical and granular polybenzoxazine resin was obtained using reverse‐phase suspension polymerization technique in the process of solidification. Besides, the influence of dispersion medium, the volume ratio of precursor to medium, the solidification temperature, and the agitation speed were studied in detail in the process of polymerization. Second, the spherical shape of the polybenzoxazine resin was identified by scanning electronic microscope and the thermal stability of resin was measured by thermogravimetric analysis. Finally, the adsorption capacity of the spherical resin on pyridine was studied in cyclohexane systems. The correlation coefficient of Langmuir adsorption constant temperature line was bigger than 0.99, which indicated that the equilibrium sorption date was coincident with the Langmuir isotherm equation. And the saturated adsorptive capacity of dried resin achieved 222.2 mg g^?1. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Synthesis of syndiotacticity‐rich high molecular weight poly(vinyl alcohol) by suspension polymerization of vinyl pivalate and saponification

Vinyl pivalate (VPi) was suspension‐polymerized to synthesize high molecular weight (HMW) poly(vinyl pivalate) (PVPi) with a high conversion above 95% for a precursor of syndiotacticity‐rich HMW poly(vinyl alcohol) (PVA). Also, the effects of the polymerization conditions on the conversion, molecular weight, and degree of branching (DB) of PVPi and PVA prepared by the saponification of PVPi were investigated. Bulk polymerization was slightly superior to suspension polymerization in increasing the molecular weight of PVA. On the other hand, the latter was absolutely superior to the former in increasing the conversion of the polymer, indicating that the suspension polymerization rate of VPi was faster than that of the bulk one. These effects could be explained by a kinetic order of a 2,2′‐azobis(2,4‐dimethylvaleronitrile) concentration calculated by the initial rate method. Suspension polymerization of VPi at 55°C by controlling various polymerization factors proved to be successful in preparing PVA of HMW [number‐average degree of polymerization (P_n): 8200–10,500], high syndiotactic diad content (58%), and very high yield (ultimate conversion of VPi into PVPi: 94–98%). In the case of the bulk polymerization of VPi at the same conditions, the maximum P_n and conversion of 10,700–11,800 and 32–43% were obtained, respectively. The DB was lower and the P_n was higher with PVA prepared from PVPi polymerized at lower initiator concentrations. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 832–839, 2003     

甲醇在聚苯胺修饰铂钼共沉积电极上的催化氧化

用恒电位法和循环伏安法在铂电极上分别制备了聚苯胺修饰的分散氢钼青铜电极和分散铂电极,以及聚苯胺修饰的不同铂钼比例的铂与氢钼青铜共沉积电极。用循环伏安法研究了制备电极在c(H2SO4)=0.5mol/L水溶液中的电化学行为,以及对c(CH3OH)=0.1 mol/L的催化氧化行为。其中,分散氢钼青铜电极对甲醇无催化氧化的作用,铂与氢钼青铜共沉积电极对甲醇的催化氧化效果优于分散铂电极。铂-氢钼青铜共沉积电极对甲醇氧化的催化能力与共沉积铂钼的比例有关,当制备电极所用的溶液中n(氯铂酸)∶n(钼酸钠)=2∶1时,共沉积电极对甲醇的催化氧化活性最高,此时甲醇在共沉积电极上的氧化峰电流是单纯铂电极的2.632倍。     

室式分离机转鼓结构的改进与液流分析

介绍了室式分离机的转鼓结构及工作过程．为提高这种机器的分离效率,重点对室式分离机的转鼓结构做了改进．通过对室式分离机改进型转鼓中悬浮液的流动速度进行分析,为实现不停机自动排渣提供理论基础．     

汽车悬架最优控制与半主动控制研究

基于1/4汽车悬架为控制对象,建立了汽车悬架动力学模型.以线性二次型最优（LQG）控制和改进后的半主动开关（on-off）控制为控制策略,在MATLAB/Simulink软件平台上进行仿真.与被动悬架比较,采用正弦激励下的频域分析和随机路面激励下的时域分析,证明了LQG控制和半主动开关控制在汽车控制工程中的可行性.     

悬挂式重力补偿系统精密跟踪方法

介绍了一种用于研究空间机器人微重力条件下的工作特性的悬挂系统——悬挂式重力补偿系统,并给出了悬挂模块的动力学模型.通过数值求解与仿真,运用非线性规化求出了一定条件下的最优控制参数;用正交试验寻优、基于时间最优控制的试凑法证明了优化模型的解正确性.该研究为空间机器人地面试验系统模拟微重力环境下精密跟踪运动提供了最优控制方法.     

预张力悬索桥及其静力学性能分析

为从理论上获得预张力悬索桥的力学特性,利用大位移不完全广义势能变分原理,建立了预张力悬索桥的一般基础微分方程.在进一步引入假设条件下,导出了基于古典挠度理论的平衡微分方程.通过对微分方程的解析,讨论了预张力悬索桥的静力学特性及其与普通悬索桥的区别.结合算例悬索桥的数值分析表明,预张力悬索桥由于抗风索的存在,以及结构中建立的预张力,在提高结构刚度、减小加劲梁弯矩等方面具有一定的优越性.     

改进型Boussinesq方程高精度紧致差分显格式

采用一种高精度的紧致差分显格式对改进型Boussinesq方程进行数值求解;采用具有TVD性质的三阶Runge-Kutta方法进行预报,用三次样条函数进行校正,时间精度可达到四阶;在空间离散上采用六阶精度的三点紧致显格式进行计算;运用以上数值格式对Beji和Nadaoka改进型Boussinesq方程进行了求解,求解证明:高精度的数值结果和已知的试验结果吻合良好.作为验证算例,同时对波浪在台阶上的传播进行了模拟,从效果对比上可以看出,所得结果明显比Kittitanasuan的计算结果更靠近试验值.