Mg-Al-Zn（RE）镁合金轧制变形行为及强化机制

针对典型的Mg-Al-Zn系AZ31变形镁合金以及添加了0．8％Ce和0．8％Nd的AZ31镁合金，研究了合金在轧制加工过程中组织与性能的变化以及稀土元素对合金的影响，并探讨了合金的主要强化机制。结果表明：Mg-Al-Zn系合金轧制加工过程中加丁硬化严重，容易发生脆性断裂。添加稀土元素后的合金强度和塑性都有明显提高，稀土元素可形成Al4ce等含稀土化合物，起到细晶强化和第二相强化作用。     

我国铸造有色合金及其特种铸造技术发展现状

结合我国在铸造有色合金领域的发展概况,从合金发展、应用和有色合金熔体技术以及特种铸造在有色合金中的应用角度,分析了五十年来我国在该领域所取得的成绩和存在的问题,以引起广大科技工作者和生产技术人员对这方面自主创新的重视,不断提高铸造有色合金的技术水平,扩大其应用领域。     

THE APPARENT VISCOSITY OF SEMI-SOLID AZ91D ALLOY AT STEADY STATE

The rheological behavior of semi-solid AZ91D at steady state is studied using a Couette type viscometer in the present paper. The results show that the apparent viscosity of semi-solid AZ91D at the steady state increases with the solid fraction increasing, and goes up sharply when the solid fraction reaches a certain value, which is called critical fraction. In addition, the apparent viscosity of semi-solid AZ91D at the steady state takes on a distinct downtrend with the shearing rate increasing, which indicates a strong shear thinning property. In addition, the critical solid fraction becomes higher under larger shearing rate, owing to the more globular shape of the solid particles. Based on the present experiment results, an empirical equation is built as that, relating the steady state apparent viscosity of semi-solid AZ91D with the solid fraction fs andshearing rate (?) at the same time: ηapp=10.74exp(6.95fs)(?)-0.86.     

Preparation and hydrogen sorption properties of Mg-Cu-Y-H systems

Mg-xwt.%CuY (x=15, 20, 25) composites were successfully prepared by reactive mechanical alloying (RMA).X-ray diffraction (XRD) measurement shows that main phases of the as milled composites are MgH2 and Mg2Cu, and they converted into Mg and MgCu2 after dehydrogenation, respectively.Pressure-Composition-Isotherm (PCI) test shows that the composites exhibit double pressure plateau at each isothermal desorption process.The hydrogen absorption and desorption kinetics of the composites become worse with increasing x content, indicating that Mg-Cu phase has a negative effect on the hydrogen sorption properties of the composites.It is supposed that the good hydrogen sorption properties of the composites attribute to the catalyst effect of yttrium hydride distributed in Mg substrate and the particles size reduction and crystal defects formed by RMA.     

AZ91D合金微弧氧化中金属型试样与触变成形试样的电参数对比

通过对两种不同加工工艺(金属型铸造、触变成形)AZ91D镁合金在完全相同电解液中进行的两组相同的微弧氧化实验,研究基材对微弧氧化过程的影响,探索电流-处理时间的变化规律。实验证明,基体对微弧氧化过程的起弧电压及电流-时间变化曲线有明显影响,但对膜层厚度、孔隙率及电流-时间变化曲线的影响不大。电流在整个实验过程中呈波浪形减小,并最终伴随二次起弧的发生。短时间、大电流的方法可以生成一定厚度的致密陶瓷层(20～30μm),表面光洁度较高,而且有利于节能。两组实验的实验现象无明显差异。     

TRPM7-Mediated Calcium Transport in HAT-7 Ameloblasts

TRPM7 plays an important role in cellular Ca²⁺, Zn²⁺ and Mg²⁺ homeostasis. TRPM7 channels are abundantly expressed in ameloblasts and, in the absence of TRPM7, dental enamel is hypomineralized. The potential role of TRPM7 channels in Ca²⁺ transport during amelogenesis was investigated in the HAT-7 rat ameloblast cell line. The cells showed strong TRPM7 mRNA and protein expression. Characteristic TRPM7 transmembrane currents were observed, which increased in the absence of intracellular Mg²⁺ ([Mg²⁺]_i), were reduced by elevated [Mg²⁺]_i, and were inhibited by the TRPM7 inhibitors NS8593 and FTY720. Mibefradil evoked similar currents, which were suppressed by elevated [Mg²⁺]_i, reducing extracellular pH stimulated transmembrane currents, which were inhibited by FTY720. Naltriben and mibefradil both evoked Ca²⁺ influx, which was further enhanced by the acidic intracellular conditions. The SOCE inhibitor BTP2 blocked Ca²⁺ entry induced by naltriben but not by mibefradil. Thus, in HAT-7 cells, TRPM7 may serves both as a potential modulator of Orai-dependent Ca²⁺ uptake and as an independent Ca²⁺ entry pathway sensitive to pH. Therefore, TRPM7 may contribute directly to transepithelial Ca²⁺ transport in amelogenesis.     

青海镁产业专利导航发展分析

通过对盐湖提镁技术与镁合金等重点技术的专利分析,得到全球镁产业链不同环节的技术优势国家;从镁合金的专利权人排名来看,日本和韩国的企业展现出优势;基于专利权人的分析,挖掘中国镁技术领域的主要研究团队等重要情报信息;通过对中国及青海镁产业的专利布局分析,确定中国镁产业技术优势省、相关研发机构,总结青海省在镁产业领域的当前水平与可能的突破点,对镁产业关键技术进行导航探究,深度剖析镁产业研究价值与发展空间。同时对青海盐湖产业发展的优劣势条件进行分析,提出青海镁产业未来发展应该结合本地特色增加专利申请量,综合开发利用资源,提升关键技术,加强人才引进,促进产学研深度融合等发展建议。     

六水氯化镁在六种多元醇中溶解度的测定和关联

六水氯化镁的溶解度是镁盐综合利用的重要基础数据。采用静态平衡法测定了六水氯化镁在1,2-丙二醇、1,3-丙二醇、1,3-丁二醇、一缩二乙二醇、二缩三乙二醇、一缩二丙二醇6种多元醇中的溶解度（278.15~328.15 K）。实验结果表明,六水氯化镁在6种多元醇中的溶解度均随着温度的升高而增大,其中在一缩二乙二醇中的溶解度最大,在二缩三乙二醇中的溶解度随着温度的变化较其他多元醇变化更为明显。使用Apelblat方程、λh方程、Van′t Hoff方程和多项式方程对溶解度数据进行了关联,结果良好,其中Apelblat方程和多项式方程拟合结果优于其他方程。利用Van′t Hoff方程计算了6种体系的溶解焓、溶解熵和吉布斯自由能。这些结果对镁盐的分离提取及镁基功能材料的制备具有重要的参考价值。