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81.
82.
83.
Wagner's criterion to predict the minimum concentration of solute (N
B(min)
0
)necessary for the exclusive formation of its scale has been modified to incorporate both thermodynamic and kinetics requirements. The analysis presented here involves a receding alloy/scale interface for which the composition of the alloy at this interface is governed by thermodynamic equilibrium between the two competing scale phases and the base alloy. This is a more rigorous analysis than that of Wagner's, who assumed the alloy/scale interface to be immobile and the solute composition at the interface to be zero. A comparison is made between values of N
B(min)
0
found experimentally and those predicted by Wagner's and the present criterion for a number of alloy-gas systems. It is shown that the criterion developed in the present analysis can often provide a better approximation of the actual N
B(min)
0
.The expressions derived from the present analysis have been extended also in a semiquantitative manner to provide a criterion for the minimum amount of solute in the alloy required for the transition from internal to external scale formation. 相似文献
84.
甲基偶氮四唑热稳定性和热分解机理的量子化学研究 总被引:2,自引:0,他引:2
采用量子化学方法全优化计算了1—甲基—5—偶氮四唑(1—MAT)和2—甲基—5—偶氮四唑(2—MAT)热分解反应位能曲线,探讨了热稳定性和分解机理。热分解活化能计算值分别为245.9,183.2k/mo1,静态分子结构和动态分解性质都显示出1—MAT比2—MAT有更好的热稳定性。裂解优先以开环方式发生。 相似文献
85.
本工作是在非离子凝胶的分子热力学模型基础,引入Donnan平衡项和大分子离子链的静电排斥项对凝胶自由能的贡献,建立了一个新的离子凝胶的分子热力学模型。该模型在解释离子凝胶的PH敏感性及其各种影响因素,以及预测PH溶胀曲线方面都取得了较好的效果。 相似文献
86.
加压热煤气脱硫工艺研究 总被引:2,自引:0,他引:2
介绍了加压热煤气脱硫“北京煤化-SMOVEN”工艺以及工艺研究试验的主要结果。热煤气脱硫小型连续试验装置投入稳定运行,取得了较好的结果,试验验证了SMOVEN工艺的技术合理性和操作可行性,为其工艺放大研究打下良好基础。 相似文献
87.
Miscibility between acrylic copolymers and tackifier resins are investigated in terms of phase diagrams, and the probe tack of the blends are measured as a function of both temperature and rate of separation in order to obtain the master curves. It is found that the probe tack of the pressure sensitive adhesives are closely related to the miscibility between the components. The master curves of the miscible blends shift along the X(rate)-axis according to the change of Tg of the bulk materials with a gradual variation of the peak heights. However, those of the immiscible blends will not shift along the X(rate)-axis, but the magnitude will decrease with increase of a dispersed phase. 相似文献
88.
The viscoelastic and peeling properties of polybutadiene/tackifying resin compatible blends have been studied in detail. Viscoelastic properties have been described through the variations of the complex shear modulus, G*(ω), as a function of frequency, ω and peeling properties through the variations of peeling force (F) as a function of peeling rate (V).
After showing the objective character of the peeling curves obtained, the variations of the peeling force and peeling geometry have been studied as a function of volume fraction of the tackifying resin.
In this first paper, the analysis is focused on the first domain of the peeling curves, i.e. the cohesive fracture region. In this region, the peeling properties have been related to the viscoelastic properties in the terminal region of relaxation. It is shown that the longest relaxation time, τo, is a reducing parameter of the peeling curves, so a peeling master curve-which is independent of temperature, resin volume fraction and polymer molecular weight-may be defined. Furthermore, the variations of the test geometry as a function of peeling rate have been investigated: the variations of the radius of curvature of the aluminium foil have been analyzed with respect to the viscoelastic behavior of the adhesive, which in fact governs the test geometry.
A detailed analysis of all these features leads to a model which allows one to calculate the peeling curves in the cohesive domain from the adhesive formulation. 相似文献
After showing the objective character of the peeling curves obtained, the variations of the peeling force and peeling geometry have been studied as a function of volume fraction of the tackifying resin.
In this first paper, the analysis is focused on the first domain of the peeling curves, i.e. the cohesive fracture region. In this region, the peeling properties have been related to the viscoelastic properties in the terminal region of relaxation. It is shown that the longest relaxation time, τo, is a reducing parameter of the peeling curves, so a peeling master curve-which is independent of temperature, resin volume fraction and polymer molecular weight-may be defined. Furthermore, the variations of the test geometry as a function of peeling rate have been investigated: the variations of the radius of curvature of the aluminium foil have been analyzed with respect to the viscoelastic behavior of the adhesive, which in fact governs the test geometry.
A detailed analysis of all these features leads to a model which allows one to calculate the peeling curves in the cohesive domain from the adhesive formulation. 相似文献
89.
Optimization of reactive SMB and Varicol systems 总被引:2,自引:0,他引:2
Hariprasad J. Subramani Kus Hidajat Ajay K. Ray 《Computers & Chemical Engineering》2003,27(12):1883-1901
A comprehensive optimization study on a simulated moving bed reactor (SMBR) system is reported in this article for the direct synthesis of methyl tertiary butyl ether (MTBE) from tertiary butyl alcohol (TBA) and methanol. The applicability of the Varicol process, which is based on non-synchronous shift of the inlet and outlet ports, is explored for the first time for a reactive system. Multi-objective (two and three objective functions) optimization has been performed for both existing as well as design stage for SMBR and Varicol systems and their efficiencies are compared. The optimization problem involves relatively large number of decision variables; both continuous variables, such as flow rates in various sections and length of the columns and discrete variables, such as number of columns and column configuration. Pareto optimal solutions are obtained. It is observed that a five-column Varicol performs better than an equivalent five-column SMBR and its performance is nearly equal to that of a six-column SMBR in terms of purity and yield of MTBE and minimal eluent consumption. This is an important inference as it enables the reduction of fixed and operating costs while at the same time helps to achieve high purity and yield of the desired product and conversion of the limiting reactant. A state-of-the-art optimization technique, viz., non-dominated sorting genetic algorithm (NSGA), which allows handling of these complex optimization problems, is employed for this study. This is the first time that, not only the separating potential of Varicol has been extended to reaction systems, but also was optimized for multiple objectives. 相似文献
90.
强震区土石坝筑坝材料动力特性试验研究(投稿研究生论坛) 总被引:1,自引:0,他引:1
土石坝筑坝材料的动力特性是进行坝工设计和动力评价的基础。以西部强震区某土石坝工程为研究对象,采用室内动三轴试验,对其坝壳料、心墙料和坝基断层料进行动力特性试验研究,并以Hardin-Drnevich模型为基础,确定筑坝材料的动弹模、阻尼比等特性参数,试验表明:在动应变在10-6 ~ 10-5 范围内,动模量与围压、固结比成正相关;随动模量的增大,相关性降低;动应变和振级的拟合指数模型则表明不同围压、固结比的心墙料的应变-振级曲线趋势一致,坝壳料较为离散;试验中固结围压对粗骨料阻尼比-应变曲线的影响较固结比大,可为强震区土石坝的动力稳定评价提供可靠的理论依据。 相似文献