One-step formation of ethyl methyl ketone from 1-butene and water on ultrastable Y-type zeolite catalyst

Proton exchanged ultrastable Y-type zeolite with silica/alumina = 40 showed a pronounced catalytic activity for the formation of ethyl methyl ketone directly from 1-butene and water. The formation rate of ethyl methyl ketone was much higher than those on MoO₃-based catalysts in the oxidation of 1-butene by oxygen. It was suggested that the basic site necessary for the formation of ethyl ketone directly from 1-butene and water would be the pentacoordinated Al.     

铝合金6061在低硫酸浓度硬质氧化过程中氧化膜微观组织的演变

采用自制的阳极氧化试验装置和扫描电子显微镜分别对铝合金6061在硫酸浓度为1%、2%、3%、4%和5%H2SO4(W t.%)的氧化液中形成的硬质阳极氧化膜进行研究。结果表明:随着硫酸浓度的增大,氧化膜的显微硬度和表面粗糙度降低,氧化膜中的孔洞逐渐变大;与硫酸浓度为1%和2%相比,3%左右硫酸浓度的氧化液所得到的氧化膜的均匀程度较好,以3%左右硫酸浓度的氧化液对铝合金6061进行硬质氧化较为理想。     

Deformation behavior and microstructure of an Al-Zn-Mg-Cu-Zr alloy during hot deformation

The hot deformation behavior and microstructures of Al-7055 commercial alloy were investigated by axisymmetric hot compression at temperatures ranging from 300°C to 450°C and strain rates from 10-2 to 10 s-1,respectively.Microstructures of deformed 7055 alloy were investigated by transmission electron microscopy (TEM).The dependence of peak stress on deformation temperature and strain rate can be expressed by the hyperbolic-sine type equation.The hot deformation activation energy of the alloy is 146 kJ/mol....     

Microscopic characterization of semi-solid aluminium alloys

The microstructural evolution and element distribution of the Al-4Cu-Mg alloy during semi-solid compression were investigated,and the precipitate behavior and dislocation morphology were discussed.The experimental results show that the microstructure,the number of CuAl2(θ phase) precipitates,and the dislocation density of the Al-4Cu-Mg alloy depend apparently on the process parameters.More segregation of Cu at the grain boundary happens with an increase of deformation temperature and a decrease of strain ra...     

工业纯铝在模拟海水中的电化学腐蚀行为

为研究铝在海水中的腐蚀过程,采用电化学阻抗谱、浸泡试验、扫描电子显微镜研究工业纯铝在模拟海水中的腐蚀行为.结果表明:铝在模拟海水中发生点蚀的区域为富含Fe的晶间化合物处,点蚀半径随时间的增加而扩大.铝在模拟海水中的溶解曲线分为4个区间:活性溶解区、过渡区、过钝化区、钝化区.铝在模拟海水中,极化电位为过钝化区时,转移电阻R t随着电位的升高而变小,铝发生严重的点蚀;而极化电位为钝化区时,铝的转移电阻R t随着电位的升高基本不变,铝的溶解行为受到抑制.工业纯铝在模拟海水中发生点蚀的电位区间是-0.45～-0.65 V,钝化电位区间为-0.75～-0.85 V.     

Numerical simulation on the rheo-diecasting of the semi-solid A356 aluminum alloy

The effect of injection pressure, piston velocity, and the forming temperature of semisolid slurry on the filling behavior of the semi-solid A356 aluminum alloy was investigated by simulation methods. The simulation results show that these processing parameters have an important effect on the filling behavior of the semi-solid A356 aluminum alloy. The slurry flows steadily in the cavity when the injection pressure, the piston velocity, and the forming temperature are low, but it is prone to turbulent flow w...     

Microstructural characterization of as-cast and homogenized 2D70 aluminum alloy

The microstructure of the as-cast 2D70 aluminum alloy and its evolution during homogenization were investigated by means of optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and differential scanning calorimetry (DSC) analysis. The results indicate that the microstructure of the as-cast 2D70 aluminum alloy mainly consists of the dendritic network of aluminum solid solution and intermetallic compounds (Al2CuMg, Al2Cu, Al9FeNi, Cu2FeAl7...     

我国铝土矿资源开发利用现状及其产业研究

矿产资源是人类社会进步与经济发展的重要物质基础,也是可持续发展不可缺乏的重要资源,它的不可再生性和发展的可持续性要求我们必须以最小的能源消耗来实现最大化的经济发展.作者以铝土矿为例,对其资源开发利用情况及产业发展现状进行了研究.     

苯甲酰丙烯酸乙酯中主要杂质的定性分析与转化

顺丁烯二酸酐与苯在三氯化铝的存在下,经傅-克反应生成苯甲酰丙烯酸,在强酸性水介质中,若温度高于35℃,则部分发生与水的加成反应生成苯甲酰乳酸。含苯甲酰乳酸的苯甲酰丙烯酸在浓硫酸的存在下与无水乙醇反应,可分别生成苯甲酰丙烯酸乙酯和苯甲酰乳酸乙酯。而苯甲酰乳酸乙酯在二甲苯中回流可脱去一分子水而转变为苯甲酰丙烯酸乙酯,从而使苯甲酰丙烯酸乙酯的纯度从85%提高到93%。