LOSA-1增产丙烯助剂的工业应用

文中介绍了在重油催化裂化装置应用LOSA-1增产丙烯助剂,使液化气收率提高1%,丙烯收率提高2.46%的使用过程和效果.LOSA-1增产丙烯助剂在工业装置应用后达到了增加丙烯产量、提高装置经济效益的目的.     

Paste Residence Time in a Spouted Bed Dryer. III: Effect of Paste Properties and Quality Interactions

The aim of this study was to evaluate the effects of paste properties on residence time during drying in a spouted bed dryer with inert bodies. The effect of paste solids content, surface tension, and viscosity on the residence time distribution and the mean residence times were studied using factorial experimental designs. The inert bodies used were glass and polyethylene beads. The mean residence times varied from 13.6 to 16.3 and 12.2 to 17.7 min for drying on glass and polyethylene beads, respectively. The analysis of variance showed that mean residence times significantly depended on solids content and surface tension for glass beads and also on viscosity for polyethylene beads. The residence time distributions for all conditions studied fitted well to the perfect mixing cell when applying the continuous stirred vessels in series model analysis. The powder density, flowability, and particle size depended on paste properties and inert type.     

饱和软土天然含水量估算指标及ω一e回归方程的建立

天然含水量ω是土的最基本物理量指标之一。采用数理统计方法，建立经验方程来修正土的天然含水量ω的测定值，使修正后的天然含水量数值与实际中的真值符合程度更为接近，效果甚好。     

350m~3高炉煤气净化单文氏管可调喉口理论计算及分析

通过单文氏管可调喉口的理论计算及分析，找出喉口最佳工作状态下的工艺参数及适合这种设备特性的煤气工作参被变化范围，以期能对实际操作过程及运行状态分析提供理论依据，提出单文氏可调喉口在更广泛意义上的设备、工艺参数选择、计算的方法。     

Preparation and characterization of polyurethane microcapsules containing n‐octadecane with styrene‐maleic anhydride as a surfactant by interfacial polycondensation

A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the T_m and T_c of microPCMs were in the range of 29.8–31.0^oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006     

A New Variable Diffusion Drying Model for the Second Falling Rate Period of Paddy Dried in a Rapid Bin Dryer

The objectives of this article is to propose a new drying model for the second falling rate period known as the variable diffusion controlled period that follows after the first falling rate period and to propose a new method to determine the second critical moisture content that separates these two periods. Experimental work on paddy drying at minimum fluidization velocity was carried out in a rapid bin dryer. The effects of operating temperatures (60-120°C) and bed depths (2-6 cm) on the paddy drying characteristics were investigated. It was found that the normalized drying rate of paddy was proportional to the normalized moisture content in the first falling rate period but in the second falling rate period, the normalized drying rate of the material varies exponentially with the normalized moisture content. The different relationship between the normalized drying rate and the normalized moisture content in the first and second falling rate periods indicate that two different mechanism of moisture transport are at work. The new exponential model of the second falling rate period and the linear model of the first falling rate period were found to fit the experimental data very well. Derivation from variable diffusion equation shows that the linear model is the result of constant diffusion coefficient whereas the new exponential model is the result of linear diffusion coefficient. This also implies that the first falling rate period is a constant diffusion controlled period and the second falling rate period is a variable diffusion controlled period. In addition, drying kinetics data of a drying process that fits the exponential model over a very slow drying period will show that the drying process is under the effect of a linear diffusion coefficient. It was also found that the proposed new method to determine the second critical moisture content that distinguishes between the first and second falling rate periods by using a sudden change in the value of the drying rate gradient to a much lower value at that point is more rigorous and yet simpler than the method of determining the specific location of the receding drying boundary since it is based on the behavior of the actual drying kinetic data.     

Formation of low-resistivity poly-Si and SiNx films by Cat-CVD for ULSI application

In this paper, bulk-Si metal–oxide–semiconductor field effect transistors (MOSFETs) are fabricated using the catalytic chemical vapor deposition (Cat-CVD) method as an alternative technology to the conventional high-temperature thermal chemical vapor deposition. Particularly, formation of low-resistivity phosphorus (P)-doped poly-Si films is attempted by using Cat-CVD-deposited amorphous silicon (a-Si) films and successive rapid thermal annealing (RTA) of them. Even after RTA processes, neither peeling nor bubbling are observed, since hydrogen contents in Cat-CVD a-Si films can be as low as 1.1%. Both the crystallization and low resistivity of 0.004 Ω·cm are realized by RTA at 1000 °C for only 5 s. It is also revealed that Cat-CVD SiN_x films prepared at 250 °C show excellent oxidation resistance, when the thickness of films is larger than approximately 10 nm for wet O₂ oxidation at 1100 °C. It is found that the thickness required to stop oxygen penetration is equivalent to that for thermal CVD SiN_x prepared at 750 °C. Finally, complementary MOSFETs (CMOSs) of single-crystalline Si were fabricated by using Cat-CVD poly-Si for gate electrodes and SiN_x films for masks of local oxidation of silicon (LOCOS). At 3.3 V operation, less than 1.0 pA μm⁻¹ of OFF leakage current and ON/OFF ratio of 10⁷–10⁸ are realized, i.e. the devices can operate similarly to conventional thermal CVD process.     

深基坑施工安全的监测与实例

从明确深基坑施工安全监测的关键出发，确定了监测内容和相关极限报警值，用工程实例进行了阐述。     

The Content Driven Mobile Internet

The development of future mobile networks will be driven, in large part, by content and web based services. In this paper, we examine several performance, scalability and architectural challenges faced by future mobile web applications and how advanced mobile content delivery techniques can address these challenges. We review existing content delivery using a taxonomy that consists of three categories: network scaling, end system acceleration, and content and protocol optimization. While wireline content delivery focuses on network and server scalability, mobile content delivery will likely benefit most from optimizing radio link usage. We also present our ongoing work in this area, which extends the functionality of edge caching to the terminal, uses user interest correlation information to maintain low terminal power consumption and adds a new dimension to radio resource management. This revised version was published online in August 2006 with corrections to the Cover Date.     

新型内循环石油焦燃烧器烧焦管内颗粒流动特性

针对石油焦及其气化余焦的燃烧和流化特性,自建了冷态实验装置。以石英砂颗粒作为固体物料,常温空气为流化介质,在烧焦管内表观气速为3.07~6.63 m/s,颗粒循环强度为24.7~154.2 kg/(m2.s)的条件下,采用DDY型差压变送器和脉冲磷光颗粒示踪法分别测量了烧焦管内的床层轴向平均固含率分布和颗粒停留时间分布规律。结果表明,当表观气速为3.96 m/s时,随着颗粒循环强度的提高,烧焦管相同高度处平均固含率分布增大;当颗粒循环强度为106.5 kg/(m2.s)时,随着烧焦管内表观气速的提高,烧焦管整个高度上的平均固含率分布减小。烧焦管内颗粒的扩散由弥散颗粒扩散和颗粒团扩散组成。建立了烧焦管内床层轴向平均固含率关联式及颗粒的轴向扩散模型,模型的计算值与实验值能较好地吻合。