牛物法PDO合成PTT结构与性能的研究

采用生物法1，3-丙二醇（PDO）直接酯化缩聚合成聚对苯二甲酸丙二醇酯（PTT），通过IR、^1H NMR、DSC和TG方法对其进行了表征，并与化学法PDO合成的PTT进行比较。结果表明，生物法PDO合成的产物是PTT；生物法PDO合成的肿比同一纯度的化学法PDO合成的肿色泽好、粘度大、摩尔质量高，且随PDO纯度提高，肿粘度、摩尔质量增大；生物法PDO合成的肿熔点与化学法PDO合成的肿相差不大，熔融峰比化学法PDO合成的肿尖锐，熔融热大，结晶度高；不同PDO合成的肿树脂热失重相差不大，表明PDO不同对肿热分解行为影响不大。     

Hydrogen evolution during the oxidation of formaldehyde on Au:: The influence of single crystal structure and Tl-upd

Hydrogen evolution during formaldehyde oxidation in alkaline solution has been monitored by Differential Electrochemical Mass Spectrometry on Au(111) and polycrystalline gold. The current efficiency for hydrogen evolution increases with higher concentration and is in the same range on both, polycrystalline Au and Au(111) electrode. The onset potentials and half-wave potentials are higher on Au(111). Reaction orders for the faradaic current on the bare gold electrodes have been determined as 0.21 for higher and 0.76 for lower concentrations. Reaction orders for hydrogen evolution during formaldehyde oxidation are 1.4 times higher in each case. Tafel slopes in the range of 140-160 mV are found. This signifies that the first reaction step involving the formation of adsorbed hydrogen is largely determining the overall reaction rate. In the presence of thallium adlayers hydrogen evolution from formaldehyde oxidation is largely suppressed. On the thallium modified polycrystalline Au, formaldehyde oxidation is shifted for 100 mV to higher potentials where Tl is partially desorbed and hydroxide is coadsorbed on the modified surface. On thallium modified Au(111), a similar process takes place, but in the same potential region as the onset of formaldehyde oxidation on the bare surface and therefore the formaldehyde oxidation is only slightly shifted. Tafel slopes are decreased to 80 mV/dec in the presence of thallium. In the presence of adsorbed thallium, the first reaction step is in equilibrium, the coverage with adsorbed hydrogen is smaller and its recombination to H₂ is largely suppressed.     

EPVC系列旋风管的结构优化研究

介绍了ＥＰＶＣ系列导叶式旋风管的叶片形状、优化的叶片出口参数间的匹配关系以及新的防返混锥排尘结构，总结了无泄料盘时的排尘机理及尺寸设计要点。另外，还简单介绍了旋风管装置的工业应用情况。     

Nanocomposites based on polyethylene and Mg-Al layered double hydroxide. I. Synthesis and characterization

Low density polyethylene (LDPE)/Mg-Al layered double hydroxide (LDH) nanocomposites have been synthesized with different compositions by melt-mixing technique using maleic anhydride grafted polyethylene as compatibilizer. LDH has been modified by sodium dodecylbenzene sulfonate using reconstruction method and characterized by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The nanocomposites are characterized by different techniques such as, transmission electron microscopy (TEM), XRD and rheology. The TEM analysis shows a complex nature of particle dispersion in the polymer matrix with wide distribution of particles sizes and shapes. The rheological analysis showed significant changes in linear viscoelastic responses of the composites, even at very low concentration (2 phr) of LDH materials, in comparison to the pure polymer in low frequency regime in dynamic frequency sweep experiments. These changes are related to the LDHs-polymer chains interactions resulting in network-like structure.     

超声振动对聚合物结构性能的影响

介绍了聚合物挤出成型过程中的超声振动技术，并对挤出模头引入超声振动后对聚合物物理机械性能、相容性、结晶性能的影响进行了评述。     

Self-propagating high-temperature synthesis of advanced ceramics MoSi2–HfB2–MoB

This study focuses on the investigation of the macrokinetic features of SHS (combustion synthesis) of elemental mixtures Mo–Hf–Si–B, in particular the mechanisms of structure and phase formation in the combustion front as well as the structure and properties of consolidated ceramics. Two routes for the fabrication of the composite SHS powder in system MoSi₂–HfB₂–MoB were used: (1) synthesis using Mo–Si–B and Hf–B mixtures followed by mixing of the combustion products and (2) synthesis using the four-component Mo–Hf–Si–B mixture. Dense ceramic samples with a homogeneous structure and low residual porosity (0.8–3.6%) were prepared by hot pressing of SHS powders. Although the particles size distribution and phase composition of SHS powders are similar for both synthesis routes, the structure and properties of both the composite SHS powders and hot-pressed ceramics differ considerably. Synthesis using the four-component Mo–Hf–Si–B mixture allows one to produce hierarchically ordered nanocomposite material with improved mechanical properties: hardness up to 17.6?GPa and fracture toughness up to 7.16?MPa?m^1/2.     

Face recognition with Symmetric Local Graph Structure (SLGS)

Face recognition demonstrates the significant progress in the research field of biometric and computer vision. The fact is due to the current systems perform well under relatively control environments but tend to suffer when the present of variation in pose, illumination, and facial expression. In this work, a novel approach for face recognition called Symmetric Local Graph Structure (SLGS) is presented based on the Local Graph Structure (LGS). Each pixel is represented with a graph structure of its neighbours’ pixels. The histograms of the SLGS were used for recognition by using the nearest neighbour classifiers that include Euclidean distance, correlation coefficient and chi-square distance measures. AT&T and Yale face databases were used to be experimented with the proposed method. Extensive experiments on the face database clearly showed the superiority of the proposed approach over Local Binary Pattern (LBP) and LGS. The proposed SLGS is robust to variation in term of facial expressions, facial details, and illumination. Due to good performance of SLGS, it is expected that SLGS has a potential for application implementation in computer vision.     

多矿物粘土基陶瓷地砖

以易熔粘土为基，并引入难熔粘土和熔剂成分，合成了地砖坯料。经研究确定，只要遵循一定的条件，是可以用上述原料生产出优质产品的。指出了制品结构和相组成的形成特点。     

A novel layered Li [Li0.12NizMg0.32−zMn0.56]O2 cathode material for lithium-ion batteries

Layered Li[Li_0.12Ni_zMg_0.32−zMn_0.56]O₂ oxide cathodes containing lithium atoms in the transition metal layers were synthesized and characterized using X-ray diffraction (XRD), galvanostatic cycling, and differential scanning calorimetry (DSC). The Li[Li_0.12Ni_zMg_0.32−zMn_0.56]O₂ cathodes deliver a specific discharge capacity of about 190 mAh/g at room temperature and 236 mAh/g at 55 °C when cycled between 2.7 and 4.6 V versus Li/Li⁺. Excellent capacity retention and smooth potential profiles at room and elevated temperatures over extended cycles suggest that this material does not convert into a spinel structure.     

基于粒子群优化建模的贝叶斯网络结构学习方法

贝叶斯网络(BN)在不确定性的条件下表示信息和推理论证具有良好的性能,但由于其结构搜索空间的复杂性,通常将从一个数据集合中学习贝叶斯网络的结构认为是一种NP-hard的问题。基于此,提出一种新的基于粒子群优化算法建模的贝叶斯网络结构学习方法。为了学习一个贝叶斯网络的结构,该方法先使用粒子群优化算法在排序空间中进行搜索,然后运行K2算法计算每个排序的吻合度。每个排序都会有一个网络结构与之一致,该方法会返回这个网络的计分。仿真结果表明,在不同规模的数据集中,该算法相对于其他贝叶斯网络结构学习算法对不同类型的网络都具有更好的网络稳定性。