不锈钢在湿法磷酸中腐蚀行为研究

本文采用腐蚀实验和电化学测试方法对不锈钢在湿法磷酸中的腐蚀行为进行了研究，并进行钝化膜的组成与结构分析。研究表明，磷酸中加入ＳＯ４＾２＾－，ｃＬ＾－，Ｆ＾－均提高合金的维钝电流密度和致纯电流浓度，加速材料的腐蚀，这些杂质共存时腐蚀性更大。湿法磷酸中存在的Ｓｉ＾４＾＋，Ａｌ＾３＾＋，Ｍｇ＾２＾＋和Ｆｅ＾３＾＋起缓蚀作用。不锈钢纯化膜主要由Ｃｒ和Ｆｅ的氧化物组成，表面形成致密稳定的Ｃｒ２Ｏ３保护膜是提     

火焰原子吸收光谱法测定硅粉中的铜

介绍了用火焰原子吸收法测定工业硅粉中微量铜的具体方法和过程，同时也给出了最佳实验条件。实验中采用新的样品处理方法，得到了令人满意的结果。其中样品回收率为99．8％—104．0%，相对标准偏差为0．31％—0.38％。本方法在实际应用过程中，简单、快速、     

Cu（Ac）2-Co（Ac）2-KBr催化SPC氧化对甲基苯甲醚

研究了无机复合催化剂催化SPC氧化对甲基苯甲醚的反应性能：以Cu（Ac）2-Co（Ac）2-KBr为催化剂,利用过碳酸钠氧化对甲酚甲基化产物对甲基苯甲醚,系统研究了催化剂组成比例、催化剂用量、溶剂、反应温度、反应时间等因素对反应的影响,结果表明,Cu（Ac）2-Co（Ac）2-KBr具有较高的催化活性和选择性,体现出金属离子之间的协同作用,对甲基苯甲醚在m（Cu（Ac）2）：m（Co（Ac）2）：m（KBr）=0．1：0．5：0．1（质量比）,n催化剂：n底物=0．14,冰醋酸作溶剂,稍过量的过碳酸钠,65℃条件下的转化率可达45．9％,生成对甲氧基苯甲醛的选择性为68．3％。提出了氧化反应的H原子转移机理。     

The mechanism of CO oxidation over Cu(110): Effect of CO gas energy

The effect of the temperature of gas phase CO upon the kinetics of the oxygen titration reaction: CO_g +O_a CO_2,g, has been studied. It is found that the reaction's rate is independant of CO gas temperature between 300 and 623 K. The activation energy (6.5 kcal/mole), dependence upon CO pressure (first-order), and independence upon oxygen coverage for 0.1 _o 0.4 are all independant of the CO gas phase temperature. This result rules out any Eley-Rideal type mechanism whereby CO reacts directly from the gas phase with an oxygen adatom without first being accommodated to the surface temperature in an absorbed state. The result is instead interpretable in terms of a Langmuir-Hinshelwood mechanism.Camille and Henry Dreyfus Foundation Teacher-Scholar Fellowship.     

钢框架-钢板剪力墙结构修复后的使用性能指标

为便于钢框架-钢板剪力墙结构震后快速修复,统计既有实验结果,提出修复后使用的三级性能指标,基于等效拉杆理论,研究结构在侧向载荷作用下塑性铰的出现顺序、层间位移角和结构应力发展等情况,并建立有限元模型对指标进行验证.结果 表明:在一级修复性能指标(位移角1/220)下,结构板墙轻微受损,对应的修复方法为对板墙进行轻微修复;在二级修复性能指标(位移角1/110)下,结构板墙几乎全面进入塑性状态,需要考虑换板或增加加劲肋修复;在三级修复性能指标(位移角1/85)下,结构板墙已经全部进入屈服状态,而且框架梁端也出现塑性铰,此时不仅需要对板墙进行修复,还要考虑对框架进行修复.     

Control of floor heaves with steel pile in gob-side entry retaining

A new approach named as steel pile method is innovatively proposed in this study to control severe floor heaves in gob-side entry retaining. It is required that the steel piles be installed in the floor corners with a certain interval before the influence of the dynamic pressure induced by current panel extraction. Using numerical simulation and theoretical analysis, this study investigated the interaction between the steel piles and the floor rocks during the service life of the steel piles, and revealed the mechanism of the steel piles in controlling floor heaves. The effect of the steel pile parameters on the control of floor heaves was presented and elaborated. It is found that the effectiveness of the steel piles in controlling floor heaves can be enhanced with greater installed dip angle, longer length and smaller interval of the steel piles.Compared with traditional methods, e.g., using floor anchor bolts and floor restoration, the advantages using steel pile were successfully defined in terms of controlling effect and economic benefits. It is hoped that the proposed method can contribute to the development of gob-side entry retaining technique.     

钢曲杆在高温（火灾）下的力学特征数值分析

高温(火灾)环境下钢曲杆的受力和变形将会产生较大变化,对结构的力学特征影响较大。本文根据结构稳定理论和热力学原理,应用有限元分析方法,结合三种不同工况,分别探讨了高温(火灾)环境下不同支座形式、杆截面形式等因素对钢曲杆力学特征的影响,并对三种工况下钢曲杆力学特征进行了数值分析与对比,得出了H型钢截面无铰钢曲杆更加符合建筑安全要求的结论,研究成果可为钢曲杆抗火研究提供参考。     

加固新增设备钢结构厂房的有限元分析

由于目前越来越多的工业厂房需要增加新的使用功能,而增加的设备荷载已经超过原结构的正常使用承载能力,故需对原钢结构进行加固。本文采用钢梁底部附加预应力筋和钢梁底部加设支撑方法。为了验证此两种加固方法的可行性,并分析出最优方案,本文以山西某电力设备有限公司新建工业区工程项目为例采用了有限元分析软件ANSYS12.0对两种加固方案进行数值模拟。对两种方法在施加相同的荷载作用下对结构的受力性能进行分析。结果表明,预应力筋加固法不仅能极大的满足结构的应力变形要求,而且省工省料,施工难度小,重量更轻,所以预应力筋法比增设支撑法更合适。预应力筋加固法是未来钢结构加固方法的趋势。     

Adsorption behavior of cross-linked chitosan modified by graphene oxide for Cu（Ⅱ） removal

Cross-linked chitosan（CS）,cross-linked chitosan/graphene（CS/RGO10） and cross-linked chitosan/graphene oxide（CS/GO10） were prepared as adsorbents for Cu（Ⅱ）.The effects of pH,contact time,adsorbent dosage and initial concentration of Cu（Ⅱ） on the adsorbing abilities of CS,CS/RGO10 and CS/GO10 to Cu（Ⅱ） were investigated.The results demonstrate that the adsorption capacities of CS/GO10 and CS/RGO10 are greater than that of CS,especially at pH 5.0 and the adsorption capacities are 202.5,150 and 137.5 mg/g,respectively.Their behaviors obey the Freundlich isotherm model very well.Additionally,CS/GO10 has the shortest time to achieve adsorption equilibrium among them and can be used as a perspective adsorbent for Cu（Ⅱ）.