上海市吴淞工业区大气PM2.5水溶成分的元素分析及细胞毒性研究

通过ICP-MS测定了上海市吴淞地区大气PM2.5水溶成分金属元素含量,通过四唑盐(MTT)测定细胞存活率,通过超氧化歧化酶(SOD)和丙二醛(MDA)两个指标测定细胞氧化损伤,琼脂糖凝胶电泳测定细胞内DNA损伤,流式细胞仪(Flow cytometry)检测细胞凋亡和周期等实验研究了大气PM2.5水溶成分的细胞毒性.实验结果表明:PM2.5可溶成分中Zn元素含量最高,PM2.5在一定浓度范围内能导致细胞死亡,引起细胞的氧化损伤,影响DNA的复制,阻碍细胞增殖,但没有诱导细胞凋亡.PM2.5中可溶金属离子对细胞毒性表现为联合作用.     

佛尔哈德法测定氯化除汞上清液中的氯量

控制pH4-6，用锌粉还原氯化除汞上清液中的汞（Ⅱ）离子，取置换后液加入过量的硝酸银标准溶液，以硫酸铁铵溶液作指示剂，用硫氰酸钾标准滴定溶液滴定来测定氯量。该方法的检出限：0．25mg／100mL，回收率：98％-101％。     

Kinetics of TSCD zinc oxide nano-layer growth by modified diffuse-interface model

Deposition of zinc oxide films from aqueous solutions containing complex Zn²⁺ ions on soda-lime substrates were studied by two-stage chemical deposition (TSCD) process. It was shown that the film thickness can be controlled by the number of dipping stages. Nano-layers were produced with less than nine times dipping stages. Greater dipping numbers resulted in film thickness exceeding 100 nm. The growth rate obeyed double-stage zeroth order with respect to the concentration and first order with respect to the temperature. This rate was proportional to the difference between the temperature of the hot water and the substrate. Overall activation energy of 17.20 ± 0.42 kJ mol⁻¹ and frequency factor of 2.81 ± 0.07 μm s⁻¹ was determined for ZnO deposition. These values were attributed to two resistances. One resistance corresponded with film heat transfer mechanism. The other was attributed to species attachment to the solid substrate. A modification to the diffuse-interface kinetic model was devised for explanation of the latter. EDAX (electron dispersive elemental analysis), XRD (X-ray diffraction) and SEM (scanning electron microscopy) were used to characterize the layer formed. These methods showed that the product consisted solely of pure elliptical ZnO grains.     

微 / 纳米结构含锌硅酸钙基涂层成骨性能研究

骨科植入物涂层的表面形貌和化学组成对炎症反应的进程和骨形成的发生都发挥着重要调节作用。为综合 利用微 / 纳米仿生结构和生物活性元素的优势,将含锌 (Zn) 的纳米结构物质引入到经水热处理后的等离子喷涂硅 酸钙 (calcium silicate, CS) 涂层表面,对所制备涂层的物相组成、表面和截面形貌、比表面积、Zeta 电位和生理环 境下离子溶出等物理化学性能进行了表征。相比于常规 CS 涂层,具有微 / 纳米复合结构的 CS 和含锌 CS 涂层拥 有更高比表面积和孔容,可吸附更多血清蛋白和纤维连接蛋白,通过刺激细胞内整合素以及下游 vinculin 和 FAK 基因表达,提高了骨髓间充质干细胞 (BMSCs) 铺展能力。涂层中锌的引入进一步提高了其表面 BMSCs 的增殖能 力和与成骨细胞分化相关的基因表达。具有微 / 纳米复合结构的涂层明显上调了 RAW264.7 巨噬细胞中 M2 表型 因子（CD206 和 ARG）基因表达,而涂层中溶出的 Zn2+ 显著提高了 RAW264.7 细胞中抑炎症因子（IL-1ra 和 IL10）基因表达,促使其向抑炎症表型转化。骨科植入物涂层表面锌元素和纳米结构的引入有利于创建良好的骨免 疫微环境,促进骨形成的发生。     

季胺萃取锌的动力学研究

以恒界面池法研究了氯化物介质中季胺萃锌的动力学。考查了搅拌转速、传质界面积和温度对萃取速率的影响，判定季爱萃锌为界面化学反应的动力学模式。进一步研究了季胺萃取剂浓度和水相Ｚｎ＾２＋浓度对萃取速率的影响，得到了与理论推断相吻合的速率方程。     

脉冲电流对锌酸盐镀锌层的影响

研究了在锌酸盐镀锌体系中采用脉冲电流时，脉冲频率，脉冲的占空比、反向电流对镀层外观，耐蚀性的影响，发现在最佳脉冲条件下得到的镀锌层比直流电镀得到的镀层光亮，结晶细致，耐蚀性能有很大的提高。     

Crystallization and dissolution behavior of l(+) calcium and zinc lactate in ethanol-water solvent

Crystallization and dissolution behavior of L(+) calcium and zinc lactate in 50% ethanol-water solution was studied. The effects of stirring, standing, ultrasonic wave, and temperature on the crystallization of L(+) calcium and zinc lactate were evaluated. It was found that standing had a positive effect on crystallization of L(+) calcium and zinc lactate, while stirring promoted dissolution of crystallized particles and resulted in high residual concentration in mother liquor. The application of ultrasonic wave did not influence much on crystallization process. L(+) calcium and zinc lactate crystallized easily at 5 ‡C; however, complete crystallization took more than 72 hours. These two salts dissolved rapidly and reached equilibrium within 1 hour.     

碱金属和锌对高炉用SiAlON结合刚玉砖的复合侵蚀

将高炉用SiAlON结合刚玉砖制成外部尺寸为50mm×50mm,内孔尺寸为25mm×25mm的坩埚,分别加入由Na2CO3、K2CO3、ZnO和宝钢高炉现场高炉灰配制的炉渣(其w(Na2O+K2O)=2.75%,w(ZnO)=5.1%)和用K2CO3、ZnO、石墨配制的炉渣(其w(Na2O+K2O)=25%,w(ZnO)=25%),然后分别在还原气氛下于1350℃16h和1100℃40h进行侵蚀试验。将侵蚀后的试样纵向对称剖开,观察渣对试样的侵蚀和渗透情况,进行SEM和EDAX分析。结果表明:碱金属和锌含量不同的两种炉渣对SiAlON结合刚玉砖的侵蚀速度都很小;碱金属侵蚀机理主要是SiAlON与碱蒸气反应生成钾霞石,与渣反应生成铁橄榄石,并参与硅酸盐玻璃相的生成;刚玉颗粒与渣中的FeO、Na2O和K2O反应生成铁铝尖晶石和少量针状β-Al2O3;锌对该砖没有产生明显的化学侵蚀。     

Comparative electrochemical studies of zinc chromate and zinc phosphate as corrosion inhibitors for zinc

The anticorrosive performance of two inhibitive pigments, zinc chromate and zinc phosphate, was compared using electrochemical impedance spectroscopy (EIS) and the scanning vibrating electrode technique (SVET) in pigment extracts in 0.1 M NaCl. It was observed that zinc was protected from corrosion in both extracts. In tests using hot dip galvanised steel painted with an epoxy primer incorporating the pigments, the SVET detected the anodic and cathodic distribution along the scribes, although no significant differences were observed among the various primers. On the contrary, EIS was able to distinguish processes occurring on the metal surface exposed by the scribe in different samples. For primers with anticorrosive pigment, a time constant at high frequencies was attributed to a layer of protective nature, probably formed by metal ions from the substrate and inhibitive ions leached from the anticorrosive pigments.     

碱式碳酸锌生产工艺的研究

本文介绍了碳酸化法新工艺，技术先进、效益明显、产品质量可靠，具有推广应用的价值。