全文获取类型
收费全文 | 6664篇 |
免费 | 628篇 |
国内免费 | 531篇 |
专业分类
电工技术 | 152篇 |
综合类 | 360篇 |
化学工业 | 2782篇 |
金属工艺 | 714篇 |
机械仪表 | 88篇 |
建筑科学 | 136篇 |
矿业工程 | 324篇 |
能源动力 | 241篇 |
轻工业 | 371篇 |
水利工程 | 20篇 |
石油天然气 | 201篇 |
武器工业 | 46篇 |
无线电 | 280篇 |
一般工业技术 | 814篇 |
冶金工业 | 569篇 |
原子能技术 | 454篇 |
自动化技术 | 271篇 |
出版年
2024年 | 41篇 |
2023年 | 125篇 |
2022年 | 279篇 |
2021年 | 302篇 |
2020年 | 263篇 |
2019年 | 206篇 |
2018年 | 192篇 |
2017年 | 238篇 |
2016年 | 279篇 |
2015年 | 239篇 |
2014年 | 302篇 |
2013年 | 418篇 |
2012年 | 412篇 |
2011年 | 430篇 |
2010年 | 326篇 |
2009年 | 366篇 |
2008年 | 321篇 |
2007年 | 424篇 |
2006年 | 354篇 |
2005年 | 321篇 |
2004年 | 278篇 |
2003年 | 246篇 |
2002年 | 208篇 |
2001年 | 171篇 |
2000年 | 167篇 |
1999年 | 125篇 |
1998年 | 110篇 |
1997年 | 89篇 |
1996年 | 97篇 |
1995年 | 66篇 |
1994年 | 67篇 |
1993年 | 63篇 |
1992年 | 41篇 |
1991年 | 57篇 |
1990年 | 39篇 |
1989年 | 23篇 |
1988年 | 24篇 |
1987年 | 25篇 |
1986年 | 13篇 |
1985年 | 16篇 |
1984年 | 14篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 5篇 |
1980年 | 8篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1975年 | 2篇 |
1959年 | 1篇 |
1951年 | 7篇 |
排序方式: 共有7823条查询结果,搜索用时 9 毫秒
11.
The degradation behaviour of Kodar [poly(1,4-cyclohexylene dimethyl-eneterephthalate)] was investigated in air using thermogravimetry, differential thermal analysis and wide angle X-ray diffraction studies. The rates of crystallization and degradation were influenced by thermal exposure and polychromatic irradiation (Λ > 290 nm) for different time intervals. The crystallinity changes (Xc%) and activation energies (ΔE) for the systems have been determined. 相似文献
12.
1,3,5‐Triglyceratetriazine [first tier (G1)] and tri(1,3,5‐triglycerate) triazine [second tier (G2)] dendrimers were prepared with 1,3,5‐trichlorotriazine and sodium glycerate in a 1 : 3 mass ratio in an ethanolic medium.G1 and G2 were amorphous, white, solid substances. Their structures were elucidated with IR, 1H‐NMR, and 13C‐NMR, and their thermal stability was studied with thermogravimetric analysis. The activation energy was calculated with the Freeman–Carroll model. Densities, viscosities, and surface tensions for 0.01–0.08 mol/kg aqueous solutions increased at 0.01 mol/kg for sodium glycerate, 1,3,5‐trichlorotriazine, 1,3,5‐triazine triglycerate chloride, G1, and G2. These values were measured at 298.15 K. The apparent molal volume, reduced viscosity, and inherent viscosity were calculated from the densities and viscosities, respectively. The data were regressed for the limiting densities, limiting apparent molal volumes, intrinsic viscosities, limiting inherent viscosities, and limiting surface tensions for solute–solvent interactions. The positive limiting apparent molal volume values were noted in the order of G2 > 1,3,5‐triazine triglycerate chloride > G1 > 1,3,5‐trichlorotriazine > sodium glycerate, with weaker hydrophilic intermolecular interactions of G2. The higher intrinsic viscosity and limiting inherent viscosity values for G2 implied stronger G2–H2O hydrophilic interactions, and the higher limiting apparent molal volume of G2 indicated slightly higher dynamic conformational changes in comparison with G1, with stronger structural activities. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
13.
The swelling kinetics curves of structurally defined poly(acrylic acid) hydrogel in bidistilled water at temperatures: 25, 30, 35, 40, and 45°C were determined. The possibility of kinetically explaining the isothermal swelling process by applying the following models: reaction controlled by diffusion, first order chemical reaction kinetics, and second order chemical reaction kinetics, was investigated. It was found that kinetically explaining the swelling process using these methods was limited to only certain parts of the process. The swelling process in bidistilled water was described in full range assuming that the hydrogel's swelling rate was a kinetically controlled reaction by the rate of the movement of reactive interface of hydrogel. Based on that model, the kinetic parameters, activation energy (Ea) and preexponential factor (A), of the swelling process were determined to be Ea = 35 kJ/mol and lnA = 8.6. A possible mechanism of the investigated swelling process was discussed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
14.
The nonisothermal crystallization kinetics of a metallocene-made isotactic polypropylene (m-iPP) and its compounds with 0.1 wt % and 0.3 wt % of a sorbitol derivative [1,3:2,4-bis(3,4-dimethylbenzylidene)sorbitol (DMDBS); an α nucleator] were investigated by differential scanning calorimetry at different cooling rates from the melt. The nucleation efficiency was proved by a significant increase in the crystallization temperatures (accompanied by a slight augmentation of the degree of crystallinity and a decrease in the crystal sizes). This increase in the crystallization temperatures led to higher amounts of fractional content in the γ polymorph, even though DMDBS was supposed to be a nucleator for the α form. The Avrami and Ozawa methods effectively described only the early stage of crystallization, whereas a combined Avrami–Ozawa method was valid for the whole crystallization process. The values of the exponent for this method decreased for nucleated samples in the later stage of crystallization, especially in the case of m-iPP with 0.3 wt % DMDBS added (m-iPP03). The activation energy of the process and the surface free energy were also estimated. The production of considerable proportions of the γ polymorph in m-iPP03 corresponded to higher values of the activation energy and lower values of the surface free energy. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
15.
Theorists have predicted that repetition blindness (RB) should be absent for nonwords because they do not activate preexisting mental types. The authors hypothesized that RB would be observed for nonwords because RB can occur at a sublexical level. Four experiments showed that RB is observed for word-nonword pairs (noon noof), orthographically similar nonwords (glome glame), and identical repetitions (plass plass). More RB was found for words than for nonwords. Prior researchers may have failed to find RB for nonwords because display conditions that allow 2 words to be reliably encoded are insufficient for nonwords, or because observers coped with low ability to encode nonwords by using guessing strategies that do not require creating a mental type or tokenizing it. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
16.
Creep crack growth rates were measured using centrally cracked tension specimens of thin polypropylene film with different
crack lengths at various stresses and temperatures. The creep crack growth rates were correlated with the stress intensity
factor. There was the region of the minimum constant crack growth rate which occupied more than 70% of the total creep failure
life. This constant creep crack growth rate characteristics were analyzed on the basis of the stress-dependent Arrhenius type
thermally activated process. 相似文献
17.
Bar-Anan Yoav; Liberman Nira; Trope Yaacov; Algom Daniel 《Canadian Metallurgical Quarterly》2007,136(4):610
A picture-word version of the Stroop task was used to test the automatic activation of psychological distance by words carrying various senses of psychological distance: temporal (tomorrow, in a year), social (friend, enemy), and hypotheticality (sure, maybe). The pictures implied depth, with the words appearing relatively close to or distant from the observer. The participants classified the spatial distance of words faster when the word's implicit psychological distance matched its spatial distance (e.g., a geographically close word was classified faster when it was "friend" than when it was "enemy"). The findings are consistent with the idea that psychological distance is accessed automatically, even when it is not directly related to people's current goals, and suggest that psychological distance is an important dimension of meaning, common to spatial distance, temporal distance, social distance, and hypotheticality. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
18.
The activation of propane using zeolite H-Y and Ga3+ exchanged zeolite Y indicates that in the presence of Ga3+ the mechanism of propane activation is changed from a cracking pathway to a dehydrogenation pathway. The presence of both Ga3+ and H+ are required to achieve this effect. 相似文献
19.
石灰石分解反应的热重动力学研究 总被引:3,自引:0,他引:3
用热重分析等研究方法,对我国9个主要产地的石灰石矿样品进行了大量的实验和分析工作,并分别计算出不同产地石灰石的动力学数据。 相似文献
20.
指出了文献 [1]中的一个错误。给出了不同模型的稀土永磁材料以及磁记录材料的矫顽力 Hc和有效激活体积υ之间的正确关系 ,这样的关系被表示成一个复杂的函数关系 ,同时指出 ,对不同模型的稀土磁性材料 ,这个函数关系是不同的 相似文献