天然气吸附储存脱附过程的动态模拟

通过热动力学计算,认识了脱附过程当中储罐内温度剖面分布的典型特征:储罐轴心处的温度下降幅度最大。分析了脱附过程当中储罐壁的热交换、吸附剂的导热系数以及储罐内的初始压力对储罐内的温度剖面的影响。结论是加强储罐外壁的热交换、增大吸附剂的导热系数皆能改善吸附储罐内的温度剖面。     

Enhanced Photoelectrochemistry in CdS/Au Nanoparticle Bilayers

Three different configurations of Au‐nanoparticle/CdS‐nanoparticle arrays are organized on Au/quartz electrodes for enhanced photocurrent generation. In one configuration, Au‐nanoparticles are covalently linked to the electrode and the CdS‐nanoparticles are covalently linked to the bare Au‐nanoparticle assembly. The resulting photocurrent, φ = 7.5 %, is ca. 9‐fold higher than the photocurrent originating from a CdS‐nanoparticle layer that lacks the Au‐nanoparticles, φ = 0.8 %. The enhanced photocurrent in the Au/CdS nanoparticle array is attributed to effective charge separation of the electron–hole pair by the injection of conduction‐band electrons from the CdS‐ to the Au‐nanoparticles. Two other configurations involving electrostatically stabilized bipyridinium‐crosslinked Au/CdS or CdS/Au nanoparticle arrays were assembled on the Au/quartz crystal. The photocurrent quantum yields in the two systems are φ = 10 % and φ = 5 %, respectively. The photocurrents in control systems that include electrostatically bridged Au/CdS or CdS/Au nanoparticles by oligocationic units that lack electron‐acceptor units are substantially lower than the values observed in the analogous bipyridinium‐bridged systems. The enhanced photocurrents in the bipyridinium‐crosslinked systems is attributed to the stepwise electron transfer of conduction‐band electrons to the Au‐nanoparticles by the bipyridinium relay bridge, a process that stabilizes the electron–hole pair against recombination and leads to effective charge separation.     

Thermodynamic and Transport Properties of Liquid HFC-227ea

The thermal conductivity and heat capacity of liquid 1,1,1,2,3,3,3-hepta-fluoropropane (HFC-227ea) have been studied by a high-frequency thermal-wave method over the temperature range of 294 to 345 K at pressures up to 2.8 MPa. The purity of the samples used throughout the measurements is 99.99 mol%. The experimental uncertainties of the thermal conductivity and heat capacity measurements were estimated to be within ±1.5 and ±2%, respectively. The thermal conductivity of HFC-227ea in the liquid phase decreases as temperature increases, while the pressure has an opposite effect.     

The measurement of the diffusion coefficient and the sorption isotherm of water in paint films

An experimental technique together with a numerical model is proposed with which the diffusion coefficient and the sorption isotherm of water in paint can be measured. Inside a closed vessel, paint films are on stainless-steel plates. Water is present as water vapour in the air and in the paint. After blowing dry or wet air through the vessel for some time, the situation moves to a new equilibrium. The relative humidity of the air inside the vessel is measured as a function of time. From fitting the theoretical/numerical model against the experimental values, follow the diffusion coefficient and the sorption isotherm of water in the paint. The results show large scattering. When the independently measured sorption isotherm is used as an input parameter in the model, the fitting procedure gives much smaller scattering for the diffusion coefficient.     

Panchromatic Chromophore Mixtures in an AlPO4‐5 Molecular Sieve: Spatial Separation Effects and Energy Transfer Cascades

Dye‐loaded AlPO₄‐5 single crystals were prepared by microwave‐assisted hydrothermal synthesis from a batch, containing a mixture of three chromophores (Coumarin 40, Rhodamine BE50, and Oxazine 1) differing in their absorption range, molecular dimensions, and solubilities. Confocal fluorescence images reveal a spatial separation effect of the dye molecules, where the slimmer, more‐soluble dye molecule (Coumarin 40) is uniformly distributed in the body of the single crystal, and the bulky and/or less‐soluble ones (Rhodamine BE50, Oxazine 1) are situated in distinct domains. Visible spectra show good panchromatic absorption of visible light. Fluorescence lifetime measurements indicate the presence of an energy transfer cascade of the entirely fixed dye molecules from Coumarin 40 to Oxazine 1. The transfer mechanism is predominantly radiative.     

混合乳化剂的优选及抗高低温水包油钻井液的研制

O/W乳化钻井液用的阴离子/非离子混合乳化剂,其中的非离子乳化剂先用PIT法初选,再以O/W乳状液黏度为性能指标,用HLB法选定,其中的阴离子乳化剂也用HLB法筛选。选定的一对非离子和阴离子乳化剂按不同比例复配,利用混合表面活性剂HLB值的加和性原理,由O/W乳状液黏度-HLB值关系确定二者最佳配比。O/W乳化钻井液以体积比70/30的柴油 原油为油相,油水相体积比40/60-60/40,乳化剂加量为油水总体积的4%-7%,加入的主要处理剂有:一种代替膨润土的成胶剂,抗高温液体抑制剂,油溶性储层保护剂,降滤失剂等。该钻井液在180℃、最高压力2.5 MPa下热处理24小时或在-26℃冷冻24小时后解冻,均不发生破乳,性能不恶化;用-26℃冷冻7天的乳化剂配制的钻井液,常温和热处理后性能良好。该钻井液流变性能良好,动塑比0.23-0.60,静切力2-8/2-10 Pa,滤失量为零,抑制性良好。图1表3参4。     

灰色关联分析法在油气管道半定量风险评价中的应用

肯特(W．kent Muhlbauer)管道风险评价法是一种半定量风险评价法,但是该方法在我国还处在起步阶段,其理论基础和应用技术都很不完善。为了有效处理评分中存在的主观性和不确定性因素,已经把模糊综合评判法引入到管道风险评价中。但是,传统的相对风险值计算还不够准确,为此介绍了灰色关联分析在油气管道半定量风险评价中的应用。通过对影响管道风险的评价指标(因素)体系的综合分析,确定了灰色综合评价的层次结构模型。构建了由第三方破坏指数、腐蚀指数、设计指数、错误指数、介质危险指数5大指标体系构成的管道系统风险综合评价指标体系,并采用层次分析与专家打分相结合的方法计算权重。在油气管道半定量风险评价中应用灰色关联分析法,可以使评价结果更准确。     

炼油厂余热发电的方案选择与应用

介绍了延长石油集团公司榆林炼油厂利用异步发电机组和同步发电机组回收催化裂化装置余热余能的情况,通过对两种回收方法的技术途径、设备配置、实际应用效果和经济效益分析,得出异步发电机组的余热发电技术方案是优选方案的结论.     

网络管理中事件关联检测机制的研究

网络事件的关联检测是网络管理需要解决的一个关键问题,本文根据分布式网络管理的特点,首次明确定义了网络事件的基本关联关系,在此基础上提出了一种基于Petri Net的事件关联检测机制,实现了基于事件内容的细粒度关联检测,并且在事件检测中充分考虑了时间因素,有效地提高了事件关联检测的准确性。     

600 A IGBT开关电路及其散热系统设计

采用IGBT开关电路，对大功率电阻带进行直流脉宽调制控制，实现了内燃机车大功率直流发电机负载实验中的负载大小的连续调节。为了避免在实验过程中IGBT器件的温度过高，采用独特的双管IGBT结构和双向强迫风冷的散热系统。实验表明该电路运行稳定、可靠。