一种在硅材料表面组装金纳米颗粒的新方法

以氯金酸、L-半胱氨酸为反应试剂,利用内电流和金硫自组装效应,在硅材料表面组装了较为均一的金纳米颗粒,并利用荧光分析与硅纳米线场效应晶体管对该方法进行了相关验证。结果表明:经氢氟酸处理后的硅材料,在氯金酸和L-半胱氨酸混合溶液中反应3min可在硅表面得到较为均匀、稳定的金纳米颗粒层,其中,氯金酸浓度为0.5mmol/L,氯金酸和L-半胱氨酸浓度比为3∶1。荧光分析表明该方法组装的金颗粒表面已氨基功能化,使得金纳米颗粒修饰的硅材料在应用于生物检测时可直接醛基化修饰蛋白,简化了实验操作。同时,该方法可以在硅纳米线场效应晶体管中特异性组装金纳米颗粒,有力地支持了相关器件在疾病检测方面的应用。     

X80管线钢在含硫酸盐还原菌的土壤环境中的应力腐蚀开裂行为研究进展

X80管线钢因具有高强度、高韧性、抗脆断等性能,已成为现代油气运输中应用最为广泛的钢材之一。X80管线钢在埋地土壤环境中不可避免地受到应力和SRB(Sulfate-reducing bacteria)的共同作用,近年来有关X80管线钢在含SRB的土壤环境中的应力腐蚀开裂已成为一个研究重点。综述了应力腐蚀开裂和SRB腐蚀的影响因素,总结了关于应力和SRB协同作用对X80管线钢腐蚀行为影响的研究现状,分析了现行研究的缺陷和不足,并针对这些问题对今后的研究进行了展望。     

多耦合拘束效应对P92钢蠕变裂纹扩展行为的影响

基于断裂力学理论,针对不同面内拘束效应下P92钢高温蠕变裂纹扩展(Creep crack growth,CCG)进行了数据模拟与分析。研究发现不同的拘束效应对CCG行为有着各异的影响,主要分析了试样几何形状、尺寸以及初始裂纹深度等对CCG行为的影响,并且着重研究比较这3种耦合拘束效应对CCG行为的影响程度。基于多种耦合拘束对CCG行为的影响程度做了横向比较,研究发现:试样几何形状对CCG行为的影响程度要大于几何尺寸,试样尺寸和初始裂纹深度对CCG行为的影响程度相似,试样形状比初始裂纹深度的影响程度更大。     

空间碎片高速撞击的数值模拟方法评述

计算机数值模拟是实现空间碎片撞击效应地面模拟的重要手段之一。撞击速度增加,撞击的物理机制和效应将发生改变,计算机数值模拟方法也应随之丰富和全面。介绍了基于有网格和无网格方法的高速撞击数值模拟发展历程,并针对数值模拟中常用的有限元法和SPH法进行了分析比较,阐述了高速撞击计算机模拟中无网格法的计算优势,并提出量子力学在未来无网格法数值模拟中的可能应用。为空间碎片高速撞击更加真实可靠的数值模拟提供参考。     

Experimental Study on Tunable Electromagnetic Shielding by Microlattice Materials with Organized Microstructures

Porous metal materials are widely used for preventing electromagnetic interference, control of heat conduction and impact absorbing. However, a limitation associated with porous metals is that their irregular and non‐uniformal microstructures make their functions non‐desirably tunable. In this report, the authors propose a microlattice material with precisely controlled microstructures for electromagnetic (EM) shielding. An effective medium model taking into account of the EM stimulated surface current of the metal wires is developed to characterize the EM shielding effect of the microlattice metal. In addition, a compact and integrated measuring device is constructed by using a 3D printing method for experimental verification. The theoretical predictions agree well with the experimental measurement. The influence of the geometrical parameters of the microlattice metals on EM shielding effect is also studied. The theoretical model and the compact measuring system provide robust and efficient tools for the design of EM shielding materials.

     

Let There be Light: Polymeric Micelles with Upper Critical Solution Temperature as Light‐Triggered Heat Nanogenerators for Combating Drug‐Resistant Cancer

Complete drug release and efficient drug retention are two critical factors in reversing drug resistance in cancer therapy. In this regard, polymeric micelles with an upper critical solution temperature (UCST) are designed as a new exploration to reverse drug resistance. The amphiphilic UCST‐type block copolymers are used to encapsulate photothermal agent IR780 and doxorubicin (DOX) simultaneously. The integrated UCST‐type drug nanocarriers show light‐triggered multiple synergistic effects to reverse drug resistance and are expected to kill three birds with one stone: First, owing to the photothermal effect of IR780, the nanocarriers will be dissociated upon exposure to laser irradiation, leading to complete drug release. Second, the photothermal effect‐induced hyperthermia is expected to avoid the efflux of DOX and realize efficient drug retention. Last but not least, photothermal ablation of cancer cells can be achieved after laser irradiation. Therefore, the UCST‐type drug nanocarriers provide a new strategy in reversing drug resistance in cancer therapy.     

A New Insight into Cross‐Sensitivity to Humidity of SnO2 Sensor

The efficiency of gas sensors varies enormously from fundamental study to practical application. This big gap comes mainly from the complex and unpredictable effect of atmospheric environment, especially in humidity. Here, the cross‐sensitivity to humidity of a SnO₂ sensor from local structural and lattice evolutions is studied. The sensing response of ethanol is found to be efficiently activated by adsorbing trace of water but inhibited as humidity increases. By X‐ray diffraction, pair distribution function of synchrotron and ab initio calculations, the independent effect of water and ethanol on lattice and local structure are clearly revealed, which elucidate the intricate sensing reactions. The formation of hydrogen bonds and repulsion of ethoxides play key roles in the structural distortions, and also in adsorption energies that are critical to the sensitive behavior. The results show the sensor performance coupled with local structural evolution, which provides a new insight into the controversial effects of humidity on SnO₂ sensors.     

Short‐Wave Infrared Sensor by the Photothermal Effect of Colloidal Gold Nanorods

Photodetection in the short‐wave infrared (SWIR) spectrum is a challenging task achieved often by costly low bandgap compound semiconductors involving highly toxic elements. In this work, an alternative low‐cost approach is reported for SWIR sensors that rely on the plasmonic‐induced photothermal effect of solution‐processed colloidal gold nanorods (Au NRs). A series of uniform solution‐processed Au NRs of various aspect ratios are prepared exhibiting a strong and well‐defined longitudinal localized surface plasmon resonance (L‐LSPR) maximum from 900 nm to 1.3 µm. A hybrid device structure is fabricated by applying Au NRs on the surface of a thermistor. Under a monochromatic illumination, hybrid Au‐NR/thermistor devices exhibit a clear photoresponse in the form of photoinduced resistance drop in the wavelength window from 1.0 to 1.8 µm. The photoresponsivity of such hybrid devices reaches a maximum value of 4.44 × 10⁷ Ω W^?1 at λ = 1.4 µm (intensity = 0.28 mW cm^?2), a wavelength in agreement with the L‐LSPR of the Au NRs applied. Colloidal Au NRs, capable to perform fast conversion between photon absorption and thermal energy, thus open an interesting avenue for alternative low‐cost SWIR photodetection.     

Data-driven evaluation of fatigue performance of additive manufactured parts using miniature specimens

This overview firstly introduces the state-of-the-art research progress in length scale-related fatigue performance of conventionally-fabricated metals evaluated by miniature specimens. Some key factors for size effects sensitive to microstructures including the specimen thickness, grain size and a ratio between them are highlighted to summarize some general rules for size effects. Then, ongoing research progress and new challenges in evaluating the fatigue performance of additive manufactured parts controlled by location-specific defects, microstructure heterogeneities as well as mechanical anisotropy using miniature specimen testing technique are discussed and addressed. Finally, a potential roadmap to establish a data-driven evaluation platform based on a large number of miniature specimen-based experiment data, theoretical computations and the ‘big data’ analysis with machine learning is proposed. It is expected that this overview would provide a novel strategy for the realistic evaluation and fast qualification of fatigue properties of additive manufactured parts we have been facing to.     

宽翼T形梁桥动力学理论与特性分析

考虑了剪滞翘曲应力自平衡条件、剪切变形和剪力滞后效应等因素的影响,本文提出了一种对宽翼薄壁T形梁动力学特性的分析方法.分析中为了准确反应T形梁翼板的动位移变化,三个广义动位移被引入,且以能量变分原理为基础建立了T形梁动力反应的控制微分方程和自然边界条件,据此对T形梁的动力反应特性进行了分析,揭示了T形梁桥动力反应的规律.算例中,对比了考虑和不考虑剪滞翘曲应力自平衡条件对T形梁动力反应的影响,结果显示考虑剪滞翘曲应力自平衡条件的计算方法与有限元数值解吻合更好.