输入非线性方程误差系统的多新息辨识方法

针对输入非线性方程误差系统,即输入非线性受控自回归系统,研究了基于过参数化模型的多新息辨识方法和基于过参数化模型的递阶多新息辨识方法;研究了基于关键项分离原理的多新息辨识方法;使用辨识模型分解技术,研究了基于关键项分离原理的两阶段多新息辨识方法和三阶段多新息辨识方法.这些方法可以推广到其他输入非线性方程误差系统、输入非线性输出误差类系统、输出非线性方程误差类系统、输出非线性输出类系统、反馈非线性系统等.同时,给出了几个典型辨识算法的计算量、计算步骤和流程图.     

一种数字频率特性测试仪的设计

设计了一种基于正交调制原理的数字频率特性测试仪,系统用稳态响应法测量电路的频率特性.单片机作为主控芯片,完成系统的总体控制及数字信号处理;使用集成的直接数字频率合成芯片输出全频率范围内的正弦波.系统对待测电路的输入信号及其输出响应采样,经数字信号处理后,获得电路的幅频特性和相频特性.设计的测试仪测某RLC网络,中心频率的相对误差小于0.2%,有载品质因数相对误差小于1.25%,最大电压增益大于-1 d B.频率特性测试仪输入输出阻抗均为50Ω,幅频误差绝对值小于0.5 d B,相频误差绝对值小于3°,测试仪能满足微机械谐振传感器特征参数测试需求.     

输出非线性方程误差类系统递推最小二乘辨识方法

随着控制技术的发展,控制对象的规模越来越大,使得辨识算法的计算量也越来越大.对于结构复杂的非线性系统,特别是包含未知参数乘积的非线性系统,使得过参数化辨识方法的参数数目大幅度增加,辨识算法的计算量也急剧增加,因此探索计算量小的参数估计方法势在必行.针对输出非线性方程误差类系统,讨论了基于过参数化模型的递推最小二乘类辨识方法;为减小过参数化辨识算法的计算量和提高辨识精度,分别利用分解技术和数据滤波技术,研究和提出了基于模型分解的递推最小二乘辨识方法和基于数据滤波的递推最小二乘辨识方法.最后给出了几个典型辨识算法的计算量、计算步骤、流程图.     

实现照明 LED 用 p-ZnO 中 Ag-2N高共掺粒子数分数机理

基于密度泛函理论的第一性原理方法,对六方纤锌矿结构的Zn O晶体,N、Ag分别掺杂Zn O,以及Ag-2N共掺杂Zn O晶体的几何结构分别进行了比较研究,在此基础上计算得到了未掺杂Zn O晶体和不同掺杂情况下Zn O晶体的能带结构、总体态密度、分波态密度和电荷布居数.结果显示:Ag-2N共掺杂Zn O具有较稳定的结构,能有效提高载流子粒子数分数,更容易得到稳定的p型Zn O.     

金属-石墨烯复合物吸附活化CO2的第一性原理

在光催化CO₂的反应体系中,CO₂的吸附活化是一个关键步骤;不同的活化方式和CO₂的活化态决定了其反应路线和最终产物．以金属-石墨烯体系为研究对象,采用密度泛函理论方法,结合局域密度近似(LDA)和PWC泛函,计算该体系在CO₂吸附前后的几何结构、能量、电荷分布和态密度等的变化．结果表明:电子从金属-石墨烯体系转移到CO₂,使CO₂带负电并活化;其中Cu-G体系对CO₂的活化效果最好,C—O键长分别增加6和14 pm,O—C—O键角减小为122°;金属原子簇和石墨烯的第一电离能和电子亲和势对电子的转移起决定性作用,金属原子簇电子亲和势比石墨烯第一电离能越大,电荷越易从石墨烯转移到金属原子簇．     

First-principles Investigation of the Structural,Electronic and Elastic Properties of Al2Ca and Al4Sr Phases in Mg-Al-Ca（Sr） Alloy

First-principles calculations have been carried out to investigate the structural stabilities, electronic structures and elastic properties of Mg17Al12, Al2Ca and Al4Sr phases. The optimized structural parameters are in good agreement with the experimental and other theoretical values. The calculated formation enthalpies and cohesive energies show that Al2Ca has the strongest alloying ability, and Al4Sr has the highest structural stability. The densities of states （DOS）, Mulliken electronic populations, and electronic charge density difference are obtained to reveal the underlying mechanism of structural stability. The bulk modulus, shear modulus, Young＇s modulus, and Poisson＇s ratio are estimated from the calculated elastic constants. The mechanical properties of these phases are further analyzed and discussed. The Gibbs free energy and Debye temperature are also calculated and discussed.     

余能原理基面力元法在重力坝应力分析中的应用

介绍了二维线弹性问题的余能原理基面力元法。该方法以基线力表征物体的受力状态,以其对偶量位移梯度表征物体的变形状态。通过重力坝算例与平面4节点等参元（Q4模型）和平面4节点减缩积分单元（Q4R模型）的对比分析,探讨了基面力元法应用于重力坝应力分析的可行性。数值分析结果表明,基于余能原理的基面力元法具有较高的计算精度,可以应用于重力坝应力分析问题,有较广阔的应用前景。     

Al3Sc的FFC法制备和第一性原理计算研究

采用熔盐电脱氧法（FFC）制备Al3Sc,并应用以密度泛函理论为基础的平面波赝势方法,利用第一性原理的CASTEP软件包计算了Al3Sc的晶体结构和电子结构．结果表明：物质的量比为3：1的Al2O3和Sc2O3混合阴极片,在700℃、3．2V电解电压下,经20h电解后完全形成Al3Sc．计算了A13sc的晶格常数α=0．411nm,与XRD检测结果符合．     

Probabilistic analysis of random contact force between geomembrane and granular material

A probabilistic method based on principle of maximum entropy was employed to analyze the randomness of contact force between geomembrane and granular material. The contact force distribution is exponential according to the proposed method and the grain size is the most important factor that affects the distribution of contact force. The proposed method is then verified by a series of laboratory experiments using glass beads and cobbles as granular material and a very thin pressure, indicating that film is firstly used in these experiments which give a reliable method to measure the contact force at each contact point.     

Upper bound limit analysis of roof collapse in shallow tunnels with arbitrary cross sections under condition of seepage force

The analytical solutions for predicting the exact shape of collapse mechanisms in shallow tunnels with arbitrary excavation profiles were obtained by virtue of the upper bound theorem of limit analysis and variation principle according to Hoek-Brown failure criterion. The seepage force was included in the upper bound limit analysis, and it was computed from the gradient of excess pore pressure distribution. The seepage was regarded as a work rate of external force. The numerical results of roof collapse in square and circular tunnels with different rock parameters were derived and discussed, which proves to be valid in comparison with the previous work. The influences of different parameters on the shape of collapsing blocks were also discussed.