Synthesis and properties of novel amphiphilic sulfated ionomers by the ring‐opening reaction of an epoxidized styrene–butadiene–styrene triblock copolymer

A method for the synthesis of novel sulfated ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed. SBS was first epoxidized by performic acid in the presence of a phase‐transfer catalyst; this was followed by a ring‐opening reaction with an aqueous solution of alkali salt of bisulfate. The optimum conditions for the ring‐opening reaction of the epoxidized SBS with an aqueous solution of KHSO₄ were studied. During the ring‐opening reaction, both phase‐transfer catalyst and ring‐opening catalyst were necessary to enhance the conversion of epoxy groups to ionic groups. The products were characterized with Fourier transform infrared spectrophotometry and transmission electron microscopy (TEM). After the potassium ions of the ionomer were substituted with lead ions, the lead sulfated ionomer exhibited dark spots under TEM. Some properties of the sulfated ionomer were studied. With increasing ionic groups or ionic potential of the cations, the water absorbency and emulsifying volume of the ionomer and the intrinsic viscosity of the ionomer solution increased, whereas the oil absorbency decreased. The sulfated ionomer possessed excellent emulsifying properties compared with the sulfonated SBS ionomer. The sodium sulfated ionomers in the presence of 10% zinc stearate showed better mechanical properties than the original SBS. When the ionomer was blended with crystalline polypropylene, a synergistic effect occurred with respect to the tensile strength. The ionomer behaved as a compatibilizer for blending equal amounts of SBS and oil‐resistant chlorohydrin rubber. In the presence of 3% ionomer, the blend exhibited much better mechanical properties and solvent resistance than the blend without the ionomer. SEM photographs indicated improved compatibility between the two components of the blend in the presence of the ionomer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

自焙炭块在大型高炉上应用十年概况

自焙炭块陶瓷砌体复合炉缸技术在大型高炉上的应用已有10年，总的来说是成功的，但由于自焙炭块自身的特性，应用中也暴露出了一些问题。通过对国内大型高炉应用自焙炭块陶瓷砌体复合炉缸技术的全面调查，分析了该技术的应用前景，提出了改进措施。     

影响带锯机锯切质量的原因及处理措施

通过对锯切装置的改进，提高了锯切性能，降低了锯条成本，保证了锯切质量，使设备更加高效、安全的工作。     

江苏复杂断块高含水单元改善水驱效果的技术对策

在分析高含水开发单元特点的基础上,针对该阶段剩余油的品位、分布和油水关系极为复杂、挖潜难度大的技术难点,提出了适合江苏复杂断块油田高含水开发单元改善水驱开发效果的思路和工作程序、技术对策,并在真武油田高含水开发单元进行了实际应用,取得了良好的效果.     

赵凹区块酸化增注技术研究与应用

针对河南油田赵凹区块注水效果不好,欠注严重,酸化效果不理想的实际情况,开展了储层伤害因素分析和酸化增油技术研究,进行了酸液体系的配方优化,优选出的酸液具有对金属腐蚀性小,与地下流体配伍性好,对岩屑溶蚀率高的特点。现场实验取得了较好的增注效果,3口井实施有效率100％,注水压力下降了1-8 MPa。     

遗传算法在双向反射分布函数模型参数优化中的应用

对以大理石为代表的材料进行了双向反射分布函数测量实验，得出了样品的半球反射率，并研究了其随入射、反射天顶角等参数变化的规律。采用遗传算法建立了金刚砂和大理石材料的双向反射分布函数的参数模型，对模型进行参数反演时，通过遗传算法进行优化。拟合后的实验数据曲线表明，利用遗传算法得到的结果具有较好的一致性。     

感应电机内部物理过程的框图描述

给出了感应电机内部物理过程的框图描述。这种描述准确地反映了电机学中主、漏磁路分别处理的一般方法，感应电机内部各物理量之间的数量关系和电机学所基于的若干基本电磁定律，感应电机内部物理量之间的关系。     

利用测井新技术重新评价文46断块潜力

利用碳氧比测井和注硼中子寿命测井对文46断块的油水层进行了定性、定量解释方法的研究和探讨，建立了含油饱和度计算模型，确定了油水层的解释标准，并对该断块进行了全面的精细解释，利用测井与地质相结合的综合方法落实了解释成果的可靠性。     

ROI-based Watermarking Scheme for JPEG 2000

A new region of interest (ROI)-based watermarking method for JPEG 2000 is presented. The watermark is embedded into the host image based on the characteristics of the ROI to protect rights to the images. This scheme integrates the watermarking process with JPEG 2000 compression procedures. Experimental results have demonstrated that the proposed watermark technique successfully survives JPEG 2000 compression, progressive transmission, and principal attacks.     

郑411块超稠油试油试采工艺技术应用

郑411块沙三段地层疏松出砂、原油粘度高，属中深层超稠油，常规试油试采方法难以突破出油关，采用APR全通径氮气垫测试、地层与井筒复合防砂、水平井配合直井蒸汽吞吐、氮气泡沫封堵调剖和井筒加热举升稠油等配套工艺技术，取得了较好的效果，为中深层超稠油油藏的开发提供了技术思路。