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81.
研究了Ce对Al—16%Si合金熔体粘滞性的影响。结果表明:Ce的加入增加了合金熔体的粘度,且随着Ce含量的增加粘度值也增加。结合加入Ce的Al—16%Si合金氢含量的变化、凝固组织和DSC曲线研究了熔体结构的变化,分析了粘度与液态结构变化之间的关系。 相似文献
82.
高密度钨合金热静液挤压流动粘度的数值计算 总被引:1,自引:0,他引:1
采用粘性流体的运动微分方程分析工作介质在锥模中的挤压流动,通过分析工作介质的粘度对热静液挤压的影响,指出了合理的选择工作介质的成分使得粘度适宜,可以使热静液挤压力最小,而且能够避免挤压件缺陷的产生。挤压介质的粘度是关系到坯料变形流动的润滑性能及挤压变形流动性能的关键。在此基础上,给出了挤压介质的粘度的数学关系式,为热静液挤压工艺奠定重要的理论基础。 相似文献
83.
紫外光快速固化的树枝状丙烯酸酯齐聚物的制备和性能 总被引:2,自引:0,他引:2
通过乙二胺(EDA)和三羟甲基丙烷三丙烯酸酯(TMPTA),以甲醇为催化剂,在30℃进行6小时Michael加成反应,可制得含多个双键的树枝状丙烯酸酯齐聚物(DAO).与相似分子量的线性丙烯酸酯齐聚物相比,DAO粘度低,用作紫外光固化树脂,其固化速度快,且固化产物硬度好,耐溶剂性好. 相似文献
84.
85.
探讨了影响连续固相增粘产品活性的因素,提出了控制主反应器的温度、氮气流量、基础切片的端羧基、氮气露点等主要因素,实现生产的平稳控制,从而保证产品黏度的稳定。 相似文献
86.
Viscosity data over a temperature range of 37-115°C and a pressure range of 0-10 MPa gauge are presented for a Cold Lake bitumen sample. These data show that the compression of Cold Lake bitumen results in a significant increase in its viscosity. Results are compared with those from a similar study on an Athabasca bitumen sample. Also presented are two correlations for the effects of pressure and temperature on the viscosity of Cold Lake bitumen. 相似文献
87.
4‐(4‐dimethylaminophenyl)‐1,2,4‐triazolidine‐3,5‐dione ( DAPTD ) was prepared from 4‐dimethylaminobenzoic acid in five steps. The compound DAPTD was reacted with excess acetyl chloride in N,N‐dimethylacetamide (DMAc) solution and gave 1,2‐bisacetyl‐4‐[4‐(dimethylaminophenyl)]‐1,2,4‐triazolidine‐3,5‐dione as a model compound. Solution polycondensation reactions of monomer with succinyl chloride (SucC), suberoyl chloride (SubC), and sebacoyl chloride (SebC) were performed under conventional solution polymerization techniques in the presence of triethylamine and pyridine as a catalyst in N‐methylpyrrolidone (NMP) and led to the formation of novel aliphatic polyamides. These novel polyamides have inherent viscosities in the range of 0.09–0.21 dL/g in N,N‐dimethylformamide (DMF) at 25°C. Fluorimetric studies of the model compound as well as polymers were performed. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 947–954, 2007 相似文献
88.
James?A.?KenarEmail author Gerhard?Knothe Robert?O.?Dunn Thomas?W.?RyanIII Andrew?Matheaus 《Journal of the American Oil Chemists' Society》2005,82(3):201-205
Carbonates are a class of compounds that have recently found increasing interest in commercial applications owing to their
physical properties and relatively straightforward synthesis. In this work, physical and fuel properties of five straight-chain
C17–39 and three branched C17–33 oleochemical carbonates were investigated. These properties included cetane number (CN), low-temperature properties, (kinematic)
viscosity, lubricity, and surface tension. The carbonates studied had CN ranging from 47 to 107 depending on carbon chain
length and branching. For the same number of carbons, the CN of carbonates were lower than those of FA alkyl esters owing
to interruption of the CH2 chain by the carbonate moiety. Kinematic viscosities at 40°C ranged from 4.9 to 22.6 mm2/s whereas m.p. ranged from +3 to below −50°C depending on the carbonate structure. High-frequency reciprocating rig testing
showed the neat carbonates to have acceptable lubricity that improved as chain length increased. Finally, the carbonate's
ability to influence cold-flow properties in biodiesel (methyl soyate) and lubricity in low-lubricity ultra-low sulfur diesel
were examined. The carbonates studied did not significantly affect cold flow or lubricity properties at concentrations up
to 10,000 ppm (1 wt%). The properties of the carbonates resemble those of fatty alkyl esters with similar trends resulting
from compound structure. 相似文献
89.
Further compositional analyses of flax: Mucilage,trypsin inhibitors and hydrocyanic acid 总被引:2,自引:0,他引:2
R. S. Bhatty 《Journal of the American Oil Chemists' Society》1993,70(9):899-904
Registered Canadian cultivars of flax, and laboratory-prepared and commercially obtained samples of linseed meal (LM), were
used to determine extract viscosity and mucilage, trypsin inhibitors and hydrocyanic acid (HCN) concentrations. The mucilage
readily leached out from the seed coat (hull) fragments soaked in water, leaving behind pentagon-shaped cells that could be
seen clearly in scanning electron micrographs. Extract viscosity significantly varied in the laboratory-prepared (23–48 cS)
and commercially obtained (30–68 cS) samples of LM and may be used to obtain an indirect, qualitative estimate of flax mucilage.
Mucilage was extracted from whole seed in 5.0–5.3% yields and contained 20–24% protein (about 10% ash and 30% total carbohydrates).
Laboratory-prepared LM (raw) contained 42–51 units of trypsin inhibitor activity, commercially obtained samples, 14–37 units,
and raw rapeseed and soybean meals, 99 and 1650 units, respectively. Picric acid tests (qualitative) showed only traces of
HCN in ten cultivars of freshly ground flax. The acid silver nitrate titration procedure measured HCN quantitatively, but
showed its presence only in three of the five cultivars investigated. HCN was conveniently measured by a colorimetric procedure
(barbituric acidpyridine reaction), which may be used to screen flax cultivars. HCN content of flax was significantly influenced
by environments (growth location and season) and, to a less extent, by cultivar. 相似文献
90.
对超声波进行了简单的介绍,对其在聚合物成型加工中的降粘机理进行了一定的研究以及对它在聚合物成型加工中的应用进行了综述。在聚合物的成型加工中,超声波的合理施加可以大幅度的降低聚合物熔体的粘度,降低加工设备的要求和条件,更有利于高粘度聚合物的成型加工。 相似文献