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91.
The requirement for higher quality drinking water necessitates the application of more efficient water treatment techniques. Nanofiltration is one promising option for enhanced water treatment, for example, in enhanced organic matter removal. The characteristics of different nanofiltration membranes vary remarkably, and the selection of a membrane has to be made according to the requirements of an application. In this study six nanofiltration membranes (NF70, NF255, NTR-7450, NTR-7410, Desal-5 and TFC-S) were evaluated in improving the quality of chemically pre-treated surface water in a pilot-scale process. The results indicate that the membrane with high organics removal and slightly reduced ion removal characteristics (NF255) performed best in terms of product water quality as well as membrane productivity and fouling. The most permeable membrane (NTR-7410) suffered intensive fouling and insufficient product water quality. An interesting finding was that the permeates of all the tested membranes possessed a significant potential for microbial growth, despite the low nutrient contents. 相似文献
92.
钢板具有高的抗拉强度,但是相对于由压应力引起的屈曲来说相对脆弱.然而,当钢板与混凝土结合,屈曲增加的抵抗力和重型加劲肋的阻力是没有必要的,这样使钢桥对混凝土桥更具有经济效益和竞争力.钢混组合的新型结构形式已经在日本几个实际的桥梁中积极提出和发展了.利用钢管混凝土梁桥的新思路设计的钢-混凝土复合材料,也被分析和证明是经济可行的. 相似文献
93.
94.
Dendritic textured Nb3Si thin films, deposited by sputtering pure niobium onto silicon substrates, exhibit a rather high zero-resistance critical temperature, Tc. X-ray and TEM measurements reveal the films to be polycrystalline with the A15 phase. The resistance begins to drop sharply at a temperature of 13.3 K and down to zero at 11.9 K without residual resistivity. 相似文献
95.
Krishnamoorthy Muralirajan Ramajayam Kuppusamy Sekar Prakash Chien‐Hong Cheng 《Advanced Synthesis \u0026amp; Catalysis》2016,358(5):774-783
A green atom‐economical method for the synthesis of highly functionalized 1‐amino and 1‐carbon substituted isoquinolines from the reaction of N′‐hydroxybenzimidamides and aryl ketoximes, respectively, with alkynes via pentamethylcyclopentadienylcobalt(III)‐catalyzed C H/N O bond activation is described. The external oxidant‐free annulation reaction uses the =NOH moiety in N′‐hydroxybenzimidamides or N‐aromatic ketone oximes as the directing group and internal oxidant. This first row transition metal‐catalyzed annulation serves as an efficient alternative for the synthesis of isoquinolines, as water is the only by‐product and expensive noble metals such as rhodium(III), iridium(III), palladium(II), and ruthenium(II) are not required. The reaction proceeds via C H activation, alkyne insertion, reductive elimination, and N O activation.
96.
The palladium‐catalyzed ketone‐directed dual sp2 C H activation and sp3 C H functionalization has been applied for fullerene functionalization for the first time. The sec‐alkyl aryl ketones have been exploited to react with [60]fullerene (C60) to provide the novel and scarce C60‐fused tetralones. The combined use of a highly active cationic palladium(II) catalyst and trifluoromethanesulfonic acid is crucial for the improvement of the reaction yield. A plausible reaction mechanism leading to the observed products has been proposed, and the electrochemistry of the fullerene products has also been investigated.
97.
Shuichi Nakamura Ayaka Toda Masahide Sano Tsubasa Hatanaka Yasuhiro Funahashi 《Advanced Synthesis \u0026amp; Catalysis》2016,358(7):1029-1034
We disclose herein an efficient enantioselective conjugate addition reaction between coumarin‐3‐carboxylic acids and malonic acid half thioesters (MAHTs). The reaction was catalyzed by N‐heteroarenesulfonyl Cinchona alkaloid amides to afford double‐decarboxylative conjugate addition products in good yield with high enantioselectivity. The reaction of various coumarin‐3‐carboxylic acids with MAHTs gave products in high yield with high enantioselectivity.
98.
Copper salts, which are abundant, relatively inexpensive and possess low toxicity, have long been used as versatile catalysts for various reactions in organic synthesis. Recently, the development of Cu‐catalyzed or ‐mediated C H functionalization reactions has gained significant attention. Since the pioneering work of Daugulis on the introduction of 8‐aminoquinoline and picolinic acid auxiliaries as removable directing groups in transition metal‐catalyzed C H bond activations, the combination of copper salts with these bidentate directing groups has emerged as an innovative strategy for the construction of carbon‐carbon or carbon‐heteroatom bonds through C H bond cleavage. In addition to the 8‐aminoquinoline and picolinamide systems, several other bidentate directing groups including the 2‐aminophenyloxazoline group by Yu and Dai and the PIP system by Shi, have been developed as well. This review intends to cover most of the recent advances on copper‐catalyzed or ‐mediated direct sp2 and sp3 C H bond functionalizations assisted by these bidentate directing groups. The major achievements in this area are discussed and catalogued by the type of bonds formed (C C, C O, C N, C S, C P etc.). Special attention is paid to the reaction mechanisms. Selected examples of substrates are listed as well. In addition, a personal outlook is given at the end.
99.
Xiantao Lei Hong‐Yan Xie Chang Xu Xiaoyu Liu Xiaoan Wen Hongbin Sun Qing‐Long Xu 《Advanced Synthesis \u0026amp; Catalysis》2016,358(12):1892-1896
An intramolecular palladium(II)‐catalyzed dearomative arylation reaction of indoles via C H bond functionalization was developed, providing access to structurally novel spiroindolenines with moderate to good yields. A one‐pot process for the synthesis of spiroindoline derivatives was also realized.
100.
Huan Sun Yi Zhang Ping Chen Yun‐Dong Wu Xinhao Zhang Yong Huang 《Advanced Synthesis \u0026amp; Catalysis》2016,358(12):1946-1957
The direct functionalization of inert sp3 C H bonds is limited to a few bond types. Although the activation of sp3 C H bonds can be accomplished under mild conditions using palladium catalysts, the subsequent functionalization is not trivial due to the high energy required to convert palladium(II) to palladium(IV). We have systematically studied the palladium oxidation using computation‐guided experiments for reactions involving strong chelation control. We find that a mild external ligand could significantly accelerate the oxidation of palladium(II) to palladium(IV) for strong bidentate directing groups. The acceleration is believed to be a result of ligand stabilization of both the palladium(II) and palladium(IV) intermediates.