Application d'une méthodologie expérimentale à l'étude du diagramme ternaire d'un gel

Nous avons montré sur l'exemple d'un gel, mélange de trois constituants (C12–C15 Alcohols Benzoate, Cyclomethicone et Ethylene Vinyl Acetate Copolymer) qu'il est possible d'optimiser une formulation en un nombre preécis d'essais en faisant appel à une stratégic expérimentale optimale. Le gel avait déjàétéétudié par Chang,¹ mais par approches successives.
Nous avons utlisé les matrices d'expériences développées dans le cas des mélanges par Scheffe sous le nom de 'reseaux-simplex'. Prévoyant des intéractions de 2éme ordre entre les constituants nous avons retenu le modéle appelé'cubique réduit'. Cette approche permet l'exploration systémique de tout le domaine.
Les réponses étudiées sont la compatibilité (gel homogène ou non), la consistance, la blancheur et le coût. Le meilleur gel étant celui qui se rapproche le plus de la vaseline.
A partir des résultats, nous avons tracé des courbes d'isoréponse en blancheur, consistance et coût. La superposition des diagrammes conduit à la détermination d'une zone où les réponses sont optimales.
En ajoutant la réponse supplémentaire: 'facilité d'étalement sur la peau'on arrive au meilleur gel avec un nombre réduit d'essais.
La même méthode s'appliquerait à des mélanges de plus de trois constituants.
Study of a ternary diagram gel according to a methodology of experimental research     

准噶尔盆地石东地区白垩系地层气测显示反常特征及评价方法研究

准噶尔盆地石东地区白垩系气测显示特征与一般情况下C1高 ,重组分含量低相反。原有的气测解释评价方法都不适用 ,通过对该区气测组分特征的研究 ,应用图版法作出了石东地区白垩系气测解释图版 :TGAS— (C2 +C3) (iC4+nC4)图版 ,经石东 4井应用证实效果很好。     

熔体的粘度，亚稳相，相变和相图——Ⅲ．合金液相相图

对Sn（x）Bi（1-x）11种组分（x=0.10％，20％…80％，90％，100％）的熔体的粘度进行了测量，给出了它们的相变点Tt，相区和相参数；根据这些参数作出了一个二元合金液相相图；为了表明相区的划分和每个相区的结构特征提出两种相图的形式；第1，温度一组分（T-X）图，第2，结构-组分（df-x）图。     

P–I diagram method for combined failure modes of rigid-plastic beams

Closed-form solutions of pressure-impulse (P–I) diagrams for simply supported and fully clamped rigid-plastic beams subjected to impact load are developed. Two failure categories, i.e., bending failure and shear failure, are considered and the responses of the beams are analyzed based on five transverse velocity profiles. With proper failure criteria, the critical P–I equations for bending and shear failure are derived. After the simplification of the critical P–I equations, the influences of the shear-to-bending strength ratio and the boundary conditions on the P–I diagrams are discussed. The results are compared with those based on a single-degree-of-freedom (SDOF) model. It is shown that the proposed P–I diagram method can be conveniently applied to assess beam damage extents and damage patterns. Especially, the P–I diagrams have good agreement with those based on an elastic, perfectly plastic model when severe damage occurs.     

熔融盐法合成高密度锂离子电池正极材料LiNi_(0.8)Co_(0.2)O_2

采用热分析法对不同组成的LiOH-LiNO3二元体系进行研究,绘制了具有最低共熔点的该二元体系的步冷曲线和t-x相图,该体系的最低共熔点为175.7℃。利用低共熔混合物LiNO3-LiOH为锂盐,与高密度前驱体Ni0.8Co0.2(OH)2混合经2个恒温阶段烧结(600℃恒温6 h、800℃恒温24 h)制备出了振实密度高达3.23 g/cm3的锂离子电池正极材料LiNi0.8Co0.2O2。X射线衍射分析表明合成的LiNi0.8Co0.2O2具有规整的层状NaFeO2结构。电性能测试表明:在0.5 mA/cm2放电电流密度和3.0—4.3 V的电压范围内,LiNi0.8Co0.2O2首次放电比容量达175(mA.h)/g,放电比容量为163(mA.h)/g,库仑效率为93%。实验结果表明采用该工艺能够制备出电化学性能良好的锂离子正极材料。     

Experimental assessment of the Ru–Al–Ni ternary phase diagram at 1000 and 1100 °C

Knowledge of phase equilibria in the Ru–Al–Ni ternary system is relevant to the development of new single crystal Ni-based superalloys as well as to new high temperature protective coating systems for these alloys. A series of diffusion couple investigations have been performed across the Ru–Al–Ni ternary system in order to establish phase fields and possible diffusion paths. A continuous B2 phase has been shown to exist across the Ru–Al–Ni ternary between the RuAl and NiAl phases at temperatures of 1000 and 1100 °C. Ternary isothermal sections for Ru–Al–Ni at 1000 and 1100 °C are presented.     

T(x) phase diagram of the Cu2Se-Al2Se3 system

Twenty alloys of various compositions in the Cu₂Se-Al₂Se₃ system were prepared and investigated. The T(x) phase diagram of the Cu₂Se-Al₂Se₃ system was obtained from x-ray diffraction, differential thermal analysis, and microstructure investigation for the first time. The homogeneity region of the CuAlSe₂ semiconducting compound was established. Previous articles by this author were presented with the spelling of his name as B.V. Korzun.     

椭圆光孔上的Fraunhofer衍射图样

将椭圆域变换成圆域，从而借助于圆孔衍射问题的处理方法，给出了椭圆孔上的Ｆｒａｕｎｈｏｆｅｒ衍射图样的数学描述。     

Data requirements for neutron activation: Part I: Cross sections

Existing neutron cross section libraries such as EAF-2003 contain a large number of reactions. Of these only a small proportion are significant in the production of the nuclides that dominate activation quantities such as activity or γ-dose rate at various decay times. These reactions were identified in a recent extensive set of calculations on all the elements and reported in the ‘Activation Handbook’. These 1340 reactions are considered here and the set of reactions with no differential or integral data are listed and prioritised. A set of 339 reactions with very limited possibility of measurement are given; these require further study by theoretical calculations. A set of 100 reactions with either discrepant or no data, that might be measurable are listed and are recommended to be the subject of future experimental work.     

Thermodynamic Assessment of DyCl3-MCl （M= Na, K, Rb, Cs） Systems

Using the CALPHAD （Calculation of Phase Diagram） technique, the DyCl3-MCl （M = Na, K, Rb, Cs） systems were optimized and calculated. The modified quasi-chemical model in the pair approximation for short-range ordering was used to describe the Gibbs energies of the liquid phase in these systems. From the measured phase diagram data and experimental thermodynamic properties, a series of thermodynamic functions were optimized base on an interactive computer-assisted analysis. The optimized parameters and the experimental data were thermodynamically self-consistent. The optimized results were discussed.