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71.
ABSTRACT: The thermal evolution behavior of the organic free radicals induced in irradiated black pepper was studied by electron spin resonance spectroscopy. To analyze the time-dependent evolution process, we used the theory of transient phenomena, that is, an ordinal differential equation, as well as the nonlinear least squares numerical method. We found that the radical evolution that occurred in the irradiated pepper obeys a single exponential function and yields a unique time constant. The evolution of the organic free radical undergoes a simple reaction process of a single radical species. 相似文献
72.
73.
针对显色剂-过渡金属元素-过氧化氢体系,用分光光度法间接测定羟自由基。通过大量试验,确定了三苯甲烷类酸性酚醌吡喃类为有效显色剂,并确定了溴邻苯三酚红-亚铁离子-过氧化氢体系测定羟自由基的最佳条件,首次推测出其最可能的反应机理为:亚铁离子催化过氧化氢产生羟自由基,羟自由基氧化溴邻苯三酚红上的羰基碳氧双键,破坏其显色的共轭结构,使其褪色,此法可作为筛选羟自由基清除剂的有效方法。 相似文献
74.
F. R. Perioto M. E. T. Alvarez W. A. Araujo M. R. Wolf‐Maciel R. Maciel Filho 《应用聚合物科学杂志》2008,110(6):3544-3551
A new calculation procedure for free‐volume parameters is considered in this work by using viscosity prediction methods and the Levenberg‐Marquardt calculation scheme. All parameters used in the Vrentas–Duda free‐volume theory can be estimated from pure component properties. The prediction results are compared with experimental data for some polymer/solvent systems. The diffusion coefficient calculated by Vrentas–Duda theory can be used in the modeling of membrane separation processes. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
75.
76.
This paper deals with the thermal analysis of carbon nanotube (CNT) based composites by meshless element free Galerkin method.
Cylindrical representative volume element (cylindrical RVE) has been chosen to evaluate the thermal properties of nano-composites
using multi-domain and simplified approaches. The values of temperature have been calculated at different points and plotted
against RVE length and RVE radius. A sensitivity analysis of RVE as well as CNT dimensions has been carried out in detail.
The present computations show that the equivalent thermal conductivity is a function of CNT length, CNT radius, RVE length
and RVE radius. Based on present numerical simulations, an approximate formula is proposed to calculate the equivalent thermal
conductivity of nano-composites. The results obtained by simplified approach have been found in good agreement with those
obtained by multi-domain approach. 相似文献
77.
Yoshizaki Kazuhito; Weissman Daniel H.; Banich Marie T. 《Canadian Metallurgical Quarterly》2007,21(3):326
In the present study, we investigated whether a hemispheric division of labor is most advantageous to performance when lateralized inputs place unequal resource demands on the left and right cerebral hemispheres. In each trial, participants decided whether 2 rotated letters, presented either in the same visual field (within-field trials) or in opposite visual fields (across-field trials), were both of normal orientation, or whether one was normal and the other was mirror-reversed. To discriminate a letter's orientation, one must rotate the letter to the upright position. Therefore, we manipulated whether the two letters imposed similar or dissimilar demands on cognitive resources by varying the number of degrees that each letter needed to be rotated to reach the upright position. As predicted, in 2 experiments we found that the across-field advantage increased as the number of degrees each letter needed to be rotated became more dissimilar. These findings support a current model of hemispheric interactions, which posits that an unequal hemispheric distribution of cognitive load allows the cerebral hemispheres to take the lead for different aspects of cognitive processing. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
78.
为了解决上游围堰防渗及绕坝渗漏问题,确定最优防渗方案,对炳灵水电站右岸松动体防渗帷幕的防渗方案进行了三维有限元渗流计算,并对右岸松动体帷幕的防渗范围和灌浆排数进行了敏感性分析。通过多种防渗方案的计算,对右岸松动体的防渗方案做了相应优化,建议了满足设计要求的防渗方案。 相似文献
79.
地震采集中检波器自然频率的试验分析 总被引:9,自引:1,他引:8
王增明 《石油地球物理勘探》2003,38(3):308-316
为了达到提高分辨率的目的,对不同自然频率的检波器进行了多次试验。通过试验分析认为,检波器在自然频率方面有所差别,在单炮记录上表现为对低、高频干扰压制情况有所不同,但是资料通过处理后,几种检波器的频谱和能量均无明显的差别。高分辨率勘探不等于高频勘探,而是一种宽频带的勘探,所以选择自然频率低的检波器有利于高分辨率勘探。 相似文献
80.
In a change detection paradigm, a target object in a natural scene either rotated in depth, was replaced by another object token, or remained the same. Change detection performance was reliably higher when a target postcue allowed participants to restrict retrieval and comparison processes to the target object (Experiment 1). Change detection performance remained excellent when the target object was not attended at change (Experiment 2) and when a concurrent verbal working memory load minimized the possibility of verbal encoding. (Experiment 3). Together, these data demonstrate that visual representations accumulate in memory from attended objects as the eyes and attention are oriented within a scene and that change blindness derives, at least in part, from retrieval and comparison failure. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献