Instability of zeolite Y supported cobalt sulfide hydrotreating catalysts in the absence of H2S

Ion exchanged CoNaY was sulfided at 473 and 673 K and subsequently heated in He at 673 and 773 K. The resulting samples were characterized by means of overall sulfur analysis, temperature programmed Ar treatment and Fourier transform infrared spectroscopy. It was shown that during He flushing at sufficiently high temperature a protolysis reaction occurs resulting in the decomposition of Co sulfide into Co²⁺ ions and H₂S.     

Modified Imidazoles: Degradation Inhibitors and Adhesion Promoters for Polyimide Films on Copper Substrates

Polyimide films on copper substrates that are exposed to elevated temperatures and an oxidizing environment will be subject to degradation. In order to halt this degradation without changing the properties of the system, a polymeric agent could be placed between the polyimide and the copper. This paper will investigate three such materials that will not only slow down the degradation of the polyimide and the oxidation of the copper, but will also improve adhesion within the system. Fourier transform infrared reflection-absorption spectroscopy (FTIR-RAS) will be used to investigate the polyimide/polymeric agent/copper system.     

类金刚石薄膜作为MgF2红外增透和保护膜的研究

系统地研究了ＭｇＦ２衬底上类金刚石薄膜的折射率和生长速率与淀积工艺之间的关系，在ＭｇＦ２衬底上成功地设计并制备了红外增透和保护膜。理论与实验研究表明，类金刚石薄膜使ＭｇＦ２的红外透过率提高３％以上是完全可靠的，但起红外增透和保护是作用的统一性问题仍有待进一步研究。     

TiO_2载体表面酸性的研究

利用NH_3吸附和吡啶吸附红外技术研究TiO_2的制备条件对其表面酸性的影响。结果表明,用NH_3水中和TiCl_4溶液方法制备的TiO_2(A)表面有较强的L酸中心,中和条件对表面酸性中心数目和强度有显著影响。由TiOSO_4水解方法制备的TiO_2(B)表面具有较强的L酸中心和较弱的B酸中心,引入不同添加剂可有效地调变TiO_2载体表面的酸性。     

高灵敏度热释电摄象管红外电视系统

针对热释电摄象管(PEV)在传统的对称斩波模式下存在的各种问题,设计了一种新的非对称斩波模式PEV红外电视系统.通过提高PEV摄象机的温度响应率R_i和采用高去噪声信号处理系统,大大改善了PEV红外成象系统的性能.     

Modeling and simulation of the drying of thin sheets in a continuous infrared dryer

The model gives the temperature and moisture distributions of the air, and of the moist sheet, as a function of time and distance in the dryer. The influence of the sheet's velocity and that of the radiant energy on the dryer performance as well as the effect of the moisture content of the entering sheet have been studied. A set of 27 experiments was carried out using the infrared dryer in order to calibrate the model. In these, the following three variables each had three operational levels: web velocity, initial web moisture and heating power. The model predictions agreed very well with the experimental data. Model predictions using arithmetic averages for the parameters, and parameters correlated with operational variables, are also presented and discussed.     

近红外仿灸仪的研制与临床应用

近红外仿灸仪,也称为经络灸疗仪,是采用我国传统医学与现代科学技术相结合而研制成的一种新型中医治疗、保健仪器,可以用于治疗多种疾病。本仪器根据艾灸燃烧时所辐射的光谱,运用仿真技术进行模拟,根除了传统灸法燃烧缓慢、效率不高、烟雾较大、刺鼻熏眼、易于灼伤、操作不便等缺点,充分发挥了我国传统灸法的温经通络、补气活血、化瘀消肿,祛湿止痛的功效。     

IR Radiometry Optical System View Factor and Its Application to Emissivity Investigations of Solid and Liquid Phases

An optical system for fast IR radiometry designed for investigations of thin film thermal properties and pulsed laser melting was analyzed in this work. A methodology for determination of the view factor from calibration measurements was developed. The view factor (0.0255) of the optical system containing two paraboloid mirrors was determined experimentally from calibration measurements on pure metals and metallic alloys. The knowledge of the view factor was then applied to normal emissivity investigations at IR wavelengths. The emissivity of tungsten films prepared by magnetron sputtering was determined for different deposition conditions, varying between 0.036 and 0.071. Liquid phase emissivities of Cu, Mo, Ni, Si, Sn, Ti, and steel were also determined and were found to be higher than solid-state emissivities as predicted from the literature. A knowledge of the liquid-state emissivity of silicon enabled recalculation of the IR signal evolution to the temperature evolution, during and after a nanosecond laser pulse. This was not possible by use of the usual calibration because of silicon’s semi-transparent behavior in the IR range (1–10 μm) in the solid-state phase.     

红外加热节能技术的现状与发展前景

本文综述了国内外节能的现状与发展趋势,论述了远红外电加热领域的发展前景,强调了加强基础理论研究的重要性,介绍了我国红外加热应用的领域和国外新开发的红外产品。     

红外警戒系统的运动参数估计算法

通过对目标飞行轨迹的参数化建模，提出了由红外传感器对目标角度和辐射功率的测量实现对目标距离和其它位置、速度参数估计的算法，从而可以此作为目标威胁程度估计和目标特性识别的依据。仿真计算表明，该方法计算的精度高，对目标位置的初始先验值依赖程度较小。该算法也适合于其它测量体制的目标运动参数估计。