关于Gibbs函数变关系式引出的探讨

本文推荐陈林根编著的《工程化学》对化学热力学基本公式△G=△H-T△S的引出方法,试探基础教学的改革。     

利用独立分量分析法去除地震噪声

 独立分量分析（ICA）作为盲源分离（BSS）的一种新方法,是分解观测数据中独立信息的有力工具。以往的ICA算法一般假设噪声可以忽略不计，而实际的观测数据中又常常包含一些加性噪声。对于加性噪声的影响不能忽略的情况下，改进的ICA算法首先利用非零时间滞后协方差，应用两步特征值分解法(EVD)可成功地去除部分加性噪声的影响；再利用ICA算法就能更好地分离出原信号。本文通过对地震理论模型和实际资料的试验，说明改进的ICA算法能够有效地克服加性噪声对常规ICA算法的影响，能够分离出地震资料中的有效信号，从而实现利用独立分量分析压制地震资料噪声的目的。     

Some results on generalized residual entropy

Shannon’s entropy plays an important role in the context of information theory. Since this entropy is not applicable to a system which has survived for some units of time, the concept of residual entropy has been developed in the literature. Here we generalize the residual entropy by choosing a convex function ? with ?(1) = 0. In this paper, some orderings and aging properties have been defined in terms of the generalized residual entropy function and their properties have been studied. Quite a few results available in the literature have been generalized and some distributions (viz. uniform, exponential, Pareto, power series, finite range) have been characterized through the generalized residual entropy.     

调谐质量阻尼器参数设计中的两个问题

本文以单自由度系统安装一个调谐质量阻尼器（简称TMD）为例，对抗风和抗震两类不同激励工况下TMD的参数设计问题进行了理论研究与对比分析。通过给出相对误差系数的概念，定量评价了不同的参数方法对TMD减振性能的影响程度。本文的研究为TMD的参数设计提供了理论指导。     

低渗透油气藏岩石物性测试方法研究

本文是在已研制的瞬时脉冲岩石物性测试装置与改进的渗透率常规稳流测试装置基础上，分别利用瞬时脉冲方法和稳流测试方法对大量的致密油藏岩们作了渗透率测试实验。相同测试条件下通过对两种方法的对比与统计分析，对低渗透油气藏岩石物性测试的实验方法给予了充分的论证。经大量实验研究表明：在模拟地层压力条件下，瞬时脉冲测试方法与常规稳流测试方法测得的渗透率相对误差极小，通常小于10％，证明这两种方法用于低渗透油气藏岩石物性测试具有较强的合理性。     

集团变分法(CVM)及其在合金相图计算中的应用

介绍了集团变分法的集团概率变量、配置熵等统计分析的理论基础及Helmholtz自由能的描述模型.提出了巨势及相对化学势的几何分析理论.讨论了应用集团变分法和巨势分析理论进行相平衡计算的过程,并分析了同结构平衡相图计算的若干实例.     

香豆胶衍生物的化学结构及稳定性研究

将市售商品溶于水,用异丙醇沉析提纯,溶于0.1 mol/L NaNO3纯水溶液中,经0.5μm滤膜过滤后用水相凝胶渗透色谱法(GPC)测定,测得香豆胶(FG)、羟丙基香豆胶(HPFG)、阳离子香豆胶(CFG)的数均、重均相对分子质量Mn、Mw分别为:1.19×105、3.36×105,8.52×104、2.85×105,9.33×104、2.87×105。用甘露聚糖链在碱性条件下醚化时发生降解,解释两种改性FG的相对分子质量较FG低而多分散性(Mw/Mn)较FG高的测试结果。认为商品FG的1%水溶液黏度(1300 mPa.s)高于商品HPFG和CFG(分别为705和610 mPa.s)的原因是前者相对分子质量较高且残渣含量也较高(~10%,后二者为1%~2%)。HPFG的取代度为0.12,根据文献发表的13C-NMR数据确认HPFG分子链上羟丙基取代位置为C6。讨论了香豆胶(半乳甘露聚糖)的化学结构。热重分析法测定的热稳定性,HPFG高于CFG,CFG又高于FG。图6表3参13。     

A Novel Segmentation and Feedback Model for Resolving Contention in Optical Burst Switching

A novel segmentation and feedback model (SFM) applied to resolve contention is proposed. Simulation and performance analyses show that the SFM effectively avoids contentions in optical burst switching (OBS). The long delay time of deflection routing and the immature technology of wavelength converters and optical buffers are not deployed in the SFM. The SFM does not only realize fast switching but also allows preemption by higher priority bursts.     

盘石头水库河槽段趾板基岩的地质概况与防渗设计分析

盘石头水库河槽段趾板基岩建基面下8m为相对不透水层,如按常规进入不透水层5m设计帷幕,深度只有13m左右,对100m高坝而言,深度偏浅,为安全考虑,帷幕设计为悬挂式帷幕,主帷幕深度按1/3坝高考虑,穿透隔水层,隔水层以上以一排主帷幕和两排副帷幕防渗,隔水层以下以一排主帷幕防渗。     

Hydrolysis of Fe(OH)SO4 in the presence of metallic iron

Hydrolysis of Fe(OH)SO₄ was carried out in the presence of metallic iron in order to prevent the formation of iron(III) oxides with strongly bonded sulphate. Under the conditions of the experiment, the products were found to be mixtures of ?-Fe₂O₃ and α-FeOOH. The occluded sulphate, if any, could be easily washed out with water. The hydrolysis reaction passes through an equilibrium state before coming to completion. The entropy with enthalpy of the hydrolysis corresponding to the equilibrium state were found to be 4 e.u. and 0·5 kJ/mol, respectively. The activation energy of the hydrolysis reaction was found to be 21 kJ/mol.