New intramolecular effect observed for polyesters: An anomeric effect

A series of polyesters was prepared to evaluate hydrolytic stability as a function of cyclohexyl dibasic acid content. The three cyclohexyl dibasic acids: 1,2; 1,3; and 1,4 were formulated into polyesters with two glycols. The proportion of cis and trans isomers was evaluated via ¹H NMR. The hydrolytic stability of short chain polyesters was evaluated in an acetone/water mixture which solubilized the polyesters to mimic oligoester behavior within a thermosetting polyester coating environment. The rate of hydrolysis was monitored by acid titration and corroborated by GPC. Surprisingly, 1,2-cylohexyl diacid-based polyesters were robust, and 1,3-cyclohexyl diacid-based polyesters were the most susceptible to hydrolysis. Evidently, a 1,2-anchimeric effect for cyclohexyl dibasic acid polyesters was not an important consideration, while the 1,3-cyclohexyl ester interaction was. Consequently, an anomeric effect was proposed. Presented at the 81st Annual Meeting of the Federation of Societies for Coatings Technology, November 12–14, 2003, in Philadelphia, PA.     

标准咨询服务探讨

通过对标准化咨询服务各种模式的具体阐述，论证了其对企业发展的重要作用，以及信息化在标准服务中的的重要地位。     

FHCF: A Simple and Efficient Scheduling Scheme for IEEE 802.11e Wireless LAN

The IEEE 802.11e medium access control (MAC) layer protocol is an emerging standard to support quality of service (QoS) in 802.11 wireless networks. Some recent work shows that the 802.11e hybrid coordination function (HCF) can improve significantly the QoS support in 802.11 networks. A simple HCF referenced scheduler has been proposed in the 802.11e which takes into account the QoS requirements of flows and allocates time to stations on the basis of the mean sending rate. As we show in this paper, this HCF referenced scheduling algorithm is only efficient and works well for flows with strict constant bit rate (CBR) characteristics. However, a lot of real-time applications, such as videoconferencing, have some variations in their packet sizes, sending rates or even have variable bit rate (VBR) characteristics. In this paper we propose FHCF, a simple and efficient scheduling algorithm for 802.11e that aims to be fair for both CBR and VBR flows. FHCF uses queue length estimations to tune its time allocation to mobile stations. We present analytical model evaluations and a set of simulations results, and provide performance comparisons with the 802.11e HCF referenced scheduler. Our performance study indicates that FHCF provides good fairness while supporting bandwidth and delay requirements for a large range of network loads. Pierre Ansel received a multidisciplinary in-depth scientific training in different fields such as Pure and Applied Mathematics, Physics, Mechanics, Computer Science and Economics from the Ecole Polytechnique, Palaiseau, France. Then, he joined the Ecole Nationale Superieure des Telecommunications, Paris, France in 2005 where he went further into electronics, databases, computer network security and high speed networks. He received a multidisciplinary master of sciences degree and an additional master of sciences degree in telecommunications in 2005. He did a summer internship in 2003 in INRIA, Sophia Antipolis, France where he worked on the Quality of Service in 802.11 networks at Planete Group, France. Then in 2004, he joined France Telecom R&D, Issy-les-Moulineaux, France to work on Intranet Security issues. He designed a WiFi security supervision architecture based on WiFi Intrusion Detection Sensors. He is currently a French civil servant and belongs to the French Telecommunications Corps. Qiang Ni received the B.Eng., M.Sc. and Ph.D. degrees from Hua Zhong University of Science and Technology (HUST), Wuhan City, China in 1993, 1996 and 1999 respectively. He is currently a faculty member in the Electronic and Computer Engineering Division,School of Engineering and Design, Brunel University, West London, U.K. Between 2004 and 2005 he was a Senior Researcher at the Hamilton Institute, National University of Ireland, Maynooth. From 1999 to 2001, he was a post-doctoral research fellow in the multimedia and wireless communication laboratory, HUST, China. He visited and conducted research at the wireless and networking group of Microsoft Research Asia Lab during the year of 2000. From Sept. 2001 until may 2004, he was a research staff member at the Planète group of INRIA Sophia Antipolis France. Since 2002, he has been active as a voting member at the IEEE 802.11 wireless LAN standard working group. His current research interests include communication protocol design and performance analysis for wireless networks, cross-layer optimizations, vertical handover and mobility management in mobile wireless networks, and adaptive multimedia transmission over hybrid wired/wireless networks. He has authored /co-authored over 40 international journal/conference papers, book chapters, and standard drafts in this field. He is a member of IEEE. E-mail: Qiang.Ni@ieee.org Thierry Turletti received the M.S. (1990) and the Ph.D. (1995) degrees in computer science both from the University of Nice – Sophia Antipolis, France. He has done his PhD studies in the RODEO group at INRIA Sophia Antipolis. During the year 1995–96, he was a postdoctoral fellow in the Telemedia, Networks and Systems group at LCS, MIT. He is currently a research scientist at the Planete group at INRIA Sophia Antipolis. His research interests include multimedia applications, congestion control and wireless networking. Dr. Turletti currently serves on the Editorial Board of Wireless Communications and Mobile Computing.     

房地产项目开发建设中住宅整体质量问题探析

商品住宅的质量关系着国家的未来和房地产业的兴旺,本文试图对住宅产品的质量现状、问题及成因进行分析,在此基础上提出进一步提高品住宅整体质量的看法:     

气体悬浮焙烧炉内衬烘炉曲线的确定

根据所使用的低水泥浇注料的性能，对中铝山西分公司检修厂4号焙烧炉制定了合理的烘烤曲线，提高了耐火内衬的质量，延长了内衬的使用寿命。     

Faculty and Student Attitudes Toward Community Service: A Comparative Analysis

The Humanitarian Engineering initiative, sponsored by the William and Flora Hewlett Foundation, at the Colorado School of Mines, is creating a program that will support engineering students in understanding their responsibility for solving community development problems that exist throughout the world. As part of this effort, data has been collected on faculty and student attitudes using the ‘Community Service Attitudes Scale,” developed and validated by Shiarella, McCarthy, and Tucker. During the fall 2004, 78 students and 34 faculty members responded to this instrument. Statistically significant differences were found between the attitudes of students and faculty, males and females, and among different age groupings with respect to service activities. A general finding was that faculty displayed better attitudes toward community service than the students.     

一种网络服务自动部署方法

为满足网络服务使用者对网络服务部署的功能性和非功能性需求,运用Petri网的方法进行了互联网动态多变环境下的网络服务自动部署的研究,建立了一种基于Petri网的网络服务部署网模型,从形式化的角度描述了网络服务功能的部署情况,提出了一种按照服务质量来选择最优网络服务部署的算法。仿真的结果表明,与目前常用的固定部署算法和随机部署算法相比,按照该方法得到的网络服务部署能最好地满足服务使用者对服务的非功能性方面的需求。     

Using Automated Negotiation for Grid Services

The popularity of grid services has widened their application to numerous domains and increased the utilization of computational resources. In order to create more incentives for the resources owners to lease their resources and prevent users from wasting the resources, the introduction of a market-oriented grid is inevitable. However, the issues for the negotiation between service provider and consumer over the supply and demand of resources can be complex, with highly interdependent issues. In this research, a simulated automated negotiation mechanism including a co-evolutionary mechanism and a modified game theory approach is proposed, to assist them in reaching an agreement over the conflicting issues. In the proposed architecture, the co-evolution process is able to reduce the multiple dimensional search space into a two-dimension search space and identify the appropriate negotiation strategies for the negotiating agents to form a payoff matrix which can be used for the game theory related stage of their interaction. The multiple stage negotiation process is introduced to improve the negotiation result. In this paper, an application which requires a large amount of computational resources to process the data generated from mobile devises is used to demonstrate that the proposed system is able to resolve the conflicts and obtain a valid solution.     

Name‐Based Autoconfiguration for Mobile Ad hoc Networks

In a mobile ad hoc network, difficulties exist in supporting address autoconfiguration and naming resolution due to the lack of centralized servers. This letter presents a novel approach, called name‐based autoconfiguration (NBA), which uses host names to determine IP addresses and provides address autoconfiguration and name resolution as a single protocol.