初级金属固溶体的固相线

本文提出二元合金A_(1-x)B_x的初级金属固溶体的固相线的计算公式为:T_m(x)=T_(mA)F(x),其中T_(mA)是A金属的熔点,F(x)是以X为变量、包含A和B的原子密度N、价数Z、熔化体积增率(△V/V)和熔化熵△S的解析函数.对于以Cu、Ag、Au为基的、包含一价到四价的简单金属的24种初级金属固溶体的固相线作了理论计算.与实验结果符合较好.对于三元合金也作了相应的推广.     

LabWare树立全球LIMS的典范

本文站在技术和应用的角度，简要介绍美国LabWare公司LIMS产品的功能，对其特点进行分析，其中，该系统的先进性和可组态性，实施的准时、概算的可控制，以及成功的业绩，对中国的用户将具有很大的吸引力。     

用AIR-C2H2原子吸收光谱法测定镉镍电池正极浸渍液中钴含量

本文主要简述与运用AIR-C2H2原子吸收光谱法进行镉镍电池正极浸渍液中钴含量的测定，介绍了钴最佳测定条件及呈良好线性范围的浓度。同时对样品消化处理条件，在测定中样品的干扰因素进行了综合考虑，该方法具有很好的灵敏度，很好的重复性，干扰小，同时具有方法步骤简单，操作容易掌握等特点，对样品钴含量的测定，其相对标准偏差均小于1.0%（n=6），标准加入回收率均在97.0%～102.0%(n=5）范围内，结果表明，运用AIR-C2H2原子吸收光谱法测定镉镍电池正极浸渍液中钴含量的分析，达到了实验室分析质量控制的要求，完全适用于镉镍电池正极浸渍液中钴含量的控制分析和样品系统分析。     

Photoelectrochemical properties of sol–gel-derived Ti1−xVxO2 solid solution film photoelectrodes

Ti_1−xV_xO₂ solid solution film photoelectrodes were prepared by the dip-coating sol–gel method. X-ray diffraction and X-ray photoelectron spectroscopy were employed to ensure the formation of the solid solution and their composition. Obvious photoresponses were observed in the visible region for the solid solution film electrodes with x0.05 and the red shift of the photoresponse was enhanced with increasing x. Moreover, the solid solution film electrodes were found to be photoelectrochemically stable. However, the onset potential of photocurrent shifted positively with increasing x. Band model of the solid solution was suggested to explain the effects of the vanadium incorporation on the photoelectrochemical properties.     

A study of suppression of vapor explosions by adding inversely soluble polymers

The mechanism of the suppression of vapor explosions by adding inversely soluble polymers in water is studied. Vapor explosion experiments and quench experiment are conducted using a silver test piece. Polymetric solution (polyethylene oxide), of concentrations from 0 to 500 wppm, whose normalized viscosity (by water) varies from 1.00 to 2.00, is used. No vapor explosion is observed in the aqueous polymer solution at a concentration higher than 200 wppm. Quench experiments using the silver test piece submerged in the polymer solution and water are performed in order to examine the stability of film boiling. The suppression of the vapor film collapse is attributed to the precipitation of polyethylene as a gel around the vapor film. © 2002 Wiley Periodicals, Inc. Heat Trans Asian Res, 31(4): 297–306, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.10037     

胶体五氧化二锑研究现状及发展方向

对胶体五乳化二锑的研究现状进行了回顾，详细概述了胶体五乳化二锑的各种制备方法及其特点和适用范围，讨论了两种成胶理论。针对目前存在的问题，对胶体五乳化二锑的研究方向及研究重点提出了几点建议。     

Direct Methods Optimised for Solving Crystal Structure by Powder Diffraction Data: Limits,Strategies, and Prospects

The ab-initio crystal structure solution by powder diffraction data requires great efforts because of the collapse of the experimental information onto the one dimensional 2θ axis of the pattern. Different strategies will be described aiming at improving the process of extraction of the integrated intensities from the experimental pattern in order to make more straightforward the structure solution process by direct methods. Particular attention will be devoted to the EXPO program. Some of its performance will be analysed and results will be shown.     

苯部分加氢催化剂失活原因的研究

探讨了环己醇装置苯部分加氢催化剂失活的原因，分析了失活机理，并结合实例——母液置换法解决催化剂的氮化物中毒。     

卤素置换反应用氯化锌催化剂的再生

研究了用于催化卤素置换反应后的氯化锌催化剂的再生方法。其过程包括：用石灰乳中和，沉淀出氢氧化锌，用氢氧化锌中和氯化锌废液至pH值为5—6，通入氯气氧化氯化锌废液中的有机物，蒸发至必要的浓度。     

大港油田官109-1断块稠油油藏碱/表面活性剂吞吐采油技术

大港油田官109-1断块稠油油藏的油井由于井筒、近井地带发生原油有机沉积,储层原油流动性差,采用多种方法都不能正常生产。为此研制了一种碱性解堵液,用于油井化学吞吐。该解堵液为复配碱和抗硬剂等添加剂的10%两性木质素表面活性剂溶液,能使玻璃片表面由亲油变强亲水,在石英上的接触角为6°(稀释至1/2和1/4浓度时为11°和12°),与羊大站原油间的界面张力为1.75×10-3~3.18×10-3mN/m。该解堵液与黏度1~50 Pa.s的不同区块稠油按体积比1∶1混合形成的乳状液,60℃、175 s-1黏度为2~6 mPa.s,在配液水矿化度高达6000mg/L以上或钙镁离子浓度高达250 mg/L时,该解堵液仍能保持对稠油的乳化降黏能力。该解堵液从实验岩心中驱出的原油量比地层水多75%,驱出液为乳状液。通过一个井例介绍了化学吞吐工艺:先用一种降黏解堵液对油井进行预处理,清洗油管、炮眼及近井地带,再注入碱性解堵液(该井例中为500 m3),注入时间约15小时,然后开井生产。2000年2月至2002年6月在16口新投产井实施化学吞吐(第一轮次),15口井有效,其中2口井先后转注水,其余13口井到2005年底仍继续产油。图1表6参5。