铜基催化剂孔隙率对气体有效扩散系数的影响

研究了18种具有不同孔结构参数的粒状铜基甲醇合成催化剂孔隙率对有效扩散系数的影响。结果发现，催化剂微孔孔隙率增大，曲节因子亦增大，扩散阻力增加。将孔隙率与催化剂曲节因子关联，得到了半经验方程，用它可估算催化剂的曲节因子。     

单螺杆挤出机—熔体泵串联挤出系统的性能与应用

从原理与应用方面，分析、探讨了单螺杆挤出机-熔体泵串联挤出系统的优异性能以及在塑料挤出成型领域的高效应用。     

液动旋冲接头冲击功测试方法研究

液动旋冲接头性能参数是旋冲接头设计的主要依据之一，如何对液动旋冲接头的参数进行检测是非常重要的工作。在分析和比较了测试液动旋冲接头性能参数各种方法的基础上，选择了冲击力法来进行破岩液动旋冲接头的性能参数测试，以YD系列测力传感器为检测元件，建立了一套比较完善的自动检测系统。分析了影响单次冲击功测试的因素，得出了测试旋冲接头的性能参数的影响规律。     

数控螺纹车削的单步插补控制法

分析了运动控制芯片MCX34的控制原理及单步插补实现过程，提出了基于运动控制芯片MCX314实现螺纹切削的单步插补控制法，从而实现快速，高效的螺纹加工。该方法控制过程简单 ，同步实现锥螺纹，控制精度高（0.001mm），响应快（≤1.6MHz)，脉冲确保不丢失，解决了数控螺纹车削存在的一系列关键问题。     

Adsorption and decomposition of H2S on Pd(1 1 1) surface: a first-principles study

Gradient-corrected density functional theory was used to investigate the adsorption of H₂S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H₂S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H₂S decomposition giving rise to adsorbed S and H were determined. Both H₂S_(ad) → SH_(ad) + H_(ad) and SH_(ad) → S_(ad) + H_(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H₂S on Pd(1 1 1) surface is a facile process.     

Bulk growth of Hg0.8Cd0.2Te single crystals by a combined CVT-seeding technique

The growth of high quality Hg_0.8Cd_0.2Te bulk single crystals by CVT, combined with an in-situ seeding technique, is reported here for the first time. For this purpose, a temperature difference of 590° → 540° C with a gradient of 40°-50° C/cm at the solid-vapor interface, and about 0.1 atm of HgI₂ as a transport agent, were employed. The bulk crystals have the expected stoichiometry and compositional homogeneity. Etch pit densities of 10⁴-10⁵ cm⁻² on the (111) face and hitherto unreported etch pits on the (100) face were observed in this work. Possible origins of the sub-grain structure are discussed.     

Detection of multiple cracks using frequency measurements

A method for detection of multiple open cracks in a slender Euler-Bernoulli beams is presented based on frequency measurements. The method is based on the approach given by Hu and Liang [J. Franklin Inst. 330 (5) (1993) 841], transverse vibration modelling through transfer matrix method and representation of a crack by rotational spring. The beam is virtually divided into a number of segments, which can be decided by the analyst, and each of them is considered to be associated with a damage parameter. The procedure gives a linear relationship explicitly between the changes in natural frequencies of the beam and the damage parameters. These parameters are determined from the knowledge of changes in the natural frequencies. After obtaining them, each is treated in turn to exactly pinpoint the crack location in the segment and determine its size. The forward, or natural frequency determination, problems are examined in the passing. The method is approximate, but it can handle segmented beams, any boundary conditions, intermediate spring or rigid supports, etc. It eliminates the need for any symbolic computation which is envisaged by Hu and Liang [J. Franklin Inst. 330 (5) (1993) 841] to obtain mode shapes of the corresponding uncracked beams. The proposed method gives a clear insight into the whole analysis. Case studies (numerical) are presented to demonstrate the method effectiveness for two simultaneous cracks of size 10% and more of section depth. The differences between the actual and predicted crack locations and sizes are less than 10% and 15% respectively. The numbers of segments into which the beam is virtually divided limits the maximum number of cracks that can be handled. The difference in the forward problem is less than 5%.     

Nd3+ Doped Silicate Glass Photonic Crystal Fiber with Random Hole Distributions

The fabrication of one kind of large core area Nd3 doped silicate glass photonic crystal fiber, and demonstration of the fiber's waveguidence properties were reported. This fiber owns a random air hole distribution in the cladding. The measured minimum loss of this kind of fiber is 10 dB·m-1 at 660 nm. These fibers can sustain only a single mode at least over wavelength ranging from 660 nm to 980 nm.     

Temperature Dependence of the Raman Spectrum in Lithium Oxide Single Crystal

Temperature dependence of the Raman spectrum of lithium oxide single crystal has been measured over a temperature range of 80 to 1073 K. The frequency shift and the line width of the Raman spectrum in lithium oxide were about 531 and 4.5 cm^-1 at 80 K, respectively. At 1073 K, the frequency shift and the line width attained the values of 464 and 112 cm^-1, respectively. The strong temperature dependence of the frequency shift and line width was compared with data from some crystals with a fluorite structure.     

An application of expert systems techniques to the on-line control and fault diagnosis of a mixing process

An application of expert hierarchical control is described in this paper. The control is implemented in a two-level configuration, where the lower layer performs direct regulation control and the upper layer performs supervisory functions. In the regulation layer, a rule-based controller performs the regulation task, where the controller is constructed upon causal relations between subsystems. The control action is inferred from the measurement of both controlled and noncontrolled variables. In the supervisory layer, the main function is a fault diagnosis system which diagnoses faults on-line. The diagnosis is based upon reasoning from the structure of the system and the functions of its components, and efficient diagnosis is achieved by dividing the system into several subsystems. The overall technique has been successfully implemented on a pilot scale mixing process under on-line computer control.