An investigation of the beneficial effects of adding carbon nanotubes to standard injection grout

Mortar grouting is often used in masonry constructions to mitigate structural decay and repair damage by filling cracks and voids, resulting in an improvement in mechanical properties. This paper presents an original experimental investigation on grout with added carbon nanotubes (CNTs). The samples were prepared with different percentages of CNTs, up to 1.2 wt% with respect to the binder, and underwent three‐point bending tests in crack mouth opening displacement mode and compressive tests. The results showed that very small additions (up to 0.12 wt% of CNTs) increased not only flexural and compressive strengths (+73% and 35%, respectively, in comparison with plain mortar) but also fracture energy (+80%). These results can be explained on the basis of a reduction in porosity, as evidenced by mercury intrusion porosimetry, as well as by a crack bridging mechanism and by the probable formation of nucleation sites for hydration products, as observed through scanning electron microscopy.     

Improving the Hybrid Data Dissemination Model of Web Documents

One of the major problems in the Internet today is the scalable delivery of data. With more and more people joining the Internet community, web servers and services are being forced to deal with workloads beyond their original data dissemination design capacity. One solution that has arisen to address scalability is to use multicasting, or push-based data dissemination, to send out data to many clients at once. More recently, the idea of using multicasting as part of a hybrid system with unicasting has shown positive results in increasing server scalability. In this paper we focus on solving problems associated with the hybrid dissemination model. In particular, we address the issues of document popularity and document division while arguing for the use of a third channel, called the multicast pull channel, in the hybrid system model. This channel improves performance in terms of response time while improving the robustness of the hybrid system. We show through extensive simulation using our working hybrid server the usefulness of this additional channel and its improving effects in creating a more scalable and more efficient web server.     

Cheat-Proof Playout for Centralized and Peer-to-Peer Gaming

We explore exploits possible for cheating in real-time, multiplayer games for both client-server and serverless architectures. We offer the first formalization of cheating in online games and propose an initial set of strong solutions. We propose a protocol that has provable anti-cheating guarantees, is provably safe and live, but suffers a performance penalty. We then develop an extended version of this protocol, called asynchronous synchronization, which avoids the penalty, is serverless, offers provable anti-cheating guarantees, is robust in the presence of packet loss, and provides for significantly increased communication performance. This technique is applicable to common game features as well as clustering and cell-based techniques for massively multiplayer games. Specifically, we provide a zero-knowledge proof protocol so that players are within a specific range of each other, and otherwise have no notion of their distance. Our performance claims are backed by analysis using a simulation based on real game traces     

Multi-objective optimization of a hydrogen production through the HyS process powered by solar energy in different scenarios

Thermochemical or hybrid cycles powered by concentrated solar energy are a very promising way to produce an effective clean hydrogen through the water splitting, in terms of greenhouse gas (GHG) emissions and power production sustainability. SOL2HY2 is an European project focused on this goal. It deepens the so-called HyS process in a closed or partially open version using a proper SO₂ depolarized electrolyser, and moreover, it investigates key materials and process solutions, along the entire production chain. However, the identification of the best solution to obtain a suitable hydrogen in terms of cost, efficiency, availability of energy and material, sharing of renewable energy source, continuity of operation in different locations and plant sizes, poses many challenges in terms of flexibility and complexity of the system. In fact, it involves various chemical equipment, different solar and thermal storage technologies, and variable operative conditions with different reaction temperatures and mixture concentrations. Hence it arises the importance to have a tool for the investigation of this system.In this paper, data analysis and multi-objective techniques are used to study and optimize the process under consideration. Several mathematical methods have been exploited to make the best use of the available data, such as Design of Experiments techniques, meta-modeling strategies and genetic algorithms. All these methods have been implemented in the open source environments Scilab and R.     

Polysaccharide and volatile composition of Cabernet wine affected by different over-lees ageing

The influence of different over-lees ageing conditions on the soluble polysaccharides?? glycosyl residue and volatile composition of Cabernet wine was addressed in this work. Specific operating conditions have been considered: wine ageing on fine white lees, wine ageing on fine red lees, wine ageing on fine second-passage white lees and short ageing on rough red lees, which were compared with ageing without lees. The ageing on lees led to an increase in all wine polysaccharide glycosyl residues, with the exception of glucose, xylose and myo-inositol, and to volatile profile modifications. Different behaviours could be observed between the four types of lees, giving important hints for a rational use of them in winemaking. In particular, the use of red grape-derived lees caused the major release of polysaccharides; on the other hand, white grape-derived lees were more effective in enhancing ester content. Second-passage lees did not lead to any increase in wine polysaccharides, whereas they allowed aroma changes, and short ageing on rough red lees caused the greatest adsorption of several volatiles.     

Achieving it consultant objectives through client project success

Improving project performance is an important objective in IS project management. In consultant-assisted IS projects, however, consulting organizations may have additional objectives, such as knowledge acquisition and future business growth. In this study, we examined the relationship between client and consultant objectives and the role of coordination in affecting the achievement of these objectives. A research model was developed and tested using 199 consultant-assisted projects. The results showed that the achievement of consultant objectives was dependent upon the achievement of client objectives and that coordination had a positive impact on both client and consultant objectives.     

Synthesis of gadolinium nanoscale metal-organic framework with hydrotropes: manipulation of particle size and magnetic resonance imaging capability

Gadolinium metal-organic framework (Gd MOF) nanoparticles are an interesting and novel class of nanomaterials that are being studied as a potential replacement for small molecule positive contrast agents in magnetic resonance imaging (MRI). Despite the tremendous interest in these nanoscale imaging constructs, there are limitations, particularly with respect to controlling the particle size, which need to be overcome before these nanoparticles can be integrated into in vivo applications. In an effort to control the size, shape, and size distribution of Gd MOF nanoparticles, hydrotropes were incorporated into the reverse microemulsion synthesis used to produce these nanoparticles. A study of how hydrotropes influenced the mechanism of formation of reverse micelles offered a great deal of information with respect to the physical properties of the Gd MOF nanoparticles formed. Specifically, this study incorporated the hydrotropes, sodium salicylate (NaSal), 5-methyl salicylic acid, and salicylic acid into the reverse microemulsion. Results demonstrated that addition of each of the hydrotropes into the synthesis of Gd MOFs provided a simple route to control the nanoparticle size as a function of hydrotrope concentration. Specifically, Gd MOF nanoparticles synthesized with NaSal showed the best reduction in size distributions in both length and width with percent relative standard deviations being nearly 50% less than nanoparticles produced via the standard route from the literature. Finally, the effect of the size of the Gd MOF nanoparticles with respect to their MRI relaxation properties was evaluated. Initial results indicated a positive correlation between the surface areas of the Gd MOF nanoparticles with the longitudinal relaxivity in MRI. In particular, Gd MOF nanoparticles with an average size of 82 nm with the addition of NaSal, yielded a longitudinal relaxivity value of 83.9 mM?1 [Gd3?] sec?1, one of the highest reported values compared to other Gd-based nanoparticles in the literature to date.     

Switched-capacitor lowpass filter without active components

A method for the synthesis of lowpass filters by means of only capacitors and m.o.s. switches, i.e. without active components, is described.