SiO2纳米粒子对铜导电胶连接强度的影响

以环氧树脂为基体，间苯二胺和二氨基二苯甲烷的低融点混合物为固化荆，铜粉为导电填料，制备了热固化各向同性导电胶。研究了固化温度、固化时间及固化荆、纳米SiO2粒子添加量对连接性能的影响。在固化温度为145℃．固化时间为2h时．导电胶连接强度达到20MPa。体系中添加适量的纳米SiO2粒子，连接强度提高到25MPa。SiO2粒子均匀地分散在环氧树脂基体的三维立体网状大分子链中，起到分散应力，吸收冲击能．阻止裂纹扩展的作用。     

石膏基建筑腻子的配制与性能研究

石膏基建筑腻子改变了传统建筑腻子中固体组分仅作为惰性填料，腻子硬化完全依赖有机粘结剂固化成膜的技术模式。采用复合缓凝技术、纤雏素醚与改性木薯淀粉胶技术可配制高性能石膏基建筑腻子，它具有施工性好、硬化快、粘结强度高的特点，是一种新型绿色建材。本文介绍其配制原理、制备工艺及性能。     

水泥混凝土粘附界面的影响因素

从水泥混凝土与工作部件表面的界面水膜特性、水泥混凝土特性、工作部件表面特性、外部因素等角度入手,分析了水泥混凝土粘附界面影响因素。结果表明,水泥混凝土和工作部件的界面产生粘附的主要影响因素包括界面水膜、水灰比、砂灰比、沙率、粗集料形状、外加剂、工作部件表面形状、材料以及外力和温度等。通过分析对接触界面的水膜连续性和粘附界面的实际接触面积有影响的关键性因素,探讨了实现对水泥混凝土减粘脱附的有效途径,为利用土壤动物减粘脱附仿生研究成果解决水泥混凝土粘附问题创造了条件。     

凸包型推土板减粘降阻的有限元分析

仿生几何非光滑表面的减粘降阻功效已被大量的试验研究所证实。由于几何非光滑结构单元的大小和分布对减粘降阻效果具有显著的影响，故对其与土壤相互作用的定量分析是必要的。本文对凸包型几何非光滑表面与土壤相互作用进行了三维有限元分析，并将其同光滑表面与土壤相互作用的有限元分析结果进行了比较，分析了减粘降阻的原因。     

ZrO2薄膜的力学性能和摩擦学性能研究

在单晶硅表面成功地获得了自组装单层薄膜(MPTS-SAM),并将薄膜表面的巯基(-SH)完全氧化成磺酸基(-SO3H),从而获得了磺酸化的MPTS-SAM.采用静电自组装技术成功使ZrO2纳米微粒组装到磺酸化的MPTS-SAM表面获得淀积ZrO2薄膜.将ZrO2薄膜分别在500℃和800℃进行热处理后,ZrO2薄膜的厚度逐渐减小,这可能是随着温度的升高薄膜的表面密度逐渐增大所致.对ZrO2薄膜的力学和抗划伤性能分析发现:随着温度的升高,ZrO2薄膜的硬度和弹性模量依次增加,同时薄膜的抗划伤性能也逐渐提高.摩擦磨损实验表明:利用该方法制备的ZrO2薄膜经800℃烧结处理后适于在低负荷、低滑动速度下作为减摩、抗磨保护性涂层.     

CN<em>x/TiN多层复合涂层抗水蚀性能的研究

采用多弧-磁控溅射镀膜机在不锈钢2Cr13衬底上沉积CN_<em>x/TiN多层复合涂层。利用光电子能谱仪(XPS)和透射电子衍射(TED)对涂层的组成和结构进行分析。利用自行研制的高压水蚀试验装置对不锈钢、高铬铸铁、司太立合金以及CN_<em>x/TiN多层复合涂层的抗水蚀性能进行对比试验,最后对涂层的水蚀失效机理进行了探讨。试验结果表明:CN_<em>x/TiN多层复合涂层具有较高的硬度、附着力、抗热冲击性能以及优异的抗水蚀性能,是一种优良的汽轮机末级叶片抗水蚀用涂层。     

WC—Co硬质合金基体上金刚石薄膜的附着机理研究

金刚石涂层在硬质合金(WC-Co)基体上的附着力,是影响金刚石涂层刀具切削性能和使用寿命的关键因素.采用微波等离子体化学气相沉积(CVD)法在经酸浸蚀脱Co的硬质合金基体上生长金刚石薄膜.通过对金刚石膜/基界面的微观形貌和成分分析,初步认识了金刚石薄膜的附着机理:机械锁合作用对金刚石膜/基附着力有较大贡献;界面热应力和弱中间相的存在是导致金刚石膜自发剥离的主要原因.     

Research on Processes and Adhesion of Electroless Plating Ni-Cu-P Coating

In order to improve the corrosion and wear resistance of the coatings of electroless plating Ni-Cu-P and broaden its application, an optimizing mathematical theory test has been applied in this research. The processing parameters have been optimized and some Ni-Cu-P coatings have been obtained with smooth and glittering appearance. At the same time,the composite complexants can prevent copper from depositing first and obtain coatings with strong adhesion. The porosity of Ni-Cu-P coating (20 μm) ranked class 9. The changing color time of the coating is more than 800 seconds with HNO3 dropthan 0.5 g/L. The surface appearance of deposition is typical cystiform cells by SEM,which rank close and neatly.     

Surface Modification of Biomaterials in Hard Tissue Applications

Surface modification technologies are quite common in the biomedical field to improve the mechanical,chemical, physical and biological properties of implants such as artificial joint and cardiovascular devices. In this paper, recent progress in the investigation of the bioactivity and biocompatibility enhancement of implants using plasma spraying and plasmabased ion implantation (PIII) is described. Plasma sprayed hydroxyapatite (HA) coatings are commonly used as bioactive coatings but the relatively poor adhesion between the coatings and titanium is one of main disadvantages which have limited their biomedical applications. In our recent studies, novel bioactive coatings, such as wollastonite and dicalcium silicate, were deposited onto titanium to enhance the surfaces bioactivity and biocompatibility. Our results indicate that plasma sprayed wollastonite and dicalcium silicate coatings possess excellent bioactivity as well as relatively high bonding strength. Plasma immersion ion implantation was also employed to improve the anti-corrosion and biological properties of implants.